Construction of MOFs-based nanocomposite membranes for emerging organic contaminants abatement in water

Abstract

● Application of the MOF-composite membranes in adsorption was discussed.

● Recent application of MOFs-membranes for separation was summarized.

● Separation and degradation for emerging organic contaminants were described.

Presence of emerging organic contaminants (EOCs) in water is one of the major threats to water safety. In recent decades, an increasing number of studies have investigated new approaches for their effective removal. Among them, metal-organic frameworks (MOFs) have attracted increasing attention since their first development thanks to their tunable metal nodes and versatile, functional linkers. However, whether or not MOFs have a promising future for practical application in emerging contaminants-containing wastewater is debatable. This review summarizes recent studies about the removal of EOCs using MOFs-related material. The synthesis strategies of both MOF particles and composites, including thin-film nanocomposite and mixed matrix membranes, are critically reviewed, as well as various characterization technologies. The application of the MOF-based composite membranes in adsorption, separation (nanofiltration and ultrafiltration), and catalytic degradation are discussed. Overall, literature survey shows that MOFs-based composite could play a crucial role in eliminating EOCs in the future. In particular, modified membranes that realize separation and degradation might be the most promising materials for such application.

Graphical abstract

Keywords

Emerging organic contaminants / Metal organic frameworks / Synthesis / Adsorption / Catalysis

References

[1] Ahmadijokani F , Molavi H , Bahi A , Fernández R , Alaee P , Wu S , Wuttke S , Ko F , Arjmand M . (2022). Metal-organic frameworks and electrospinning: a happy marriage for wastewater treatment. Advanced Functional Materials, 32(51): 2207723

[2] AhmedMMavukkandyM OGiwaAElektorowiczMKatsouEKhelifiONaddeoVHasanS W (2022). Recent developments in hazardous pollutants removal from wastewater and water reuse within a circular economy. npj Clean Water, 5(12): doi.org/10.1038/s41545–022-01545–022

[3] Al-ShaeliMSmithS J DJiangSWangHZhangKLadewigB P (2021). Long-term stable metal organic framework (MOF) based mixed matrix membranes for ultrafiltration. Journal of Membrane Science, 635(1–2): 119339

[4] Amarajothi D , Li Z , Hermenegildo G . (2018). Catalysis and photocatalysis by metal organic frameworks. Chemical Society Reviews, 47: 8134–8172

[5] Asgari M , Karve V V , Babapoor A , Saboor F H , Beydaghdari M . (2022). Recent advances in MOF-based adsorbents for dye removal from the aquatic environment. Energies, 15(6): 2023

[6] Attia M S , Youssef A O , Abou-Omar M N , Mohamed E H , Boukherroub R , Khan A , Altalhi T , Amin M A . (2022). Emerging advances and current applications of NanoMOF-based membranes for water treatment. Chemosphere, 292: 133369

[7] Azhar M R , Abid H R , Periasamy V , Sun H , Tade M O , Wang S . (2017). Adsorptive removal of antibiotic sulfonamide by UiO-66 and ZIF-67 for wastewater treatment. Journal of Colloid and Interface Science, 500: 88–95

[8] Azhar M R , Abid H R , Sun H , Periasamy V , Tadé M O , Wang S . (2016). Excellent performance of copper based metal organic framework in adsorptive removal of toxic sulfonamide antibiotics from wastewater. Journal of Colloid and Interface Science, 478: 344–352

[9] Bandehali S , Parvizian F , Ruan H , Moghadassi A , Shen J , Figoli A , Adeleye A S , Hilal N , Matsuura T , Drioli E , Hosseini S M . (2021). A planned review on designing of high-performance nanocomposite nanofiltration membranes for pollutants removal from water. Journal of Industrial and Engineering Chemistry, 101: 78–125

[10] Boo C , Wang Y , Zucker I , Choo Y , Osuji C O , Elimelech M . (2018). High performance nanofiltration membrane for effective removal of perfluoroalkyl substances at high water recovery. Environmental Science & Technology, 52(13): 7279–7288

[11] Brahmi C , Benltifa M , Vaulot C , Michelin L , Dumur F , Millange F , Frigoli M , Airoudj A , Morlet-Savary F , Bousselmi L , Lalevée J . (2021). New hybrid MOF/Polymer composites for the photodegradation of organic dyes. European Polymer Journal, 154: 110560

[12] Bux H , Liang F , Li Y , Cravillon J , Wiebcke M , Caro J . (2009). Zeolitic imidazolate framework membrane with molecular sieving properties by microwave-assisted solvothermal synthesis. Journal of the American Chemical Society, 131(44): 16000–16001

[13] Cao J , Su Y , Liu Y , Guan J , He M , Zhang R , Jiang Z . (2018). Self-assembled MOF membranes with underwater superoleophobicity for oil/water separation. Journal of Membrane Science, 566: 268–277

