Hydrogel photocatalysts for efficient energy conversion and environmental treatment
Wenwei LEI, Norihiro SUZUKI, Chiaki TERASHIMA, Akira FUJISHIMA
Hydrogel photocatalysts for efficient energy conversion and environmental treatment
Photocatalysts have attracted great research interest owing to their excellent properties and potential for simultaneously addressing challenges related to energy needs and environmental pollution. Photocatalytic particles need to be in contact with their respective media to exhibit efficient photocatalytic performances. However, it is difficult to separate nanometer-sized photocatalytic materials from reaction media later, which may lead to secondary pollution and a poor recycling performance. Hydrogel photocatalysts with a three-dimensional (3D) network structures are promising support materials for photocatalysts based on features such as high specific surface areas and adsorption capacities and good environmental compatibility. In this review, hydrogel photocatalysts are classified into two different categories depending on their elemental composition and recent progresses in the methods for preparing hydrogel photocatalysts are summarized. Moreover, current applications of hydrogel photocatalysts in energy conversion and environmental remediation are reviewed. Furthermore, a comprehensive outlook and highlight future challenges in the development of hydrogel photocatalysts are presented.
hydrogel / photocatalysts / energy conversion / environmental treatment
[1] |
Weaver P, Jansen L, van Grootveld G,
|
[2] |
Lewis N S. Research opportunities to advance solar energy utilization. Science, 2016, 351(6271): aad1920
CrossRef
Google scholar
|
[3] |
Tao P, Ni G, Song C,
CrossRef
Google scholar
|
[4] |
Chen C, Kuang Y, Hu L. Challenges and opportunities for solar evaporation. Joule, 2019, 3(3): 683–718
CrossRef
Google scholar
|
[5] |
Hosseini S E, Wahid M A. Hydrogen from solar energy, a clean energy carrier from a sustainable source of energy. International Journal of Energy Research, 2020, 44(6): 4110–4131
CrossRef
Google scholar
|
[6] |
Zhang Y, Ren J, Pu Y,
CrossRef
Google scholar
|
[7] |
Gong J, Li C, Wasielewski M R. Advances in solar energy conversion. Chemical Society Reviews, 2019, 48(7): 1862–1864
CrossRef
Google scholar
|
[8] |
Kannan N, Vakeesan D. Solar energy for future world: a review. Renewable & Sustainable Energy Reviews, 2016, 62: 1092–1105
CrossRef
Google scholar
|
[9] |
Wang Q, Hisatomi T, Jia Q,
CrossRef
Google scholar
|
[10] |
Ong W J, Tan L L, Ng Y H,
CrossRef
Google scholar
|
[11] |
Luo J, Zhang S, Sun M,
CrossRef
Google scholar
|
[12] |
Tian B, Tian B, Smith B,
CrossRef
Google scholar
|
[13] |
Zhang P, Lou X W D. Design of heterostructured hollow photocatalysts for solar-to-chemical energy conversion. Advanced Materials, 2019, 31(29): 1900281
CrossRef
Google scholar
|
[14] |
Dhiman P, Naushad M, Batoo K M,
CrossRef
Google scholar
|
[15] |
Tang X, Huang Z, Cao Y,
CrossRef
Google scholar
|
[16] |
Yi J, Liao J, Xia K,
CrossRef
Google scholar
|
[17] |
Fujishima A, Honda K. Electrochemical photolysis of water at a semiconductor electrode. Nature, 1972, 238(5358): 37–38
CrossRef
Google scholar
|
[18] |
Zhou W, Li W, Wang J,
CrossRef
Google scholar
|
[19] |
