Exploring 2D perovskite chemistry for advancing efficient and stable solar cells

Abstract

Perovskite-based photovoltaic devices have garnered significant interest owing to their remarkable performance in converting light into electricity. Recently, the focus in the field of perovskite solar cells (PSCs) has shifted towards enhancing their durability over extended periods. One promising strategy is the incorporation of two-dimensional (2D) perovskites, known for their ability to enhance stability due to the large organic cations that act as a barrier against moisture. However, the broad optical bandgap and limited charge transport properties of 2D perovskites hinder their efficiency, making them less suitable as the sole light-absorbing material when compared to their three-dimensional (3D) counterparts. An innovative approach involves using 2D perovskite structures to modify the surface properties of 3D perovskite. This hybrid approach, known as 2D/3D perovskites, while enhancing their performance. Beyond solar energy applications, 2D perovskites offer a flexible platform for chemical engineering, allowing for significant adjustments to crystal and thin-film configurations, bandgaps, and charge transport properties through the different organic ligands and halide mixtures. Despite these advantages, challenges remain in integration of 2D perovskites into solar cells without compromising device stability. This review encapsulates the latest developments in 2D perovskite research, focusing on their structural, optoelectronic, and stability attributes, while delving into the challenges and future potential of these materials.

Graphical abstract

Keywords

two-dimensional (2D) perovskites / crystal structure / thin film structure / optoelectronic properties / stability / perovskite solar cells (PSCs)

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