A comprehensive study of hydrogen production from ammonia borane via PdCoAg/AC nanoparticles and anodic current in alkaline medium: experimental design with response surface methodology
Received date: 31 Oct 2019
Accepted date: 31 Jan 2020
Published date: 15 Sep 2020
Copyright
In this paper, the optimization of hydrogen (H2) production by ammonia borane (NH3BH3) over PdCoAg/AC was investigated using the response surface methodology. Besides, the electro-oxidation of NH3BH3 was determined and optimized using the same method to measure its potential use in the direct ammonium boran fuel cells. Moreover, the ternary alloyed catalyst was synthesized using the chemical reduction method. The synergistic effect between Pd, Co and Ag plays an important role in enhancement of NH3BH3 hydrolysis. In addition, the support effect could also efficiently improve the catalytic performance. Furthermore, the effects of NH3BH3 concentration (0.1–50 mmol/5 mL), catalyst amount (1–30 mg) and temperature (20°C–50°C) on the rate of H2 production and the effects of temperature (20°C–50°C), NH3BH3 concentration (0.05–1 mol/L) and catalyst amount (0.5–5 µL) on the electro-oxidation reaction of NH3BH3 were investigated using the central composite design experimental design. The implementation of the response surface methodology resulted in the formulation of four models out of which the quadratic model was adjudged to efficiently appropriate the experimental data. A further statistical analysis of the quadratic model demonstrated the significance of the model with a p-value far less than 0.05 for each model and coefficient of determination (R2) of 0.85 and 0.95 for H2 production rate and NH3BH3 electrroxidation peak current, respectively.
Hilal ÇELİK KAZICI , Şakir YILMAZ , Tekin ŞAHAN , Fikret YILDIZ , Ömer Faruk ER , Hilal KIVRAK . A comprehensive study of hydrogen production from ammonia borane via PdCoAg/AC nanoparticles and anodic current in alkaline medium: experimental design with response surface methodology[J]. Frontiers in Energy, 2020 , 14(3) : 578 -589 . DOI: 10.1007/s11708-020-0808-7
1 |
Andrews J, Shabani B. Re-envisioning the role of hydrogen in a sustainable energy economy. International Journal of Hydrogen Energy, 2012, 37(2): 1184–1203
|
2 |
Tiwari A, Pandey A. Cyanobacterial hydrogen production—a step towards clean environment. International Journal of Hydrogen Energy, 2012, 37(1): 139–150
|
3 |
Moriarty P, Honnery D. Hydrogen’s role in an uncertain energy future. International Journal of Hydrogen Energy, 2009, 34(1): 31–39
|
4 |
Acar C, Dincer I. Comparative assessment of hydrogen production methods from renewable and non-renewable sources. International Journal of Hydrogen Energy, 2014, 39(1): 1–12
|
5 |
Dincer I, Acar C. Review and evaluation of hydrogen production methods for better sustainability. International Journal of Hydrogen Energy, 2015, 40(34): 11094–11111
|
6 |
Ball M, Weeda M. The hydrogen economy–vision or reality? International Journal of Hydrogen Energy, 2015, 40(25): 7903–7919
|
7 |
Meeks N D, Baxley S. Fuel cells and the hydrogen economy. Chem Eng Prog, 2016, 112(7): 34–37
|
8 |
Granovskii M, Dincer I, Rosen M A. Economic and environmental comparison of conventional, hybrid, electric and hydrogen fuel cell vehicles. Journal of Power Sources, 2006, 159(2): 1186–1193
|
9 |
Van Mierlo J, Maggetto G, Lataire P. Which energy source for road transport in the future? A comparison of battery, hybrid and fuel cell vehicles. Energy Conversion Management, 2006, 47(17): 2748–2760
|
10 |
Wang Y, Meng W, Wang D, Wang Z R, Zou K L, Cao Z Q, Zhang K, Wu S W, Li G D. Ultrafine cobalt-molybdenum-boron nanocatalyst for enhanced hydrogen generation property from the hydrolysis of ammonia borane. International Journal of Hydrogen Energy, 2019, 44(41): 23267–23276
|
11 |
