Reverse electrodialysis heat engine with helium-gap diffusion distillation: Energy efficiency analysis
Received date: 27 Sep 2023
Accepted date: 01 Apr 2024
Copyright
The depletion of energy resources poses a significant threat to the development of human society. Specifically, a considerable amount of low-grade heat (LGH), typically below 100 °C, is currently being wasted. However, efficient utilization of this LGH can relieve energy shortages and reduce carbon dioxide emissions. To address this challenge, reverse electrodialysis heat engine (REDHE) which can efficiently convert LGH into electricity has emerged as a promising technology in recent years. Extensive efforts have been dedicated to exploring more suitable thermal distillation technologies for enhancing the performance of REDHE. This paper introduces a novel REDHE that incorporates helium-gap diffusion distillation (HGDD) as the thermal separation (TS) unit. The HGDD device is highly compact and efficient, operating at a normal atmospheric pressure, which aligns with the operational conditions of the reverse electrodialysis (RED) unit. A validated mathematical model is employed to analyze the impacts of various operating and structural parameters on the REDHE performance. The results indicate that maintaining a moderate molality of the cold stream, elevating the inlet temperatures of hot and cold streams, lengthening hot- and cold-stream channels, and minimizing the thickness of helium gaps contribute to improving the REDHE performance. Especially, a maximum energy conversion efficiency of 2.96% is achieved by the REDHE when decreasing the thickness of helium gaps to 3 mm and increasing the length of stream channels to 5 m.
Junyong Hu , Yukun Sun , Yali Hu , Haiyu Liu , Jiajie Zhang , Suxia Ma , Jiaxin Huang , Xueyi Tan , Ling Zhao . Reverse electrodialysis heat engine with helium-gap diffusion distillation: Energy efficiency analysis[J]. Frontiers in Energy, . DOI: 10.1007/s11708-024-0947-3
Abbreviations | |
AEM | Anion-exchange membrane |
AGMD | Air-gap membrane distillation |
CEM | Cation-exchange membrane |
HC | High-concentration |
HGDD | Helium-gap diffusion distillation |
IEMs | Ion-exchange membranes |
LC | Low-concentration |
LGH | Low-grade heat |
MD | Membrane distillation |
MED | Multi-effect distillation |
MSRED | Multi-stage reverse electrodialysis |
RED | Reverse electrodialysis |
REDHE | Reverse electrodialysis heat engine |
SGE | Salinity gradient energy |
TDEG | Thermal-driven electrochemical generator |
TS | Thermal separation |
Variables | |
B | Width, m |
C | Concentration of solution, mol·m−3 |
Cp | Specific heat of salt solution, J·kg−1·K−1 |
I | Current, A |
Jv | Mass flux of the vapor diffusion in the gap, kg·m−2·s−1 |
L | Length, m |
ṁ | Mass flowrate, kg·s−1 |
m | Molality, mol·kg−1 |
MNaCl | The relative molecular mass of NaCl |
N | Number of gaps in HGDD |
Ncell | Number of cells in a RED stack |
P | Output power, kW or pressure, Pa |
Q | Total LGH consumption by HGDD, kW |
α | Permselectivity of both ion-exchange membranes |
γ | Water latent heat of evaporation, kJ·kg−1 or mean ion activity coefficient |
δ | Thickness of solution compartments, m |
δc | Thickness of gap, m |
ΔP | Pressure drops, Pa |
η | Energy conversion efficiency |
ηpump | Efficiency of pump |
Φ | Specific volume, m3·kg−1 |
Superscripts and subscripts | |
af | Water-vapor-partial pressure at the gap and condensate-water-film interface |
b | Brackish solution |
c/cold | Cold-stream channel or helium gaps |
h | Hot-stream channel |
ha | Water-vapor-partial pressure at the gap and porous-medium interface |
in | Inlet flow |
out | Outlet flow |
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