A review on the development of electrolytes for lithium-based batteries for low temperature applications

Abstract

The aerospace industry relies heavily on lithium-ion batteries in instrumentation such as satellites and land rovers. This equipment is exposed to extremely low temperatures in space or on the Martian surface. The extremely low temperatures affect the discharge characteristics of the battery and decrease its available working capacity. Various solvents, cosolvents, additives, and salts have been researched to fine tune the conductivity, solvation, and solid-electrolyte interface forming properties of the electrolytes. Several different resistive phenomena have been investigated to precisely determine the most limiting steps during charge and discharge at low temperatures. Longer mission lifespans as well as self-reliance on the chemistry are now highly desirable to allow low temperature performance rather than rely on external heating components. As Martian rovers are equipped with greater instrumentation and demands for greater energy storage rise, new materials also need to be adopted involving next generation lithium-ion chemistry to increase available capacity. With these objectives in mind, tailoring of the electrolyte with higher-capacity materials such as lithium metal and silicon anodes at low temperatures is of high priority. This review paper highlights the progression of electrolyte research for low temperature performance of lithium-ion batteries over the previous several decades.

Key words： electrolyte; lithium-ion; low temperature; aerospace; solid-electrolyte interface

Acknowledgements

This work was funded by the National Aeronautics and Space Administration, USA (No. 80NSSC19M0152).

References

1 Wang X, Tang S, Guo W. . Advances in multimetallic alloy-based anodes for alkali-ion and alkali-metal batteries. Materials Today, 2021, 50(11): 259–275

2 Yoshino A. The birth of the lithium-ion battery. Angewandte Chemie International Edition, 2012, 51(24): 5798–5800

3 Manthiram A. An outlook on lithium ion battery technology. ACS Central Science, 2017, 3(10): 1063–1069

4 Wittman R M, Perry M L, Lambert T N. . Perspective—on the need for reliability and safety studies of grid-scale aqueous batteries. Journal of the Electrochemical Society, 2020, 167(9): 090545

5 Jaguemont J, Boulon L, Dubé Y. A comprehensive review of lithium-ion batteries used in hybrid and electric vehicles at cold temperatures. Applied Energy, 2016, 164: 99–114

6 Ratnakumar B V, Smart M C, Huang C K. . Lithium ion batteries for Mars exploration missions. Electrochimica Acta, 2000, 45(8–9): 1513–1517

7 Ratnakumar B V, Smart M C, Kindler A. . Lithium batteries for aerospace applications: 2003 Mars Exploration Rover. Journal of Power Sources, 2003, 119–121: 906–910

8 Huang C K, Sakamoto J S, Wolfenstine J. . The limits of low-temperature performance of Li-ion cells. Journal of the Electrochemical Society, 2000, 147(8): 2893–2896

9 Smart M C, Ratnakumar B V, Surampudi S. Electrolytes for low-temperaturelithium batteries based on ternary mixtures of aliphatic carbonates. Journal of the Electrochemical Society, 1999, 146(2): 486–492

10 SmartM CRatnakumarB VSurampudiS. Electrolytes for Li-ion cells in low temperature applications. In: 14th Annual Battery Conference on Applications and Advances, Long Beach, USA, 1999

11 SmartM CRatnakumarB VGreenbaumS, . The role of electrolyte upon the SEI formation characteristics and low temperature performance of lithium-ion cells with graphite anodes. Proceedings—Electrochemical Society, 1999, 98–16: 441–447

12 SmartM CRatnakumarB VWhitcanackL, . Performance characteristics of lithium ion cells at low temperatures. In: Proceedings of the Annual Battery Conference on Applications and Advances, Long Beach, USA, 2002

13 Smart M C, Ratnakumar B V. Effects of electrolyte composition on lithium plating in lithium-ion cells. Journal of the Electrochemical Society, 2011, 158(4): A379–A389