Appleby A J. Fuel cell technology: status and future prospects. Energy, 1996, 21(7–8): 521–653
|
12 |
Amendola S C, Sharp-Goldman S L, Janjua M S, Kelly M T, Petillo P J, Binder M. An ultrasafe hydrogen generator: aqueous, alkaline borohydride solutions and Ru catalyst. Journal of Power Sources, 2000, 85(2): 186–189
|
13 |
Miesse C M, Jung W S, Jeong K J, Lee J K, Lee J, Han J, Yoon S P, Nam S W, Lim T H, Hong S A. Direct formic acid fuel cell portable power system for the operation of a laptop computer. Journal of Power Sources, 2006, 162(1): 532–540
|
14 |
Dillon R, Srinivasan S, Arico A S, Antonucci V. International activities in DMFC R&D: status of technologies and potential applications. Journal of Power Sources, 2004, 127(1–2): 112–126
|
15 |
Zadick A, Dubau L, Artyushkova K, Serov A, Atanassov P, Chatenet M. Nickel-based electrocatalysts for ammonia borane oxidation: enabling materials for carbon-free-fuel direct liquid alkaline fuel cell technology. Nano Energy, 2017, 37: 248–259
|
16 |
Wu D F, Ouyang L Z, Huang J M, Liu J W, Wang H, Shao H, Zhu M. Synthesis and hydrogen storage property tuning of fit Zr(BH4)4. 8NH3 via physical vapour deposition and composite formation. International Journal of Hydrogen Energy, 2018, 43(41): 19182–19188
|
17 |
Zhang X B, Yan J M, Han S, Shioyama H, Yasuda K, Kuriyama N, Xu Q. A high performance anion exchange membrane-type ammonia borane fuel cell. Journal of Power Sources, 2008, 182(2): 515–519
|
18 |
Zhang X B, Han S, Yan J M, Chandra M, Shioyama H, Yasuda K, Kuriyama N, Kobayashi T, Xu Q. A new fuel cell using aqueous ammonia-borane as the fuel. Journal of Power Sources, 2007, 168(1): 167–171
|
19 |
Ouyang L Z, Chen W, Liu J W, Felderhoff M, Wang H, Zhu M. Enhancing the regeneration process of consumed NaBH4 for hydrogen storage. Advanced Energy Mater, 2017, 7(19): 1700299
|
20 |
Chen W, Ouyang L Z, Liu J W, Yao X D, Wang H, Liu Z W, Zhu M. Hydrolysis and regeneration of sodium borohydride (NaBH4): a combination of hydrogen production and storage. Journal of Power Sources, 2017, 359: 400–407
|
21 |
Hua T Q, Ahluwalia R K. Off-board regeneration of ammonia borane for use as a hydrogen carrier for automotive fuel cells. International Journal of Hydrogen Energy, 2012, 37(19): 14382–14392
|
22 |
Rees N V, Compton R G. Carbon-free energy: a review of ammonia- and hydrazine-based electrochemical fuel cells. Energy & Environmental Science, 2011, 4(4): 1255–1260
|
23 |
Tan Z H, Ouyang L Z, Liu J W, Wang H, Shao H Y, Zhu M. Hydrogen generation by hydrolysis of Mg-Mg2Si composite and enhanced kinetics performance from introducing of MgCl2 and Si. International Journal of Hydrogen Energy, 2018, 43(5): 2903–2912
|
24 |
Chandra M, Xu Q. A high-performance hydrogen generation system: transition metal-catalyzed dissociation and hydrolysis of ammonia-borane. Journal of Power Sources, 2006, 156(2): 190–194
|
25 |
Li X G, Liu T, Sato M, Takahashi S. Synthesis and characterization of Fe-Ti nanoparticles by nitrogen plasma metal reaction. Powder Technology, 2006, 163(3): 183–187
|
26 |
Rakap M, Kalu E E, Ozkar S. Polymer-immobilized palladium supported on TiO2 (Pd-PVB-TiO2) as highly active and reusable catalyst for hydrogen generation from the hydrolysis of unstirred ammonia-borane solution. International Journal of Hydrogen Energy, 2011, 36(2): 1448–1455
|
27 |
Sahiner N, Ozay O, Aktas N, Inger E, He J B. The on demand generation of hydrogen from Co-Ni bimetallic nano catalyst prepared by dual use of hydrogel: as template and as reactor. International Journal of Hydrogen Energy, 2011, 36(23): 15250–15258
|
28 |
Yuzawa H, Yoshida T, Yoshida H. Gold nanoparticles on titanium oxide effective for photocatalytic hydrogen formation under visible light. Applied Catalysis B: Environmental, 2012, 115–116: 294–302
|
29 |