[14] Cao W , Zhang Y , Shi Z , Liu T , Song X , Zhang L , Keung Wong P , Chen Z . (2021a). Boosting the adsorption and photocatalytic activity of carbon Fiber/MoS₂-based weavable photocatalyst by decorating UiO-66-NH₂ nanoparticles. Chemical Engineering Journal, 417: 128112

[15] Cao Y , Chen X , Li X , Wang B . (2021b). Tuning surface functionalization and pore structure of UiO-66 Metal–organic framework nanoparticles for organic pollutant elimination. ACS Applied Nano Materials, 4(5): 5486–5495

[16] Cao Y , Li X , Yu G , Wang B . (2023). Regulating defective sites for pharmaceuticals selective removal: structure-dependent adsorption over continuously tunable pores. Journal of Hazardous Materials, 442: 130025

[17] Carja I D , Tavares S R , Shekhah O , Ozcan A , Semino R , Kale V S , Eddaoudi M , Maurin G . (2021). Insights into the enhancement of MOF/Polymer adhesion in mixed-matrix membranes via polymer functionalization. ACS Applied Materials & Interfaces, 13(24): 29041–29047

[18] Chai P V , Choy P Y , Teoh W C , Mahmoudi E , Ang W L . (2021). Graphene oxide based mixed matrix membrane in the presence of eco-friendly natural additive gum Arabic. Journal of Environmental Chemical Engineering, 9(4): 105638

[19] Chang P H , Chen C Y , Mukhopadhyay R , Chen W , Tzou Y M , Sarkar B . (2022). Novel MOF-808 metal-organic framework as highly efficient adsorbent of perfluorooctane sulfonate in water. Journal of Colloid and Interface Science, 623: 627–636

[20] Chen C , Chen D , Xie S , Quan H , Luo X , Guo L . (2017). Adsorption behaviors of organic micropollutants on zirconium metal-organic framework UiO-66: analysis of surface interactions. ACS Applied Materials & Interfaces, 9(46): 41043–41054

[21] Chen K , Li P , Zhang H , Sun H , Yang X , Yao D , Pang X , Han X , Jason Niu Q . (2020a). Organic solvent nanofiltration membrane with improved permeability by in-situ growth of metal-organic frameworks interlayer on the surface of polyimide substrate. Separation and Purification Technology, 251: 117387

[22] Chen X , Chen D , Li N , Xu Q , Li H , He J , Lu J . (2020b). Modified-MOF-808-loaded polyacrylonitrile membrane for highly efficient, simultaneous emulsion separation and heavy metal ion removal. ACS Applied Materials & Interfaces, 12(35): 39227–39235

[23] Dai R , Guo H , Tang C Y , Chen M , Li J , Wang Z . (2019). Hydrophilic selective nanochannels created by metal organic frameworks in nanofiltration membranes enhance rejection of hydrophobic endocrine-disrupting compounds. Environmental Science & Technology, 53(23): 13776–13783

[24] Dai R , Han H , Zhu Y , Wang X , Wang Z . (2022). Tuning the primary selective nanochannels of MOF thin-film nanocomposite nanofiltration membranes for efficient removal of hydrophobic endocrine disrupting compounds. Frontiers of Environmental Science & Engineering, 16(4): 40

[25] Dai R , Wang X , Tang C Y , Wang Z . (2020). Dually charged MOF-based thin-film nanocomposite nanofiltration membrane for enhanced removal of charged pharmaceutically active compounds. Environmental Science & Technology, 54(12): 7619–7628

[26] Dong X , Cui M , Huang R , Su R , Qi W , He Z . (2020). Polydopamine-assisted surface coating of MIL-53 and dodecanethiol on a melamine sponge for oil-water separation. Langmuir, 36(5): 1212–1220

[27] Dong X , Lin Y , Ren G , Ma Y , Zhao L . (2021). Catalytic degradation of methylene blue by fenton-like oxidation of Ce-doped MOF. Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 608: 125578

[28] Dou R , Zhang J , Chen Y , Feng S . (2017). High efficiency removal of triclosan by structure-directing agent modified mesoporous MIL-53(Al). Environmental Science and Pollution Research International, 24(9): 8778–8789

[29] Du C , Zhang Z , Yu G , Wu H , Chen H , Zhou L , Zhang Y , Su Y , Tan S , Yang L , Song J , Wang S . (2021). A review of metal organic framework (MOFs)-based materials for antibiotics removal via adsorption and photocatalysis. Chemosphere, 272(12): 129501

[30] Duan J , Li Y , Pan Y , Behera N , Jin W . (2019). Metal-organic framework nanosheets: an emerging family of multifunctional 2D materials. Coordination Chemistry Reviews, 395: 25–45

[31] El-Mehalmey W A , Safwat Y , Bassyouni M , Alkordi M H . (2020). Strong interplay between polymer surface charge and MOF cage chemistry in mixed-matrix membrane for water treatment applications. ACS Applied Materials & Interfaces, 12(24): 27625–27631

