RESEARCH ARTICLE

Potential hybrid feedstock for biodiesel production in the tropics

  • Solomon GIWA ,
  • Oludaisi ADEKOMAYA ,
  • Collins NWAOKOCHA
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  • Department of Agricultural and Mechanical Engineering, College of Engineering and Environmental Studies, Olabisi Onabanjo University, Ibogun Campus, Ifo 234039, Nigeria

Received date: 24 Jul 2015

Accepted date: 06 Nov 2015

Published date: 07 Sep 2016

Copyright

2016 Higher Education Press and Springer-Verlag Berlin Heidelberg

Abstract

Recently, mixture of different oils at various proportions have been used as feedstock for biodiesel production. The primary aim is to improve fuel properties which are strongly influenced by the fatty acid composition of the individual oil that makes up the feedstock mix. The tropics are renowned for abundant oil-bearing crops of which palm kernel oil (PKO) from palm seed and groundnut oil (GNO) are prominent. This present paper investigated biodiesel production from hybrid oil (HO) of PKO (medium carbon chain and highly saturated oil) and GNO (long carbon chain and highly unsaturated oil) at 50/50 (v/v) blending. The principal fatty acids (FAs) in the HO are oleic (35.62%) and lauric acids (24.23%) with 47.80% of saturated FA and 52.26% of unsaturated FA contents. The chemical conversion of the oil to methyl ester (ME) gave 86.56% yield. Fuel properties of hybrid oil methyl ester (the HOME) were determined in accordance with standard test methods and were found to comply with both ASTM D6751 and EN 14214 standards. The oxidative stability, cetane number and kinematic viscosity (KV) of HOME were observed to be improved when compared with those of GNO methyl ester from single parent oil, which could be accredited to the improved FA composition of the HO. The KV (3.69 mm2/s) of HOME obtained in this paper was remarkably low compared with those reported in literature for most biodiesels. This value suggests better flow, atomization, spray and combustion of this fuel. Conclusively, the binary blend of oils can be a viable option to improve the fuel properties of biodiesel feedstock coupled with reduced cost.

Cite this article

Solomon GIWA , Oludaisi ADEKOMAYA , Collins NWAOKOCHA . Potential hybrid feedstock for biodiesel production in the tropics[J]. Frontiers in Energy, 2016 , 10(3) : 329 -336 . DOI: 10.1007/s11708-016-0408-8

1
Balat M, Balat H. Progress in biodiesel processing. Applied Energy, 2010, 87(6): 1815–1835

DOI

2
Giwa S, Ogunbona C. Sweet almond (Prunus amygdalus “dulcis”) seeds as a potential feedstock for Nigerian biodiesel automotive project. Revista Ambiente & Agua, 2014, 9: 37–45

3
Wakil M A, Kalam M A, Masjuki H H, Atabani A E, Rizwanul Fattah I M. Influence of biodiesel blending on physicochemical properties and importance of mathematical model for predicting the properties of biodiesel blend. Energy Conversion and Management, 2015, 94: 51–67

DOI

4
Kondamudi N, Strull J, Misra M, Mohapatra S K. A green process for producing biodiesel from feather meal. Journal of Agricultural and Food Chemistry, 2009, 57(14): 6163–6166

DOI

5
Li Q, Zheng L, Cai H, Garza E, Yu Z, Zhou S. From organic waste to biodiesel: black soldier fly, Hermetia illucens, makes it feasible. Fuel, 2011, 90(4): 1545–1548

DOI

6
Mariod A, Klupsch S, Hussein I H, Ondruschka B. Synthesis of alkyl esters from three unconventional Sudanese oils for their use as biodiesel. Energy & Fuels, 2006, 20(5): 2249–2252

DOI

7
Lin C, Li R. Fuel properties of biodiesel produced from the crude fish oil from the soapstock of marine fish. Fuel Processing Technology, 2009, 90(1): 130–136

DOI

8
Alptekin E, Canakci M, Sanli H. Evaluation of leather industry wastes as a feedstock for biodiesel production. Fuel, 2012, 95: 214–220

DOI

9
Giwa S, Layeni A, Ogunbona C. Synthesis and characterization of biodiesel from industrial starch production byproduct. Energy and Environmental Engineering Journal, 2012, 1: 45–51

10
Cao L, Zhang S. Production and characterization of biodiesel derived from Hodgsonia macrocarpa seed oil. Applied Energy, 2015, 146: 135–140

DOI

11
Giwa S, Abdullah L C, Adam N M. Investigating “egusi” (Citrullus Colocynthis L.) seed oil as potential biodiesel feedstock. Energies, 2010, 3(4): 607–618

DOI

12
Meneghetti S M P, Meneghetti M R, Serra T M, Barbosa D C, Wolf C R. Biodiesel production from vegetable oil mixture: cottonseed, soybean, and castor oil. Energy & Fuels, 2007, 21(6): 3746–3747

DOI

13
Moser B R. Influence of blending canola, palm, soybean, and sunflower oil methyl esters on fuel properties of biodiesel. Energy & Fuels, 2008, 22(6): 4301–4306

DOI

14
Taravus S, Temur H, Yartasi A. Alkali-catalyzed biodiesel production from mixtures of sunflower oil and beef tallow. Energy & Fuels, 2009, 23(8): 4112–4115