14 Arai J, Nakahigashi R. Study of Li metal deposition in lithium ion battery during low-temperature cycle using in situ solid-state 7 Li nuclear magnetic resonance. Journal of the Electrochemical Society, 2017, 164(13): A3403–A3409

15 Ratnakumar B V, Smart M C, Surampudi S. Electrochemical impedance spectroscopy and its applications. In: Annual Battery Conference on Applications and Advances, 2002, 273–277

16 Ratnakumar B V, Smart M C, Surampudi S. Effects of SEI on the kinetics of lithium intercalation. Journal of Power Sources, 2001, 97–98: 137–139

17 Smart M C, Ratnakumar B V, Surampudi S. . Irreversible capacities of graphite in low-temperature electrolytes for lithium-ion batteries. Journal of the Electrochemical Society, 1999, 146(11): 3963–3969

18 Smart M C, Ratnakumar B V, Ewell R C. . The use of lithium-ion batteries for JPL’s Mars missions. Electrochimica Acta, 2018, 268: 27–40

19 Kulova T L, Skundin A M. A critical review of electrode materials and electrolytes for low-temperature lithium-ion batteries. International Journal of Electrochemical Science, 2020, 15(9): 8638–8661

20 Smart M C, Ratnakumar B V, Whitcanack L D. . Improved low-temperature performance of lithium-ion cells with quaternary carbonate-based electrolytes. Journal of Power Sources, 2003, 119–121: 349–358

21 Smart M C, Ratnakumar B V, Behar A. . Gel polymer electrolyte lithium-ion cells with improved low temperature performance. Journal of Power Sources, 2007, 165(2): 535–543

22 Smart M C, Lucht B L, Dalavi S. . The effect of additives upon the performance of MCMB/LiNi_xCo_1−xO₂ Li-ion cells containing methyl butyrate-based wide operating temperature range electrolytes. Journal of the Electrochemical Society, 2012, 159(6): A739–A751

23 Jones J P, Smart M C, Krause F C. . The effect of electrolyte additives upon lithium plating during low temperature charging of graphite-LiNiCoAlO₂ lithium-ion three electrode cells. Journal of the Electrochemical Society, 2020, 167(2): 020536

24 Etacheri V, Haik O, Goffer Y. . Effect of fluoroethylene carbonate (FEC) on the performance and surface chemistry of Si-nanowire Li-ion battery anodes. Langmuir, 2012, 28(1): 965–976

25 Smart M C, Ratnakumar B V, Surampudi S. Use of organic esters as cosolvents in electrolytes for lithium-ion batteries with improved low temperature performance. Journal of the Electrochemical Society, 2002, 149(4): A361–A370

26 Smart M C, Ratnakumar B V, Whitcanack L D. . Li-ion electrolytes containing ester Co-solvents for wide operating temperature range. ECS Transactions, 2008, 11(29): 99–108

27 Zheng J, Yan P, Cao R. . Effects of propylene carbonate content in CsPF₆-containing electrolytes on the enhanced performances of graphite electrode for lithium-ion batteries. ACS Applied Materials & Interfaces, 2016, 8(8): 5715–5722

28 Kim T, Song W, Son D Y. . Lithium-ion batteries: outlook on present, future, and hybridized technologies. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2019, 7(7): 2942–2964

29 Purwanto A, Yudha C S, Ubaidillah U. . NCA cathode material: synthesis methods and performance enhancement efforts. Materials Research Express, 2018, 5(12): 122001

30 Bruce P G, Armstrong A R, Gitzendanner R L. New intercalation compounds for lithium batteries: layered LiMnO₂. Journal of Materials Chemistry, 1999, 9(1): 193–198

31 Liu C, Massé R, Nan X. . A promising cathode for Li-ion batteries: Li₃V₂(PO₄)₃. Energy Storage Materials, 2016, 4: 15–58

32 Ni Q, Zheng L, Bai Y. . An extremely fast charging Li₃V₂(PO₄)₃ cathode at a 4.8 V cutoff voltage for Li-ion batteries. ACS Energy Letters, 2020, 5(6): 1763–1770