[32] Ermakov S . (2021). Novel mixed matrix membranes based on polymer of intrinsic microporosity PIM-1 modified with metal-organic frameworks for removal of heavy metal ions and food dyes by nanofiltration. Membranes, 12(1): 14

[33] Fan G , Zhan J , Luo J , Lin J , Qu F , Du B , You Y , Yan Z . (2021). Fabrication of heterostructured Ag/AgCl@g-C₃N₄@UIO-66-NH₂ nanocomposite for efficient photocatalytic inactivation of microcystis aeruginosa under visible light. Journal of Hazadous Materials, 404: 124062

[34] Fang X , Li J , Li X , Pan S , Zhang X , Sun X , Shen J , Han W , Wang L . (2017). Internal pore decoration with polydopamine nanoparticle on polymeric ultrafiltration membrane for enhanced heavy metal removal. Chemical Engineering Journal, 314: 38–49

[35] Ferjani E , Lajimi R H , Deratani A , Roudesli M S . (2018). Bulk and surface modification of cellulose diacetate based RO/NF membranes by polymethylhydrosiloxane preparation and characterization. Desalination, 146(146): 325–330

[36] Freund R , Zaremba O , Arnauts G , Ameloot R , Skorupskii G , Dinca M , Bavykina A , Gascon J , Ejsmont A , Goscianska J , Kalmutzki M , Lachelt U , Ploetz E , Diercks C S , Wuttke S . (2021). The current status of MOF and COF applications. Angewandte Chemie International Edition, 60(45): 23975–24001

[37] Furukawa H , Cordova K E , O’Keeffe M , Yaghi O M . (2013). ChemInform abstract: the chemistry and applications of metal-organic frameworks. Science, 341(6149): 1230444

[38] Gao J , Chen W , Shi H , Li Z , Jing L , Hou C , Wang J , Wang Y . (2022). Co₃O₄@Fe₃O₄/Cellulose Blend membranes for efficient degradation of perfluorooctanoic acid in the visible light-driven photo-fenton system. Surfaces and Interfaces, 34: 102302

[39] Gao Y , Kang R , Xia J , Yu G , Deng S . (2019). Understanding the adsorption of sulfonamide antibiotics on MIL-53s: metal dependence of breathing effect and adsorptive performance in aqueous solution. Journal of Colloid and Interface Science, 535: 159–168

[40] Gao Y , Liu K , Kang R , Xia J , Yu G , Deng S . (2018). A Comparative study of rigid and flexible MOFs for the adsorption of pharmaceuticals: kinetics, isotherms and mechanisms. Journal of Hazardous Materials, 359: 248–257

[41] Gao Y , Lu J , Xia J , Yu G . (2020). In situ synthesis of defect-engineered MOFs as a photoregenerable catalytic adsorbent: understanding the effect of LML, adsorption behavior, and photoreaction process. ACS Applied Materials & Interfaces, 12(11): 12706–12716

[42] Gao Y , Yan S , He Y , Fan Y , Zhang L , Ma J , Hou R , Chen L , Chen J . (2021). A photo-Fenton self-cleaning membrane based on NH₂-MIL-88B(Fe) and graphene oxide to improve dye removal Performance. Journal of Membrane Science, 626: 119192

[43] Gholipoor O , Hosseini S A . (2021). Phenol removal from wastewater by CWPO process over the Cu-MOF nanocatalyst: process modeling by response surface methodology (RSM) and kinetic and isothermal studies. New Journal of Chemistry, 45(5): 2536–2549

[44] Gokulakrishnan S A , Arthanareeswaran G , Laszlo Z , Vereb G , Kertesz S , Kweon J . (2021). Recent development of photocatalytic nanomaterials in mixed matrix membrane for emerging pollutants and fouling control, membrane cleaning process. Chemosphere, 281: 130891

[45] Gong Y , Gao S , Tian Y , Zhu Y , Fang W , Wang Z , Jin J . (2020). Thin-film nanocomposite nanofiltration membrane with an ultrathin polyamide/UIO-66-NH₂ active layer for high-performance desalination. Journal of Membrane Science, 600: 117874

[46] Gong Y , Yang B , Zhang H , Zhao X . (2018). A g-C₃N₄/MIL-101(Fe) heterostructure composite for highly efficient BPA degradation with persulfate under visible light irradiation. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 6(46): 23703–23711

[47] GuDLiuYZhuHGanYZhangBYangWHaoJ (2022). Magnetic porphyrin-based metal organic gel for rapid RhB removal and enhanced antibacterial activity by heterogeneous photo-Fenton reaction under visible light. Chemosphere, 303(Pt 2): 135114

[48] Han B , Zhang D , Shao Z , Kong L , Lv S . (2013). Preparation and characterization of cellulose acetate/carboxymethyl cellulose acetate blend ultrafiltration membranes. Desalination, 311: 80–89

