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Amino acid promoted hydrogen battery system using Mn-pincer complex for reversible CO2 hydrogenation to formic acid

  • Zupeng CHEN , 1 ,
  • Henrik JUNGE , 2 ,
  • Matthias BELLER , 2
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  • 1. Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China; Leibniz-Institute for Catalysis, University of Rostock, Rostock 18059, Germany
  • 2. Leibniz-Institute for Catalysis, Rostock 18059, Germany

Received date: 09 Sep 2022

Accepted date: 27 Sep 2022

Published date: 15 Oct 2022

Copyright

2022 Higher Education Press 2022

Cite this article

Zupeng CHEN , Henrik JUNGE , Matthias BELLER . Amino acid promoted hydrogen battery system using Mn-pincer complex for reversible CO2 hydrogenation to formic acid[J]. Frontiers in Energy, 2022 , 16(5) : 697 -699 . DOI: 10.1007/s11708-022-0843-7

Acknowledgments

Z. Chen acknowledges the support from the Alexander von Humboldt Foundation.
1
TansP. Trends in atmospheric carbon dioxide. 2022-9-5, available at website of the National Oceanic and Atmospheric Administration

2
KeelingR. Carbon dioxide measurements. 2022-10-2, available at website of the Scripps Institution of Oceanography

3
Zhang W, Jin Z, Chen Z. Rational-designed principles for electrochemical and photoelectrochemical upgrading of CO2 to value-added chemicals. Advanced Science, 2022, 9(9): 2105204

DOI

4
Huang Z, Zhu L, Li A. . Renewable synthetic fuel: turning carbon dioxide back into fuel. Frontiers in Energy, 2022, 16(2): 145–149

DOI

5
Zhang W, Hu Y, Ma L. . Progress and perspective of electrocatalytic CO2 reduction for renewable carbonaceous fuels and chemicals. Advanced Science, 2018, 5(1): 1700275

DOI

6
Dutta I, Chatterjee S, Cheng H. . Formic acid to power towards low-carbon economy. Advanced Energy Materials, 2022, 12(15): 2103799

DOI

7
Wei D, Sang R, Moazezbarabadi A. . Homogeneous carbon capture and catalytic hydrogenation: toward a chemical hydrogen battery system. JACS Au, 2022, 2(5): 1020–1031

DOI

8
Wei D, Junge H, Beller M. An amino acid based system for CO2 capture and catalytic utilization to produce formats. Chemical Science, 2021, 12(17): 6020–6024

DOI

9
Sordakis K, Tang C, Vogt L K. . Homogeneous catalysis for sustainable hydrogen storage in formic acid and alcohols. Chemical Reviews, 2018, 118(2): 372–433

DOI

10
Mellmann D, Sponholz P, Junge H. . Formic acid as a hydrogen storage material-development of homogeneous catalysts for selective hydrogen release. Chemical Society Reviews, 2016, 45(14): 3954–3988

DOI

11
Bertini F, Glatz M, Gorgas N. . Carbon dioxide hydrogenation catalysed by well-defined Mn(i) PNP pincer hydride complexes. Chemical Science, 2017, 8(7): 5024–5029

DOI

12
Dubey A, Nencini L, Fayzullin R R. . Bio-inspired Mn(i) complexes for the hydrogenation of CO2 to formate and formamide. ACS Catalysis, 2017, 7(6): 3864–3868

DOI

13
Schlenker K, Christensen E G, Zhanserkeev A A. . Role of ligand-bound CO2 in the hydrogenation of CO2 to formate with a (PNP)Mn catalyst. ACS Catalysis, 2021, 11(13): 8358–8369

DOI

14
Andérez-Fernández M, Vogt L K, Fischer S. . A stable manganese pincer catalyst for the selective dehydrogenation of methanol. Angewandte Chemie International Edition, 2017, 56(2): 559–562

DOI

15
Anderson N H, Boncella J, Tondreau A M. Manganese-mediated formic acid dehydrogenation. Chemistry—A European Journal, 2019, 25(45): 10557–10560

DOI

16
Léval A, Agapova A, Steinlechner C. . Hydrogen production from formic acid catalyzed by a phosphine free manganese complex: investigation and mechanistic insights. Green Chemistry, 2020, 22(3): 913–920

DOI

17
Wei D, Sang R, Sponholz P. . Reversible hydrogenation of carbon dioxide to formic acid using a Mn-pincer complex in the presence of lysine. Nature Energy, 2022, 7(5): 438–447

DOI

18
Filonenko G A, van Putten R, Schulpen E N. . Highly efficient reversible hydrogenation of carbon dioxide to formates using a ruthenium PNP-pincer catalyst. ChemCatChem, 2014, 6(6): 1526–1530

DOI

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