DOI

15
Chen Y H, Chen J H, Chang C Y, Chang C C. Biodiesel production from tung (Vernicia montana) oil and its blending properties in different fatty acid compositions. Bioresource Technology, 2010, 101(24): 9521–9526

DOI

16
Serqueira D S, Fernandes D M, Cunha R R, Squissato A L, Santos D Q, Richter E M, Munoz R A A. Influence of blending soybean, sunflower, colza, corn, cottonseed, and residual cooking oil methyl biodiesels on the oxidation stability. Fuel, 2014, 118: 16–20

DOI

17
Lebedevas S, Vaicekauskas A, Lebedeva G, Makareviciene V, Janulis P, Kazancev K. Use of waste fats of animal and vegetable origin for the production of biodiesel fuel: quality, motor properties, and emissions of harmful components. Energy & Fuels, 2006, 20(5): 2274–2280

DOI

18
de Almeida V F, García-Moreno P J, Guadix A, Guadix E M. Biodiesel production from mixtures of waste fish oil, palm oil and waste frying oil: optimization of fuel properties. Fuel Processing Technology, 2015, 133: 152–160

DOI

19
Freire L M S, Filho J R C, Moura C V R, Soledade L E B, Stragevitch L, Cordeiro A M T M, Santos I M G, Souza A G. Evaluation of the oxidative stability and flow properties of quaternary mixtures of vegetable oils for biodiesel production. Fuel, 2012, 95: 126–130

DOI

20
Sharma Y C, Singh B. A hybrid feedstock for a very efficient preparation of biodiesel. Fuel Processing Technology, 2010, 91(10): 1267–1273

DOI

21
Qiu F, Li Y, Yang D, Li X, Sun P. Biodiesel production from mixed soybean oil and rapeseed oil. Applied Energy, 2011, 88(6): 2050–2055

DOI

22
Chen Y H, Chen J H, Luo Y M. Complementary biodiesel combination from tung and medium-chain fatty acid oils. Renewable Energy, 2012, 44: 305–310

DOI

23
Eze S O O. Physico-chemical properties of oil from some selected underutilized oil seeds available for biodiesel preparation. African Journal of Biotechnology, 2012, 11: 10003–10007

24
Alamu O J, Waheed M A, Jekayinfa S O, Akintola T A. Optimal transesterification duration for biodiesel production from Nigerian palm kernel oil. Agricultural Engineering International CIGR E-Journal, 2007, 9: 1–11

25
Kaya C, Hamamci C, Baysal A, Akba O, Erdogan S, Saydut A. Methyl ester of peanut (Arachis hypogea L.) seed oil as a potential feedstockfor biodiesel production. Renewable Energy, 2009, 34(5): 1257–1260

DOI

26
Ibeto C N, Ofoefule A U, Ezeugwu H C. Fuel quality assessment of biodiesel produced from groundnut oil (Arachis hypogea L.) and its blend with petroleum diesel. American Journal Food Technology, 2011, 6(9): 798–803

DOI

27
Moser B R. Biodiesel production, properties, and feedstocks. In Vitro Cell Dev. Biology-Plant, 2009, 45: 229–266

28
Oyinlola A, Ojo A, Adekoya L O. Development of a laboratory model screw press for peanut oil expression. Journal of Food Engineering, 2004, 64(2): 221–227

DOI

29
Srivastava A, Prasad R. Triglycerides-based diesel fuels. Renewable & Sustainable Energy Reviews, 2000, 4(2): 111–133

DOI

30
Ramos M J, Fernandez C M, Casas A, Rodriguez L, Perez A. Influence of fatty acid composition of raw materials on biodiesel properties. Bioresource Technology, 2009, 100(1): 261–268

DOI

31
Ahmad M, Rashid S, Khan M A, Zafar M, Sultana S, Gulzar S. Optimization of base catalyzed transesterification of peanut oil biodiesel. African Journal of Biotechnology, 2009, 8: 441–446

32
Gerpen J V. Biodiesel processing and production. Fuel Processing Technology, 2005, 86(10): 1097–1107

DOI

33
Saloua F, Saber C, Hedi Z. Methyl ester of [Maclura pomifera (Rafin.) Schneider] seed oil: Biodiesel production and characterization. Bioresource Technology, 2010, 101(9): 3091–3096

DOI

34
Atapour M, Kariminia H. Characterization and transesterification of Iranian bitter almond oil for biodiesel production. Applied Energy, 2011, 88(7): 2377–2381

DOI

35
Rashid U, Anwar F, Ansari T M, Arif M, Ahmad M. Optimization of alkaline transesterification of rice bran oil for biodiesel production using response surface methodology. Journal of Chemical Technology and Biotechnology (Oxford, Oxfordshire), 2009, 84(9): 1364–1370

DOI

36
Knothe G, Cermak C S, Evangelista R L. Cuphea oil as source of biodiesel with improved fuel properties caused by high content of methyl decanoate. Energy & Fuels, 2009, 23(3): 1743–1747

DOI

37
Usta N. Use of tobacco seed oil methyl ester in a turbocharged indirect injection diesel engine. Biomass and Bioenergy, 2005, 28: 77–86

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