[49] Hasan Z , Choi E J , Jhung S H . (2013). Adsorption of naproxen and clofibric acid over a metal-organic framework MIL-101 functionalized with acidic and basic groups. Chemical Engineering Journal, 219: 537–544

[50] Hayama M , Yamamoto K I , Kohori F , Uesaka T , Ueno Y , Sugaya H , Itagaki I , Sakai K . (2004). Nanoscopic behavior of polyvinylpyrrolidone particles on polysulfone/polyvinylpyrrolidone film. Biomaterials, 25(6): 1019–1028

[51] He L , Dong Y , Zheng Y , Jia Q , Shan S , Zhang Y . (2019). A novel magnetic MIL-101(Fe)/TiO₂ composite for photo degradation of tetracycline under solar light. Journal of Hazadous Materials, 361: 85–94

[52] Hermes S , Schröder F , Chelmowski R , Wöll C , Fischer R A . (2005). Selective nucleation and growth of metal−organic open framework thin films on patterned COOH/CF^3- terminated self-assembled monolayers on Au(111). Journal of the American Chemical Society, 127(40): 13744–13745

[53] Hou P , Xing G , Han D , Wang H , Yu C , Li Y . (2018). Preparation of zeolite imidazolate framework/graphene hybrid aerogels and their application as highly efficient adsorbent. Journal of Solid State Chemistry, 265: 184–192

[54] Hu P , Zhao Z , Sun X , Muhammad Y , Li J , Chen S , Pang C , Liao T , Zhao Z . (2019). Construction of crystal defect sites in N-coordinated UiO-66 via mechanochemical in-situ N-doping strategy for highly selective adsorption of cationic dyes. Chemical Engineering Journal, 356: 329–340

[55] Hu T , Tang L , Feng H , Zhang J , Li X , Zuo Y , Lu Z , Tang W . (2022). Metal-organic frameworks (MOFs) and their derivatives as emerging catalysts for electro-Fenton process in water purification. Coordination Chemistry Reviews, 451: 214277

[56] Hu Y , Dong X , Nan J , Jin W , Ren X , Xu N , Lee Y M . (2011). Metal-organic framework membranes fabricated via reactive seeding. Chemical Communications (Cambridge), 47(2): 737–739

[57] Huang J , Huang D , Zeng F , Ma L , Wang Z . (2021). Photocatalytic MOF fibrous membranes for cyclic adsorption and degradation of dyes. Journal of Materials Science, 56(4): 3127–3139

[58] Hussain S , Peng X . (2021). Ultra-fast photothermal-responsive Fe-TCPP-based thin-film nanocomposite membranes for ON/OFF switchable nanofiltration. Separation and Purification Technology, 278: 119528

[59] Jhaveri J H , Murthy Z V P . (2016). A comprehensive review on anti-fouling nanocomposite membranes for pressure Driven membrane separation processes. Desalination, 379: 137–154

[60] Ji W , Wang X , Ding T , Chakir S , Xu Y , Huang X , Wang H . (2023). Electrospinning preparation of nylon-6@UiO-66-NH₂ fiber membrane for selective adsorption enhanced photocatalysis reduction of Cr(VI) in water. Chemical Engineering Journal, 451: 138973

[61] Jia Z , Jiang M , Wu G . (2017). Amino-MIL-53(Al) sandwich-structure membranes for adsorption of p-nitrophenol from aqueous solutions. Chemical Engineering Journal, 307: 283–290

[62] Jiang Y , Sun J , Yang X , Shen J , Fu Y , Fan Y , Xu J , Wang L . (2021). Cd-MOF@PVDF mixed-matrix membrane with good catalytic activity and recyclability for the production of benzimidazole and amino acid derivatives. Inorganic Chemistry, 60(3): 2087–2096

[63] Jiang Z R , Wang H , Hu Y , Lu J , Jiang H L . (2015). Polar group and defect engineering in a metal–organic framework: synergistic promotion of carbon dioxide sorption and conversion. ChemSusChem, 8(5): 878–885

[64] Jin J , Kim J P , Wan S , Kim K H , Choi Y , Li P , Kang J , Ma Z , Lee J H , Kwon O , Kim D W , Park J H . (2022). Hierarchical oore enhanced adsorption and photocatalytic performance of graphene oxide/Ti-based metal-organic framework hybrid for toluene removal. Applied Catalysis B: Environmental, 317: 121751

[65] Jun B M , Al-Hamadani Y A J , Son A , Park C M , Jang M , Jang A , Kim N C , Yoon Y . (2020). Applications of metal-organic framework based membranes in water purification: A review. Separation and Purification Technology, 247: 116947

[66] Jurchevsky E B , Pervov A G . (2020). Potentialities of membrane water treatment for removing organic pollutants from natural water. Thermal Engineering, 67(7): 484–491

[67] Karimi M , Mohebali H , Sadeghi S , Safarifard V , Mahjoub A , Heydari A . (2021). Additive-free aerobic C-H oxidation through a defect-engineered Ce-MOF catalytic system. Microporous and Mesoporous Materials, 322: 111054