Hu Y. A highly efficient photocatalyst—hydrogenated black TiO2 for the photocatalytic splitting of water. Angewandte Chemie International Edition, 2012, 51(50): 12410–12412
CrossRef
Google scholar
|
[20] |
Naldoni A, Altomare M, Zoppellaro G,
CrossRef
Google scholar
|
[21] |
Liu N, Häublein V, Zhou X,
CrossRef
Google scholar
|
[22] |
Hsu C C, Wu N L. Synthesis and photocatalytic activity of ZnO/ZnO2 composite. Journal of Photochemistry and Photobiology A Chemistry, 2005, 172(3): 269–274
CrossRef
Google scholar
|
[23] |
Elmolla E S, Chaudhuri M. Degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution by the UV/ZnO photocatalytic process. Journal of Hazardous Materials, 2010, 173(1–3): 445–449
CrossRef
Google scholar
|
[24] |
Yu W, Zhang J, Peng T. New insight into the enhanced photocatalytic activity of N-, C- and S-doped ZnO photocatalysts. Applied Catalysis B: Environmental, 2016, 181: 220–227
CrossRef
Google scholar
|
[25] |
Tian C, Zhang Q, Wu A,
CrossRef
Google scholar
|
[26] |
Fu J, Yu J, Jiang C,
CrossRef
Google scholar
|
[27] |
Wen J, Xie J, Chen X,
CrossRef
Google scholar
|
[28] |
Ye L, Liu J, Jiang Z,
CrossRef
Google scholar
|
[29] |
Li Y, He R, Han P,
CrossRef
Google scholar
|
[30] |
Xu M, Han L, Dong S. Facile fabrication of highly efficient g-C3N4/Ag2O heterostructured photocatalysts with enhanced visible-light photocatalytic activity. ACS Applied Materials & Interfaces, 2013, 5(23): 12533–12540
CrossRef
Google scholar
|
[31] |
Kato H, Kudo A. Visible-light-response and photocatalytic activities of TiO2 and SrTiO3 photocatalysts codoped with antimony and chromium. Journal of Physical Chemistry B, 2002, 106(19): 5029–5034
CrossRef
Google scholar
|
[32] |
Domen K, Kudo A, Onishi T. Mechanism of photocatalytic decomposition of water into H2 and O2 over NiOSrTiO3. Journal of Catalysis, 1986, 102(1): 92–98
CrossRef
Google scholar
|
[33] |
Iwashina K, Kudo A. Rh-doped SrTiO3 photocatalyst electrode showing cathodic photocurrent for water splitting under visible-light irradiation. Journal of the American Chemical Society, 2011, 133(34): 13272–13275
CrossRef
Google scholar
|
[34] |
Takata T, Jiang J, Sakata Y,
CrossRef
Google scholar
|
[35] |
Xu C, Ravi Anusuyadevi P, Aymonier C,
CrossRef
Google scholar
|
[36] |
Wei Z, Zhu Y, Guo W,
CrossRef
Google scholar
|
[37] |
Jiang Z, Huang Z, Guo W,
CrossRef
Google scholar
|
[38] |
Fang W, Jiang Z, Yu L,
CrossRef
Google scholar
|
[39] |
Li Y, Han P, Hou Y,
CrossRef
Google scholar
|
[40] |
Li Y, Hou Y, Fu Q,
CrossRef
Google scholar
|
[41] |
Meng A, Zhang L, Cheng B,
CrossRef
Google scholar
|
[42] |
Ran J, Zhang J, Yu J,
CrossRef
Google scholar
|
[43] |
Wang Q, Domen K. Particulate photocatalysts for light-driven water splitting: mechanisms, challenges, and design strategies. Chemical Reviews, 2020, 120(2): 919–985
CrossRef
Google scholar
|
[44] |
Nakata K, Fujishima A. TiO2 photocatalysis: design and applications. Journal of Photochemistry and Photobiology C, Photochemistry Reviews, 2012, 13(3): 169–189
CrossRef
Google scholar
|
[45] |
Chen H, Lee S W, Kim T H,
CrossRef
Google scholar
|
[46] |
Shang J, Li W, Zhu Y. Structure and photocatalytic characteristics of TiO2 film photocatalyst coated on stainless steel webnet. Journal of Molecular Catalysis A Chemical, 2003, 202(1–2): 187–195
CrossRef
Google scholar
|
[47] |
Carneiro J O, Teixeira V, Portinha A,
CrossRef
Google scholar
|
[48] |
Liu X, Chen Q, Lv L,