Turhan T, Avcibasi Y G, Sahiner N. Versatile p(3-sulfopropyl methacrylate) hydrogel reactor for the preparation of Co, Ni nanoparticles and their use in hydrogen production. Journal of Industrial and Engineering Chemistry, 2013, 19(4): 1218–1225
|
30 |
Tong D G, Han X, Chu W, Chen H, Ji X Y. Preparation of mesoporous Co-B catalyst via self-assembled triblock copolymer templates. Materials Letters, 2007, 61(25): 4679–4682
|
31 |
Sahiner N, Sagbas L. The use of poly(vinyl phosphonic acid) microgels for the preparation of inherently magnetic Co metal catalyst particles in hydrogen production. Journal of Power Sources, 2014, 246: 55–62
|
32 |
Yao Q L, Lu Z H, Yang Y W, Chen Y Z, Chen X S, Jiang H L. Facile synthesis of graphene-supported Ni-CeOx nano-composites as highly efficient catalysts for hydrolytic dehydrogenation of ammonia borane. Nano Research, 2018, 11(8): 4412–4422
|
33 |
Choi S M, Seo M H, Kim H, Kim W B. Synthesis and characterization of graphene-supported metal nanoparticles by impregnation method with heat treatment in H2 atmosphere. Synthetic Metals, 2011, 161(21–22): 2405–2411
|
34 |
Ozay O, Aktas N, Inger E, Sahiner N. Hydrogel assisted nickel nanoparticle synthesis and their use in hydrogen production from sodium boron hydride. International Journal of Hydrogen Energy, 2011, 36(3): 1998–2006
|
35 |
Fernandes R, Patel N, Miotello A. Hydrogen generation by hydrolysis of alkaline NaBH4 solution with Cr-promoted Co-B amorphous catalyst. Applied Catalysis B: Environmental, 2009, 92(1–2): 68–74
|
36 |
Wang S, Zhang D, Ma Y Y, Zhang H, Gao J, Nie Y T, Sun X H. Aqueous solution synthesis of Pt-M (M= Fe, Co, Ni) bimetallic nanoparticles and their catalysis for the hydrolytic dehydrogenation of ammonia borane. ACS Applied Materials & Interfaces, 2014, 6(15): 12429–12435
|
37 |
Tano T, Esumi K, Meguro K. Preparation of organopalladium sols by thermal-decomposition of palladium acetate. Journal of Colloid and Interface Science, 1989, 133(2): 530–533
|
38 |
Bezerra M A, Santelli R E, Oliveira E P, Villar L S, Escaleira L A. Response surface methodology (RSM) as a tool for optimization in analytical chemistry. Talanta, 2008, 76(5): 965–977
|
39 |
Ling Z, Cao J, Zhang W, Zhang Z, Fang X, Gao X. Compact liquid cooling strategy with phase change materials for Li-ion batteries optimized using response surface methodology. Applied Energy, 2018, 228: 777–788
|
40 |
Yılmaz Ş, Ecer Ü, Şahan T. Modelling and optimization of As(III) adsorption onto thiol-functionalized bentonite from aqueous solutions using response surface methodology approach. ChemistrySelect, 2018, 3(32): 9326–9335
|
41 |
Çelik Kazici H, Yildiz F, İzgi M S, Ulaş B, Kivrak H. Novel activated carbon supported trimetallic PdCoAg nanoparticles as efficient catalysts for the hydrolytic dehydrogenation of ammonia borane. International Journal of Hydrogen Energy, 2019, 44(21): 10561–10572
|
42 |
Şahan T, Erol F, Yılmaz Ş. Mercury(II) adsorption by a novel adsorbent mercapto-modified bentonite using ICP-OES and use of response surface methodology for optimization. Microchemical Journal, 2018, 138: 360–368
|
43 |
Hitit Z Y, Lazaro C Z, Hallenbeck P C. Hydrogen production by co-cultures of Clostridium butyricum and Rhodospeudomonas palustris: optimization of yield using response surface methodology. International Journal of Hydrogen Energy, 2017, 42(10): 6578–6589
|
44 |
Zhang X B, Han S, Yan J M, Shioyama H, Kuriyama N, Kobayashi T, Xu Q. Electrochemical oxidation of ammonia borane on gold electrode. International Journal of Hydrogen Energy, 2009, 34(1): 174–179
|
45 |
Smiljanić M, Srejic I, Potocnik J, Mitric M, Rakocevic Z, Strbac S. Synergistic electrocatalytic effect of Pd and Rh nanoislands co-deposited on Au(poly) on HER in alkaline solution. International Journal of Hydrogen Energy, 2018, 43(42): 19420–19431
|
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