[68] Kasik A , James J , Lin Y S . (2016). Synthesis of ZIF-68 membrane on a ZnO modified α-Alumina support by a modified reactive seeding method. Industrial & Engineering Chemistry Research, 55(10): 2831–2839

[69] Khan A , Ali M , Ilyas A , Naik P , Vankelecom I F J , Gilani M A , Bilad M R , Sajjad Z , Khan A L . (2018). ZIF-67 filled PDMS mixed matrix membranes for recovery of ethanol via pervaporation. Separation and Purification Technology, 206: 50–58

[70] Kong Z , Lu L , Zhu C , Xu J , Fang Q , Liu R , Shen Y . (2022). Enhanced adsorption and photocatalytic removal of PFOA from water by functionalized MOF with in-situ-growth TiO₂: regulation of electron density and bandgap. Separation and Purification Technology, 297: 121449

[71] Lee A , Elam J W , Darling S B . (2016). Membrane materials for water purification: design, development, and application. Environmental Science. Water Research & Technology, 2(1): 17–42

[72] Lee D T , Zhao J , Oldham C J , Peterson G W , Parsons G N . (2017). UiO-66-NH₂ metal-organic framework (MOF) nucleation on TiO₂, ZnO, and Al₂O₃ atomic layer deposition-treated polymer fibers: role of metal oxide on MOF growth and catalytic hydrolysis of chemical warfare agent simulants. ACS Applied Materials & Interfaces, 9(51): 44847–44855

[73] Lee S , Ahn S , Lee H , Kim J . (2022). Layer-by-layer coating of MIL-100(Fe) on a cotton fabric for purification of water-soluble dyes by the combined effect of adsorption and photocatalytic degradation. RSC Advances, 12(27): 17505–17513

[74] Li A , Zhou M , Luo P , Shang J , Wang P , Lyu L . (2020a). Deposition of MOFs on polydopamine-modified electrospun polyvinyl alcohol/silica nanofibers mats for chloramphenicol adsorption in water. Nano, 15(4): 2050046

[75] Li H , Cao X , Zhang C , Yu Q , Zhao Z , Niu X , Sun X , Liu Y , Ma L , Li Z . (2017a). Enhanced adsorptive removal of anionic and cationic dyes from single or mixed dye solutions using MOF PCN-222. RSC Advances, 7(27): 16273–16281

[76] Li H , Zhu L , Zhang J , Guo T , Li X , Xing W , Xue Q . (2019a). High-efficiency separation performance of oil-water emulsions of polyacrylonitrile nanofibrous membrane decorated with metal-organic frameworks. Applied Surface Science, 476: 61–69

[77] Li J , Wang H , Yuan X , Zhang J , Chew J W . (2020b). Metal-organic framework membranes for wastewater treatment and water regeneration. Coordination Chemistry Reviews, 404: 213116

[78] Li R , Chen Z , Cai M , Huang J , Chen P , Liu G , Lv W . (2018). Improvement of sulfamethazine photodegradation by Fe(III) assisted MIL-53(Fe)/percarbonate system. Applied Surface Science, 457: 726–734

[79] Li Q , Cheng L , Shen J , Shi J , Chen G , Zhao J , Duan J , Liu G , Jin W . (2017b). Improved ethanol recovery through mixed-matrix membrane with hydrophobic MAF-6 as filler. Separation and Purification Technology, 178: 105–112

[80] Li T , Zhang Z , Liu L , Gao M , Han Z . (2021). A stable metal-organic framework nanofibrous membrane as photocatalyst for simultaneous removal of methyl orange and formaldehyde from aqueous solution. Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 617: 126359

[81] Li W , Li Y , Wen X , Teng Y , Wang J , Yang T , Li X , Li L , Wang C . (2022a). Flexible Zr-MOF anchored polymer nanofiber membrane for efficient removal of creatinine in uremic toxins. Journal of Membrane Science, 648: 120369

[82] Li W Q , Wang Y X , Chen J Q , Hou N N , Li Y M , Liu X C , Ding R R , Zhou G N , Li Q , Zhou X G , Mu Y . (2022b). Boosting photo-Fenton process enabled by ligand-to-cluster charge transfer excitations in iron-based metal organic framework. Applied Catalysis B: Environmental, 302: 120882

[83] Li X , Li X , Wang B . (2022c). H₂O₂ activation by two-dimensional metal-organic frameworks with different metal nodes for micropollutants degradation: metal dependence of boosting reactive oxygen species generation. Journal of Hazardous Materials, 440: 129757

[84] Li X , Liu Y , Wang J , Gascon J , Li J , Van der Bruggen B . (2017c). Metal-organic frameworks based membranes for liquid separation. Chemical Society Reviews, 46(23): 7124–7144