CrossRef
Google scholar
|
[49] |
Zhang R, Ma M, Zhang Q,
CrossRef
Google scholar
|
[50] |
Jiang W, Luo W, Zong R,
CrossRef
Google scholar
|
[51] |
Zhang Z, Xiao F, Guo Y,
CrossRef
Google scholar
|
[52] |
Mai N X D, Bae J, Kim I T,
CrossRef
Google scholar
|
[53] |
Im J S, Bai B C, In S J,
CrossRef
Google scholar
|
[54] |
Lei L, Wang W, Wang C,
CrossRef
Google scholar
|
[55] |
Lei W, Qi S, Rong Q,
CrossRef
Google scholar
|
[56] |
Xiang Q, Yu J, Jaroniec M. Graphene-based semiconductor photocatalysts. Chemical Society Reviews, 2012, 41(2): 782–796
CrossRef
Google scholar
|
[57] |
Mills A, Le Hunte S. An overview of semiconductor photocatalysis. Journal of Photochemistry and Photobiology A Chemistry, 1997, 108(1): 1–35
CrossRef
Google scholar
|
[58] |
Maeda K. Z-scheme water splitting using two different semiconductor photocatalysts. ACS Catalysis, 2013, 3(7): 1486–1503
CrossRef
Google scholar
|
[59] |
Wang H, Zhang L, Chen Z,
CrossRef
Google scholar
|
[60] |
Liu G, Yu J C, Lu G Q,
CrossRef
Google scholar
|
[61] |
Jing L, Qu Y, Wang B,
CrossRef
Google scholar
|
[62] |
Abe R, Sayama K, Sugihara H. Development of new photocatalytic water splitting into H2 and O2 using two different semiconductor photocatalysts and a shuttle redox mediator IO3−/I−. Journal of Physical Chemistry B, 2005, 109(33): 16052–16061
CrossRef
Google scholar
|
[63] |
Chen F, An W, Liu L,
CrossRef
Google scholar
|
[64] |
Liu C, Yue M, Liu L,
CrossRef
Google scholar
|
[65] |
Yun J, Jin D, Lee Y S,
CrossRef
Google scholar
|
[66] |
Sharma G, Kumar A, Sharma S,
CrossRef
Google scholar
|
[67] |
Thomas M, Naikoo G A, Sheikh M U D,
CrossRef
Google scholar
|
[68] |
Jiang W, Liu Y, Wang J,
CrossRef
Google scholar
|
[69] |
Chen Y, Xiang Z, Wang D,
CrossRef
Google scholar
|
[70] |
Chen X, Chen Q, Jiang W,
CrossRef
Google scholar
|
[71] |
Chen F, An W, Li Y,
CrossRef
Google scholar
|
[72] |
Hou C, Zhang Q, Li Y,
CrossRef
Google scholar
|
[73] |
Jiang R, Zhu H, Yao J,
CrossRef
Google scholar
|
[74] |
Kaur K, Jindal R. Comparative study on the behaviour of Chitosan-Gelatin based Hydrogel and nanocomposite ion exchanger synthesized under microwave conditions towards photocatalytic removal of cationic dyes. Carbohydrate Polymers, 2019, 207: 398–410
CrossRef
Google scholar
|
[75] |
Yang J, Gao J, Wang X,
CrossRef
Google scholar
|
[76] |
Zhu H, Li Z, Yang J. A novel composite hydrogel for adsorption and photocatalytic degradation of bisphenol A by visible light irradiation. Chemical Engineering Journal, 2018, 334: 1679–1690
CrossRef
Google scholar
|
[77] |
Yang J, Chen D, Zhu Y,
CrossRef
Google scholar
|
[78] |
Hashimoto K, Irie H, Fujishima A. TiO2 photocatalysis: a historical overview and future prospects. Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, 2005, 44(12): 8269–8285
CrossRef
Google scholar
|
[79] |
Fujishima A, Zhang X, Tryk D A. TiO2 photocatalysis and related surface phenomena. Surface Science Reports, 2008, 63(12): 515–582
CrossRef
Google scholar
|
[80] |
Schneider J, Matsuoka M, Takeuchi M,
CrossRef
Google scholar
|
[81] |
Guo Q, Zhou C, Ma Z,
CrossRef
Google scholar
|
[82] |
Leary R, Westwood A. Carbonaceous nanomaterials for the enhancement of TiO2 photocatalysis. Carbon, 2011, 49(3): 741–772
CrossRef
Google scholar
|
[83] |
Jiang Y, Ning H, Tian C,
CrossRef
Google scholar
|
[84] |
Zhang W, He H, Tian Y,