33 Vadivel S, Phattharasupakun N, Wutthiprom J. . High-performance Li-ion batteries using nickel-rich lithium nickel cobalt aluminium oxide−nanocarbon core−shell cathode: in operando X–ray diffraction. ACS Applied Materials & Interfaces, 2019, 11(34): 30719–30727

34 Yan P, Zheng J, Lv D. . Atomic-resolution visualization of distinctive chemical mixing behavior of Ni, Co, and Mn with Li in layered lithium transition-metal oxide cathode materials. Chemistry of Materials, 2015, 27(15): 5393–5401

35 Zaghib K, Dontigny M, Perret P. . Electrochemical and thermal characterization of lithium titanate spinel anode in C–LiFePO₄//C-Li₄Ti₅O₁₂ cells at sub-zero temperatures. Journal of Power Sources, 2014, 248: 1050–1057

36 Qin R, Wei Y, Zhai T. . LISICON structured Li₃V₂(PO₄)₃ with high rate and ultralong life for low-temperature lithium-ion batteries. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2018, 6(20): 9737–9746

37 Ho C K, Li C Y V, Deng Z. . Hierarchical macropore-mesoporous shell carbon dispersed with Li₄Ti₅O₁₂ for excellent high rate sub-freezing Li-ion battery performance. Carbon, 2019, 145: 614–621

38 Na Y, Sun X, Fan A. . Methods for enhancing the capacity of electrode materials in low-temperature lithium-ion batteries. Chinese Chemical Letters, 2020, 32(3): 973–982

39 Li Q, Lu D, Zheng J. . Li⁺-desolvation dictating lithium-ion battery’s low-temperature performances. ACS Applied Materials & Interfaces, 2017, 9(49): 42761–42768

40 Okumura T, Horiba T. Phase transition of carbonate solvent mixture solutions at low temperatures. Journal of Power Sources, 2016, 301: 138–142

41 Smart M C, Ratnakumar B V, Chin K B. . Lithium-ion electrolytes containing ester cosolvents for improved low temperature performance. Journal of the Electrochemical Society, 2010, 157(12): A1361–A1374

42 Smart M C, Ratnakumar B, Whitcanack L. . Performance demonstration of MCMB-LiNiCoO₂ cells containing electrolytes designed for wide operating temperature range. ECS Transactions, 2010, 25(36): 273–282

43 Smart M C, Ratnakumar B V, Whitcanack L D. . Life verification of large capacity Yardney Li-ion cells and batteries in support of NASA missions. International Journal of Energy Research, 2010, 34(2): 116–132

44 Smith K A, Smart M C, Prakash G K S. . Electrolytes containing fluorinated ester Co-solvents for low-temperature Li-ion cells. ECS Transactions, 2008, 11(29): 91–98

45 Zhang S S. Lithium oxalyldifluoroborate as a salt for the improved electrolytes of Li-ion batteries. ECS Meeting Abstracts, 2006, MA2006-02(5): 267–267

46 Li Q, Liu G, Cheng H. . Low-temperature electrolyte design for lithium-ion batteries: prospect and challenges. Chemistry (Weinheim an der Bergstrasse, Germany), 2021, 27(64): 15842–15865

47 Jin Y, Kneusels N J H, Marbella L E. . Understanding fluoroethylene carbonate and binylene carbonate based electrolytes for Si anodes in lithium ion batteries with NMR spectroscopy. Journal of the American Chemical Society, 2018, 140(31): 9854–9867

48 BachandG. Using copper nanoparticle additive to improve the performance of silicon anodes in lithium-ion batteries. Dissertation for the Master’s Degree. Reno: University of Nevada, 2017

49 Holoubek J, Yu M, Yu S. . An all-fluorinated ester electrolyte for stable high-voltage Li metal batteries capable of ultra-low-temperature operation. ACS Energy Letters, 2020, 5(5): 1438–1447