[85] Li X , Yao Y , Wang B . (2022d). Incorporating Fe–O cluster in multivariate (MTV) metal–organic frameworks for promoting visible-light photo-Fenton degradation of micropollutants from water. Chemical Engineering Journal, 446: 137446

[86] Li Y , Fang Y , Cao Z , Li N , Chen D , Xu Q , Lu J . (2019b). Construction of g-C₃N₄/PDI@MOF heterojunctions for the highly efficient visible light-driven degradation of pharmaceutical and phenolic micropollutants. Applied Catalysis B: Environmental, 250: 150–162

[87] Li Y , Li X , Wang B . (2022e). Controlling metal clusters in breathing metal–organic framework nanostructures for boosting visible-light-induced ·OH radical formation. ACS Applied Nano Materials, 5(2): 2510–2521

[88] Liang Q , Cui S , Jin J , Liu C , Xu S , Yao C , Li Z . (2018). Fabrication of BiOI@UIO-66(NH₂)@g-C₃N₄ ternary Z-scheme heterojunction with enhanced visible-light photocatalytic activity. Applied Surface Science, 456: 899–907

[89] Lin S , Zhao Y , Yun Y S . (2018). Highly effective removal of nonsteroidal anti-inflammatory pharmaceuticals from water by Zr(IV)-based metal–organic framework: adsorption performance and mechanisms. ACS Applied Materials & Interfaces, 10(33): 28076–28085

[90] Lin Y , Wu H C , Yasui T , Yoshioka T , Matsuyama H . (2019). Development of an HKUST-1 nanofiller-templated poly(ether sulfone) mixed matrix membrane for a highly efficient ultrafiltration process. ACS Applied Materials & Interfaces, 11(20): 18782–18796

[91] Liu X , Demir N K , Wu Z , Li K . (2015). Highly water-stable zirconium metal-organic framework UiO-66 membranes supported on Alumina hollow fibers for desalination. Journal of the American Chemical Society, 137(22): 6999–7002

[92] Liu X , Wang X , Kapteijn F . (2020). Water and metal-organic frameworks: from interaction toward utilization. Chemical Reviews, 120(16): 8303–8377

[93] Liu Y , Su Y , Cao J , Guan J , Zhang R , He M , Fan L , Zhang Q , Jiang Z . (2017). Antifouling, high-flux oil/water separation carbon nanotube membranes by polymer-mediated surface charging and hydrophilization. Journal of Membrane Science, 542: 254–263

[94] Liu Y , Tu W , Chen M , Ma L , Yang B , Liang Q , Chen Y . (2018). A mussel-induced method to fabricate reduced graphene oxide/halloysite nanotubes membranes for multifunctional applications in water purification and oil/water separation. Chemical Engineering Journal, 336: 263–277

[95] Long J , Wang Y , Jiang H L , Qiang X . (2017). Metal-organic frameworks as platforms for catalytic applications. Advanced Materials, 30(37): 1703663

[96] Lu W , Duan C , Zhang Y , Gao K , Dai L , Shen M , Wang W , Wang J , Ni Y . (2021). Cellulose-based electrospun nanofiber membrane with core-sheath structure and robust photocatalytic activity for simultaneous and efficient oil emulsions separation, dye degradation and Cr(VI) reduction. Carbohydrate Polymers, 258: 117676

[97] Lustig W , Mukherjee S , Rudd N , Desai A , Li J , Ghosh S . (2017). Metal–organic frameworks: functional luminescent and photonic materials for sensing applications. Chemical Society Reviews, 46(11): 3242–3285

[98] Lyu Q , Deng X , Hu S , Lin L C , Ho W S W . (2019). Exploring the potential of defective UiO-66 as reverse osmosis membranes for desalination. Journal of Physical Chemistry C, 123(26): 16118–16126

[99] Meng C , Ding B , Zhang S , Cui L , Ostrikov K K , Huang Z , Yang B , Kim J H , Zhang Z . (2022). Angstrom-confined catalytic water purification within Co-TiO_x laminar membrane nanochannels. Nature Communications, 13(1): 4010

[100] Meng J , Liu X , Niu C , Pang Q , Li J , Liu F , Liu Z , Mai L . (2020). Advances in metal-organic framework coatings: versatile synthesis and broad applications. Chemical Society Reviews, 49(10): 3142–3186

[101] Mi X , Li X . (2022). Construction of a stable porous composite with tunable graphene oxide in Ce-based-MOFs for enhanced solar-photocatalytic degradation of sulfamethoxazole in water. Separation and Purification Technology, 301: 122006

[102] Mon M , Bruno R , Ferrando-Soria J , Armentano D , Pardo E . (2018). Metal–organic framework technologies for water remediation: towards a sustainable ecosystem. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 6(12): 4912–4947

[103] Mon M , Lloret F , Ferrando-Soria J , Martí-Gastaldo C , Armentano D , Pardo E . (2016). Selective and efficient removal of mercury from aqueous media with the highly flexible arms of a bioMOF. Angewandte Chemie International Edition, 55(37): 11167–11172