CrossRef
Google scholar
|
[85] |
Hu J, Xie J, Jia W,
CrossRef
Google scholar
|
[86] |
Li X, Shi J, Hao H,
CrossRef
Google scholar
|
[87] |
Qian R, Zong H, Schneider J,
CrossRef
Google scholar
|
[88] |
Yue Y, Wang X, Wu Q,
CrossRef
Google scholar
|
[89] |
Arikal D, Kallingal A. Photocatalytic degradation of azo and anthraquinone dye using TiO2/MgO nanocomposite immobilized chitosan hydrogels. Environmental Technology, 2019, online, doi:10.1080/09593330.2019.1701094
CrossRef
Google scholar
|
[90] |
Lučić M, Milosavljević N, Radetić M,
CrossRef
Google scholar
|
[91] |
Zhao K, Feng L, Lin H,
CrossRef
Google scholar
|
[92] |
Liu M, Ishida Y, Ebina Y,
CrossRef
Google scholar
|
[93] |
Liu J, Chen H, Shi X,
CrossRef
Google scholar
|
[94] |
Khan S, Kubota Y, Lei W,
CrossRef
Google scholar
|
[95] |
Wu Q, Huang F, Zhao M,
CrossRef
Google scholar
|
[96] |
Nowotny M K, Sheppard L R, Bak T,
CrossRef
Google scholar
|
[97] |
Elbanna O, Zhu M, Fujitsuka M,
CrossRef
Google scholar
|
[98] |
Su R, Ge S, Li H,
CrossRef
Google scholar
|
[99] |
Wang J, Li X, Cheng Q,
CrossRef
Google scholar
|
[100] |
Ding Y, Zhou Y, Nie W,
CrossRef
Google scholar
|
[101] |
Mu C, Zhang Y, Cui W,
CrossRef
Google scholar
|
[102] |
Qin L, Ru R, Mao J,
CrossRef
Google scholar
|
[103] |
Taghizadeh M T, de Siyahi V, Ashassi-Sorkhabi H,
CrossRef
Google scholar
|
[104] |
Chen S, Jacobs D L, Xu J,
CrossRef
Google scholar
|
[105] |
Chen S, Li Y, Wang C. Visible-light-driven photocatalytic H2 evolution from aqueous suspensions of perylene diimide dye-sensitized Pt/TiO2 catalysts. RSC Advances, 2015, 5(21): 15880–15885
CrossRef
Google scholar
|
[106] |
Chen S, Wang C, Bunes B R,
CrossRef
Google scholar
|
[107] |
Yang S, Gong Y, Zhang J,
CrossRef
Google scholar
|
[108] |
Wang Y, Wang X, Antonietti M. Polymeric graphitic carbon nitride as a heterogeneous organocatalyst: from photochemistry to multipurpose catalysis to sustainable chemistry. Angewandte Chemie International Edition, 2012, 51(1): 68–89
CrossRef
Google scholar
|
[109] |
Wang X, Maeda K, Chen X,
CrossRef
Google scholar
|
[110] |
Wang X, Maeda K, Thomas A,
CrossRef
Google scholar
|
[111] |
Hu C, Lin Y, Yang H C. Recent developments in graphitic carbon nitride based hydrogels as photocatalysts. ChemSusChem, 2019, 12(9): 1769–1806
CrossRef
Google scholar
|
[112] |
Jiang W, Zhu Y, Zhu G,
CrossRef
Google scholar
|
[113] |
Li J, Yu X, Zhu Y,
CrossRef
Google scholar
|
[114] |
Chu Y C, Lin T J, Lin Y,
CrossRef
Google scholar
|
[115] |
Liang Y, Wang X, An W,
CrossRef
Google scholar
|
[116] |
Hu J, Zhang P, Cui J,
CrossRef
Google scholar
|
[117] |
Liu G, Li T, Song X,
CrossRef
Google scholar
|
[118] |
Zhang G, Lan Z, Wang X. Conjugated polymers: catalysts for photocatalytic hydrogen evolution. Angewandte Chemie International Edition, 2016, 55(51): 15712–15727
CrossRef
Google scholar
|
[119] |
Wang X, Chen L, Chong S Y,
CrossRef
Google scholar
|
[120] |
Liu D, Wang J, Bai X,
CrossRef
Google scholar
|
[121] |
Cohen E, Weissman H, Pinkas I,
CrossRef
Google scholar
|
[122] |
Chen S, Slattum P, Wang C,
CrossRef
Google scholar
|
[123] |
Krieg E, Bastings M M C, Besenius P,
CrossRef
Google scholar
|
[124] |
Singh P, Mittal L S, Vanita V,
CrossRef
Google scholar
|
[125] |
Zhang Z, Chen X, Zhang H,
CrossRef
Google scholar
|
[126] |
Weingarten A S, Kazantsev R V, Palmer L C,
