Silica nanoparticles assisted Ba2SiO4:Eu2+—a bluish-green emitting remote phosphor for white light application

Abinaya Mayavan , Aarthi Kannan , Sakthivel Gandhi

Front. Optoelectron. ›› 2025, Vol. 18 ›› Issue (2) : 8

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Front. Optoelectron. ›› 2025, Vol. 18 ›› Issue (2) : 8 DOI: 10.1007/s12200-025-00150-w
RESEARCH ARTICLE

Silica nanoparticles assisted Ba2SiO4:Eu2+—a bluish-green emitting remote phosphor for white light application

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Abstract

Silica nanoparticles were used to develop a bluish-green emitting Ba2SiO4:Eu2+ phosphor, demonstrating their potential for white light applications. The phosphor showed a 48% enhancement of emission intensity compared to conventional silica-assisted phosphors. The use of silica nanoparticles as a precursor could lead to the creation of a more homogeneous distribution of cations and dopant ions. This uniform distribution could facilitate the proper infusion of dopants into the crystal host, resulting in improved emission. The phosphor exhibited high thermal stability, with 56% of its luminescence intensity maintained even at 190 ℃ compared to room temperature. To reduce thermal stress, a flexible remote phosphor has been developed successfully using optimized silica nanoparticles assisted Ba2SiO4:Eu2+ phosphor.

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Keywords

Remote phosphor / Barium silicate phosphor / Bluish-green emission / Silica nanoparticle

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Abinaya Mayavan, Aarthi Kannan, Sakthivel Gandhi. Silica nanoparticles assisted Ba2SiO4:Eu2+—a bluish-green emitting remote phosphor for white light application. Front. Optoelectron., 2025, 18(2): 8 DOI:10.1007/s12200-025-00150-w

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References

[1]

Wei, Q. , Ding, J. , Zhou, X. , Wang, X. , Wang, Y. : New strategy of designing a novel yellow-emitting phosphor Na4Hf2Si3O12:Eu2+ for multifunctional applications. J. Alloys Compd. 817, 152762 (2019)

[2]

Yang, S.H. , Lin, C.M. , Tung, W.M. , Wang, W.J. , Hung, T.C. : Luminescence enhancement of SrZn2(PO4)2:Eu2+, Mn2+ phosphor co-doped with Al3+. J. Alloys Compd. 695, 2757- 2763 (2017)

[3]

Ling, J. , Xu, W. , Yang, J. , Mu, T. , Zhang, Y. , Zhou, Y. , Hong, M. : The effect of Lu3+ doping upon YAG: Ce phosphor ceramics for high-power white LEDs. J. Eur. Ceram. Soc. 41 (12), 5967- 5976 (2021)

[4]

Peng, Y. , Wang, H. , Liu, J. , Sun, Q. , Mou, Y. , Guo, X. : Broadband and stable phosphor-in-glass enabling ultrahigh color rendering for all-inorganic high-power WLEDs. ACS Appl. Electron. Mater. 2 (9), 2929- 2936 (2020)

[5]

Ryckaert, J. , Correia, A. , Tessier, M.D. , Dupont, D. , Hens, Z. , Hanselaer, P. , Meuret, Y. : Selecting the optimal synthesis parameters of InP/CdxZn1-x Se quantum dots for a hybrid remote phosphor white LED for general lighting applications. Opt. Express 25 (24), A1009 (2017)

[6]

Xu, L. , Zhao, G. , Meng, S. , Fang, Y. , Hou, J. , Liu, Y. , Liao, M. , Zou, J. , Hu, L. : Enhanced luminescent performance for remote LEDs of Ce:YAG phosphor-in-glass film on regular textured glass substrate by using chemical wet-etching. Ceram. Int. 44 (18), 22283- 22288 (2018)

[7]

Chen, M.J. , Loan, N.T.P. , Van Tho, L. , Bui, T.M. , Le, P.X. , Anh, N.D.Q. , Liao, H.Y. , Chang, J.C. , Lee, H.Y. : The impacts of Ba2Li2Si2O7:Sn2+, Mn2+ and CaMgSi2O6:Eu2+, Mn2+ particles on the optical properties of remote phosphor LED. Mater. Sci. Pol. 38 (1), 197- 205 (2020)

[8]

Perera, I.U. , Narendran, N. : Analysis of a remote phosphor layer heat sink to reduce phosphor operating temperature. Int. J. Heat. Mass Transf. 117, 211- 222 (2018)

[9]

Wang, Q.Y. , Yuan, P. , Wang, T.W. , Yin, Z.Q. , Lu, F.C. : Effect of Sr and Ca substitution of Ba on the photoluminescence properties of the Eu2+ activated Ba2MgSi2O7 phosphor. Ceram. Int. 46 (2), 1374- 1382 (2020)

[10]

Balakrishnan, P. , Jayachandiran, M. , Kennedy, M.M. : Photoluminescence properties and energy transfer in the color tunable Ba2CaZn2Si6O17Bi3+, Tb3+, Eu3+ silicate phosphor for white LED applications. Inorg. Chem. Commun. 123, 108308 (2021)

[11]

Asami, K. , Ueda, J. , Yasuda, K. , Hongo, K. , Maezono, R. , Brik, M.G. , Tanabe, S. : Development of persistent phosphor of Eu2+ doped Ba2SiO4 by Er3+ codoping based on vacuum referred binding energy diagram. Opt. Mater. 84, 436- 441 (2018)

[12]