[104] Na L , Long Z , Xiaoying J , Gary O , Zuliang C . (2018). Simultaneous removal of tetracycline and oxytetracycline antibiotics from wastewater using a ZIF-8 metal organic-framework. Journal of Hazardous Materials, 366: 563–572

[105] Naeimi S , Faghihian H . (2017). Application of novel metal organic framework, MIL-53(Fe) and its magnetic hybrid: for removal of pharmaceutical pollutant, doxycycline from aqueous solutions. Environmental Toxicology and Pharmacology, 53(jul): 121–132

[106] Navarathna C M , Dewage N B , Karunanayake A G , Farmer E L , Perez F , Hassan E B , Mlsna T E , Pittman C U . (2020). Rhodamine B adsorptive removal and photocatalytic degradation on MIL-53-Fe MOF/magnetic magnetite/biochar composites. Journal of Inorganic and Organometallic Polymers and Materials, 30(1): 214–229

[107] Navarro M , Benito J , Paseta L , Gascon I , Coronas J , Tellez C . (2018). Thin-film nanocomposite membrane with the minimum amount of MOF by the Langmuir-Schaefer technique for nanofiltration. ACS Applied Materials & Interfaces, 10(1): 1278–1287

[108] Ni L , Zhu Y , Ma J , Wang Y . (2021). Novel strategy for membrane biofouling control in MBR with CdS/MIL-101 modified PVDF membrane by in situ visible light irradiation. Water Research, 188: 116554

[109] Parkerson Z J , Le T , Das P , Mahmoodi S N , Esfahani M R . (2021). Cu-MOF-polydopamine-incorporated functionalized nanofiltration membranes for water treatment: effect of surficial adhesive modification techniques. ACS ES&T Water, 1(2): 430–439

[110] Paseta L , Navarro M , Coronas J , Téllez C . (2019). Greener processes in the preparation of thin film nanocomposite membranes with diverse metal-organic frameworks for organic solvent nanofiltration. Journal of Industrial and Engineering Chemistry, 77: 344–354

[111] Peng Y , Zhang Y , Huang H , Zhong C . (2018). Flexibility induced high-performance MOF-based adsorbent for nitroimidazole antibiotics capture. Chemical Engineering Journal, 333: 678–685

[112] Qiu J , Zhang X , Feng Y , Zhang X , Wang H , Yao J . (2018). Modified metal-organic frameworks as photocatalysts. Applied Catalysis B: Environmental, 231: 317–342

[113] QuWWenHQuXGuoYHuLLiuWTianSHeCShuD (2022). Enhanced Fenton-like catalysis for pollutants removal via MOF-derived Co_xFe_(3–x)O₄ membrane: oxygen vacancy-mediated mechanism. Chemosphere, 303(Pt 3): 135301

[114] Ragab D , Gomaa H G , Sabouni R , Salem M , Ren M , Zhu J . (2016). Micropollutants removal from water using microfiltration membrane modified with ZIF-8 metal organic frameworks (MOFs). Chemical Engineering Journal, 300: 273–279

[115] Ren J , Ledwaba M , Musyoka N M , Langmi H W , Mathe M , Liao S , Pang W . (2017). Structural defects in metal-organic frameworks (MOFs): formation, detection and control towards practices of interests. Coordination Chemistry Reviews, 349: 169–197

[116] Ren Y , Li T , Zhang W , Wang S , Shi M , Shan C , Zhang W , Guan X , Lv L , Hua M , Pan B . (2019). MIL-PVDF blend ultrafiltration membranes with ultrahigh MOF loading for simultaneous adsorption and catalytic oxidation of methylene blue. Journal of Hazardous Materials, 365: 312–321

[117] Ren Y , Wang S , Zhang J , Lu J , Shan C , Zhang Y , Dionysiou D D , Lv L , Pan B , Zhang W . (2021). Enhancing the performance of Fenton-like oxidation by a dual-layer membrane: a sequential interception-oxidation process. Journal of Hazardous Materials, 402: 123766

[118] Rickhoff T A , Sullivan E , Werth L K , Kissel D S , Keleher J J . (2019). A biomimetic cellulose-based composite material that incorporates the antimicrobial metal-organic framework HKUST-1. Journal of Applied Polymer Science, 136(3): 46978

[119] Rojas S , Horcajada P . (2020). Metal-organic frameworks for the removal of emerging organic contaminants in water. Chemical Reviews, 120(16): 8378–8415

[120] Rosario-Ortiz F L , Wert E C , Snyder S A . (2010). Evaluation of UV/H₂O₂ treatment for the oxidation of pharmaceuticals in wastewater. Water Research, 44(5): 1440–1448

[121] Song X , Gan B , Qi S , Guo H , Tang C Y , Zhou Y , Gao C . (2020). Intrinsic nanoscale structure of thin film composite polyamide membranes: connectivity, defects, and structure-property correlation. Environmental Science & Technology, 54(6): 3559–3569

