Single-crystalline silver nanoplates with an average in-plane dimension and thickness of about 700 and 25 nm, respectively, were fabricated on a large scale in aqueous poly(vinyl pyrrolidone)/AgNO3 solution by a simple one-step hydrothermal method. In this process, poly(vinyl pyrrolidone) (PVP) acts as both reducing agent and shape-directing agent. SAED and XRD measurements reveal that the growth of silver nanoplates is mainly dominated by (111) facets.
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