Investigation of Cu leaching from municipal solid waste incinerator bottom ash with a comprehensive approach

Abstract

Municipal solid waste incinerator (MSWI) bottom ash is often reused as a secondary construction material. This study used a comprehensive approach to characterize the leaching behavior of copper (Cu) from the MSWI bottom ash. The batch titration procedure was used to determine the acid neutralizing capacity and Cu leaching as a function of pH. The sequential extraction procedure (SEP) was adopted to analyze the speciation of Cu in the MSWI bottom ash. The metal speciation equilibrium model for surface and ground water (Visual MINTEQ) was used to evaluate the equilibrium of the leachates with the relative minerals, and to determine the speciation of the aqueous Cu in the leachates. Based on the multi-analysis of the results, Cu would be significantly released from the MSWI bottom ash when it is acidic. The Cu leaching pattern was not only affected by dissolved organic carbon, it was also limited by its speciation in the MSWI bottom ash. Furthermore, almost 100% of the aqueous Cu in the leachate was bound to organic matter in basic and neutral conditions, but mostly existed as Cu²⁺ in an acidic condition. These findings provide an important insight into predicting the leaching behavior of Cu from the MSWI bottom ash, as well as its impact on the environment.

Keywords

MSWI bottom ash / Cu leaching / batch titration procedure / SEP

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Acknowledgements

This work was financially supported by the Innovative Research Team in Higher Educational Institutions of Zhejiang Province (No. T200912) and Significant Science and Technology Project of Zhejiang Province (Nos. 2008C13024-2, 2009C03007-1 and No. 2009C03007-2).

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