50 Zheng H, Xiang H, Jiang F. . Lithium difluorophosphate-based dual-salt low concentration electrolytes for lithium metal batteries. Advanced Energy Materials, 2020, 10(30): 2001440

51 Thenuwara A C, Shetty P P, McDowell M T. Distinct nanoscale interphases and morphology of lithium metal electrodes operating at low temperatures. Nano Letters, 2019, 19(12): 8664–8672

52 Zhang N, Deng T, Zhang S. . Critical review on low-temperature Li-ion/metal batteries. Advanced Materials, 2022, 34(15): 1–31

53 Dong X, Wang Y G, Xia Y. Promoting rechargeable batteries operated at low temperature. Accounts of Chemical Research, 2021, 54(20): 3883–3894

54 Holoubek J, Liu H, Wu Z. . Tailoring electrolyte solvation for Li metal batteries cycled at ultra-low temperature. Nature Energy, 2021, 6(3): 303–313

55 Thenuwara A C, Shetty P P, Kondekar N. . Efficient low-temperature cycling of lithium metal anodes by tailoring the solid-electrolyte interphase. ACS Energy Letters, 2020, 5(7): 2411–2420

56 Gupta A, Manthiram A. Designing advanced lithium-based batteries for low-temperature conditions. Advanced Energy Materials, 2020, 10(38): 2001972

57 Zhou J, Ji H, Qian Y. . Molecular simulations guided polymer electrolyte towards superior low-temperature solid lithium-metal batteries. ACS Applied Materials & Interfaces, 2021, 13(41): 48810–48817

58 Song S, Wu Y, Tang W. . Composite solid polymer electrolyte with garnet nanosheets in poly(ethylene oxide). ACS Sustainable Chemistry & Engineering, 2019, 7(7): 7163–7170

59 Zhu F, Bao H, Wu X. . High-performance metal-organic framework-based single ion conducting solid-state electrolytes for low-temperature lithium metal batteries. ACS Applied Materials & Interfaces, 2019, 11(46): 43206–43213

60 Fu C, Homann G, Grissa R. . A polymerized-ionic-liquid-based polymer electrolyte with high oxidative stability for 4 and 5 V class solid-state lithium metal batteries. Advanced Energy Materials, 2022, 12(27): 2200412

61 Liu J, Xu R, Yan C. . In situ regulated solid electrolyte interphase via reactive separators for highly efficient lithium metal batteries. Energy Storage Materials, 2020, 30(5): 27–33

62 Yao B, Ding Z, Zhang J. . Encapsulation of LiFePO₄ by in-situ graphitized carbon cage towards enhanced low temperature performance as cathode materials for lithium-ion batteries. Journal of Solid State Chemistry, 2014, 216: 9–12

63 Fu C, Shen S, Wu R. . Facile controlled synthesis of hierarchically structured mesoporous Li₄Ti₅O₁₂/C/RGO composites as high-performance anode of lithium-ion batteries. Frontiers in Energy, 2022, 16(4): 607–612

64 Gao Y, Rojas T, Wang K. . Low-temperature and high-rate-charging lithium metal batteries enabled by an electrochemically active monolayer-regulated interface. Nature Energy, 2020, 5(7): 534–542

65 Bian Z, Tang Z, Xie J. . Preparation and lithium storage performances of G-C₃N₄/Si nanocomposites as anode materials for lithium-ion battery. Frontiers in Energy, 2020, 14(4): 759–766

66 Wu H, Chan G, Choi J W. . Stable cycling of double-walled silicon nanotube battery anodes through solid-electrolyte interphase control. Nature Nanotechnology, 2012, 7(5): 310–315

67 Hubble D, Brown D E, Zhao Y. . Liquid electrolyte development for low-temperature lithium-ion batteries. Energy & Environmental Science, 2022, 15(2): 550–578

68 Domi Y, Usui H, Hirosawa T. . Impact of low temperatures on the lithiation and delithiation properties of Si-based electrodes in ionic liquid electrolytes. ACS Omega, 2022, 7(18): 15846–15853