Zahedi, M. , Hassanzadeh-Tabrizi, S.A. , Saffar-Teluri, A. : Sol-gel synthesis and luminescence properties of Ba2SiO4:Sm3+ nanostructured phosphors. Ceram. Int. 44 (9), 10169- 10174 (2018)

[13]

Hu, X. , Li, Z. , Xu, X. , Li, Y. : Enhancement of photoluminescence of Ba2SiO4:Eu2+ by co-doping of La3+ or Y3+. J. Rare Earths. 27 (1), 47- 49 (2009)

[14]

Kim, D. , Jeon, K.W. , Jin, J.S. , Kang, S.G. , Seo, D.K. , Park, J.C. : Remarkable flux effect of Li-codoping on highly enhanced luminescence of orthosilicate Ba2SiO4:Eu2+ phosphors for NUVLEDs: autonomous impurity purification by eutectic Li2CO3 melts. RSC Adv. 5 (127), 105339- 105346 (2015)

[15]

Venkataravanappa, M. , Nagabhushana, H. , Darshan, G.P. , Sharma, S.C. , Archana, K.V. , Basavaraj, R.B. , Prasad, B.D. : Facile ultrasound route for the fabrication of green emitting Ba2SiO4:Eu2+ nanophosphors for display and dosimetric applications. Mater. Res. Bull. 97, 281- 292 (2018)

[16]

Cao, R. , Wang, X. , Ouyang, X. , Jiao, Y. , Li, Y. , Wan, H. , Li, W. , Luo, Z. : Thermally stable orange-red emitting Ba2SiO4:Sm3+ phosphor: synthesis and luminescence properties. J. Lumin. 224, 117292 (2020)

[17]

Bispo-Jr, A.G. , Lima, S.A.M. , Lanfredi, S. , Praxedes, F.R. , Pires, A.M. : Tunable blue-green emission and energy transfer properties in Ba2SiO4:Tb3+ obtained from sol-gel method. J. Lumin. 214, 116604 (2019)

[18]

Eagleman, Y. , Bourret-Courchesne, E. , Derenzo, S.E. : Investigation of Eu2+ doped barium silicates as scintillators. IEEE Trans. Nucl. Sci. 59 (2), 479- 486 (2012)

[19]

Mayavan, A. , Ganesamurthi, J.S. , Jang, K. , Gandhi, S. : Development of bluish green-emitting Ca2-xEuxSiO4 phosphor: a novel approach using silica nanoparticles as precursor. J. Lumin. 230, 117664 (2021)

[20]

Mayavan, A. , Krishnan, S.D. , Rajendran, P. , Jang, K. , Gandhi, S. : Silica nanoparticles assisted preparation of reddish-yellow emitting Eu2+ activated remote-type CaSrSiO4 phosphor for warm white LED applications. Ceram. Int. 46 (8), 12216- 12223 (2020)

[21]

Mayavan, A. , Kannan, A. , Gandhi, S. : Photoluminescence assessment of Ba2-xEuxSiO4 phosphor prepared through a solid phase reaction technique using silica nanoparticles as a precursor. Mater. Chem. Phys. 288, 126329 (2022)

[22]

Ibrahim, I.M. , Zikry, F. , Sharaf, M.A. : Preparation of spherical silica nanoparticles Stober silica. J. Am. Sci. 6, 98- 989 (2010)

[23]

Huang, Y. , Qin, J. , Fan, Z. , Wei, D. , Seo, H.J. : Photoenergy conversion behaviors of photoluminescence and photocatalysis in silver-coated LiBaPO4:Eu2+. Inorg. Chem. 58 (19), 13161- 13169 (2019)

[24]

Dhananjaya, N. , Nagabhushana, H. , Nagabhushana, B.M. , Rudraswamy, B. , Shivakumara, C. , Chakradhar, R.P.S. : Spherical and rod-like Gd2O3:Eu3+ nanophosphors-structural and luminescent properties. Bull. Mater. Sci. 35 (4), 519- 527 (2012)

[25]

Yang, L. , Mu, Z. , Zhang, S. , Wang, Q. , Zhu, D. , Zhao, Y. , Luo, D. , Zhang, Q. , Wu, F. : Dy3+ doped Ca9Gd(PO4)7: a novel single-phase full-color emitting phosphor. J. Mater. Sci. Mater. Electron. 29 (8), 6548- 6555 (2018)

[26]

Zhuo, Y. , Wu, F. , Niu, Y. , Wang, Y. , Zhang, Q. , Teng, Y. , Dong, H. : Super broadband emission across NIR-I and NIR-II under blue light excitation of Cr3+, Ni2+ Co-doped Sr2GaTaO6 phosphor achieved by two-site occupation and effective energy transfer. Laser Photonics Rev. 18 (8), 2400105 (2024)

[27]

Li, Q. , Zhang, S. , Lin, W. , Li, W. , Li, Y. , Mu, Z. , Wu, F. : A warm white emission of Bi3+-Eu3+ and Bi3+-Sm3+ codoping Lu2Ge2O7 phosphors by energy transfer of Bi3+-sensitized Eu3+/Sm3+. Spectrochim. Acta. A Mol. Biomol. Spectrosc. 228, 117755 (2020)

[28]

Genevès, T. , Domenichini, B. , Imhoff, L. , Potin, V. , Heintz, O. , Peterlé, P.M. , Bourgeois, S. : Elaboration and characterization of barium silicate thin films. Micron 39 (8), 1145- 1148 (2008)

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