Generation of enhanced stability of SnO/In(OH)₃/InP for photocatalytic water splitting by SnO protection layer¹

Abstract

InP shows a very high efficiency for solar light to electricity conversion in solar cell and may present an expectation property in photocatalytic hydrogen evolution. However, it suffers serious corrosion in water dispersion. In this paper, it is demonstrated that the stability and activity of the InP-based catalyst are effectively enhanced by applying an anti-corrosion SnO layer and In(OH)₃ transition layer, which reduces the crystal mismatch between SnO and InP and increases charge transfer. The obtained Pt/SnO/In(OH)₃/InP exhibits a hydrogen production rate of 144.42 µmol/g in 3 h under visible light illumination in multi-cycle tests without remarkable decay, 123 times higher than that of naked In(OH)₃/InP without any electron donor under visible irradiation.

Graphical abstract

Keywords

SnO/In(OH)₃/InP photocatalyst / enhanced activity and stability for water splitting / corrosion inhibition / enhancing charge transfer and decreasing crystal mismatch

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Electronic Supplementary Material

Supplementary material is available in the online version of this article at https://doi.org/10.1007/s11708-021-0764-x and is accessible for authorized users.

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