CrossRef
Google scholar
|
[127] |
Weingarten A S, Kazantsev R V, Palmer L C,
CrossRef
Google scholar
|
[128] |
Sai H, Erbas A, Dannenhoffer A,
CrossRef
Google scholar
|
[129] |
Byun J, Landfester K, Zhang K. Conjugated polymer hydrogel photocatalysts with expandable photoactive sites in water. Chemistry of Materials, 2019, 31(9): 3381–3387
CrossRef
Google scholar
|
[130] |
Li F, Yang J, Gao J,
CrossRef
Google scholar
|
[131] |
Luna A L, Matter F, Schreck M,
CrossRef
Google scholar
|
[132] |
Jiang Z, Zhang X, Yang G,
CrossRef
Google scholar
|
[133] |
Yu J, Low J, Xiao W,
CrossRef
Google scholar
|
[134] |
Habisreutinger S N, Schmidt-Mende L, Stolarczyk J K. Photocatalytic reduction of CO2 on TiO2 and other semiconductors. Angewandte Chemie International Edition, 2013, 52(29): 7372–7408
CrossRef
Google scholar
|
[135] |
Ran J, Jaroniec M, Qiao S. Cocatalysts in semiconductor-based photocatalytic CO2 reduction: achievements, challenges, and opportunities. Advanced Materials, 2018, 30(7): 1704649
CrossRef
Google scholar
|
[136] |
Bie C, Zhu B, Xu F,
CrossRef
Google scholar
|
[137] |
Fu J, Jiang K, Qiu X,
CrossRef
Google scholar
|
[138] |
Jung H, Cho K M, Kim K H,
CrossRef
Google scholar
|
[139] |
Rechberger F, Niederberger M. Translucent nanoparticle-based aerogel monoliths as 3-dimensional photocatalysts for the selective photoreduction of CO2 to methanol in a continuous flow reactor. Materials Horizons, 2017, 4(6): 1115–1121
CrossRef
Google scholar
|
[140] |
Godiya C B, Martins Ruotolo L A, Cai W. Functional biobased hydrogels for the removal of aqueous hazardous pollutants: current status, challenges, and future perspectives. Journal of Materials Chemistry A, Materials for Energy and Sustainability, 2020, 8(41): 21585–21612
CrossRef
Google scholar
|
[141] |
Jing G, Wang L, Yu H,
CrossRef
Google scholar
|
[142] |
Mohammadzadeh Pakdel P, Peighambardoust S J. A review on acrylic based hydrogels and their applications in wastewater treatment. Journal of Environmental Management, 2018, 217: 123–143
CrossRef
Google scholar
|
[143] |
Zhang M, Luo W, Wei Z,
CrossRef
Google scholar
|
[144] |
Zhang M, Jiang W, Liu D,
CrossRef
Google scholar
|
[145] |
Yang J, Li Z, Zhu H. Adsorption and photocatalytic degradation of sulfamethoxazole by a novel composite hydrogel with visible light irradiation. Applied Catalysis B: Environmental, 2017, 217: 603–614
CrossRef
Google scholar
|
[146] |
Hua M, Zhang S, Pan B,
CrossRef
Google scholar
|
[147] |
Fu F, Wang Q. Removal of heavy metal ions from wastewaters: a review. Journal of Environmental Management, 2011, 92(3): 407–418
CrossRef
Google scholar
|
[148] |
Tahir M B, Kiran H, Iqbal T. The detoxification of heavy metals from aqueous environment using nano-photocatalysis approach: a review. Environmental Science and Pollution Research International, 2019, 26(11): 10515–10528
CrossRef
Google scholar
|
[149] |
Li Y, Cui W, Liu L,
CrossRef
Google scholar
|
[150] |
Guo Y, Bae J, Fang Z,
CrossRef
Google scholar
|
[151] |
Zhou X, Guo Y, Zhao F,
CrossRef
Google scholar
|
[152] |
Zhou X, Zhao F, Guo Y,
CrossRef
Google scholar
|
[153] |
Zhao F, Zhou X, Shi Y,
CrossRef
Google scholar
|
[154] |
Lei W, Khan S, Chen L,
CrossRef
Google scholar
|
[155] |
Gao M, Peh C K, Zhu L,
CrossRef
Google scholar
|
[156] |
Yang M, Tan C, Lu W,
CrossRef
Google scholar
|
/
〈 | 〉 |