[122] Sorribas S , Gorgojo P , Tellez C , Coronas J , Livingston A G . (2013). High flux thin film nanocomposite membranes based on metal-organic frameworks for organic solvent nanofiltration. Journal of the American Chemical Society, 135(40): 15201–15208

[123] Tan Y , Sun Z , Meng H , Han Y , Wu J , Xu J , Xu Y , Zhang X . (2019). A new MOFs/polymer hybrid membrane: MIL-68(Al)/PVDF, fabrication and application in high-efficient removal of p-nitrophenol and methylene blue. Separation and Purification Technology, 215: 217–226

[124] Tian C , Zhao J , Ou X , Wan J , Cai Y , Lin Z , Dang Z , Xing B . (2018). Enhanced adsorption of p-arsanilic acid from water by amine-modified UiO-67 as examined using extended X-ray absorption fine structure, X-ray photoelectron spectroscopy, and density functional theory calculations. Environmental Science & Technology, 52(6): 3466–3475

[125] Tran N H , Reinhard M , Gin K Y . (2018). Occurrence and fate of emerging contaminants in municipal wastewater treatment plants from different geographical regions: a review. Water Research, 133: 182–207

[126] Trickett C A , Gagnon K J , Lee S , Gándara F , Bürgi H B , Yaghi O M . (2015). Definitive molecular level characterization of defects in UiO-66 crystals. Angewandte Chemie International Edition, 54(38): 11162–11167

[127] Vandezande P , Gevers L M , Vankelecom I J . (2008). Solvent resistant nanofiltration: separating on a molecular level. Chemical Society Reviews, 37(2): 365–405

[128] Vinothkumar K , Shivanna Jyothi M , Lavanya C , Sakar M , Valiyaveettil S , Balakrishna R G . (2022). Strongly co-ordinated MOF-PSF matrix for selective adsorption, separation and photodegradation of dyes. Chemical Engineering Journal, 428: 132561

[129] Wang C , Zheng T , Luo R , Liu C , Zhang M , Li J , Sun X , Shen J , Han W , Wang L . (2018a). In situ growth of ZIF-8 on PAN fibrous filters for highly efficient U(VI) removal. ACS Applied Materials & Interfaces, 10(28): 24164–24171

[130] Wang H , Zhan J , Yao W , Wang B , Deng S , Huang J , Yu G , Wang Y . (2018b). Comparison of pharmaceutical abatement in various water matrices by conventional ozonation, peroxone (O₃/H₂O₂), and an electro-peroxone process. Water Research, 130: 127–138

[131] Wang H , Zhao S , Liu Y , Yao R , Wang X , Cao Y , Ma D , Zou M , Cao A , Feng X , Wang B . (2019). Membrane adsorbers with ultrahigh metal-organic framework loading for high flux separations. Nature Communications, 10(1): 4204

[132] Wang X , Chen J , Fang M , Wang T , Yu L , Li J . (2016). ZIF-7/PDMS mixed matrix membranes for pervaporation recovery of butanol from aqueous solution. Separation and Purification Technology, 163: 39–47

[133] Wang Z , He M , Jiang H , He H , Qi J , Ma J . (2022). Photocatalytic MOF membranes with two-dimensional heterostructure for the enhanced removal of agricultural pollutants in water. Chemical Engineering Journal, 435: 133870

[134] Wojnárovits L , Takacs E . (2019). Rate constants of sulfate radical anion reactions with organic molecules: a review. Chemosphere, 220: 1014–1032

[135] Wu G , Ma J , Li S , Guan J , Jiang B , Wang L , Li J , Wang X , Chen L . (2018). Magnetic copper-based metal organic framework as an effective and recyclable adsorbent for removal of two fluoroquinolone antibiotics from aqueous solutions. Journal of Colloid and Interface Science, 528: 360–371

[136] Xia Z , Shi B , Zhu W , Lü C . (2021). Temperature-responsive polymer-tethered Zr-porphyrin MOFs encapsulated carbon dot nanohybrids with boosted visible-light photodegradation for organic contaminants in water. Chemical Engineering Journal, 426: 131794

[137] Xiang X , Chen D , Li N , Xu Q , Li H , He J , Lu J . (2022). Mil-53(Fe)-loaded polyacrylonitrile membrane with superamphiphilicity and double hydrophobicity for effective emulsion separation and photocatalytic dye degradation. Separation and Purification Technology, 282: 111910

[138] Xiao S , Huo X , Fan S , Zhao K , Yu S , Tan X . (2021). Design and synthesis of Al-MOF/PPSU mixed matrix membrane with pollution resistance. Chinese Journal of Chemical Engineering, 29: 110–120

[139] Xie A , Cui J , Yang J , Chen Y , Lang J , Li C , Yan Y , Dai J . (2020). Photo-Fenton self-cleaning PVDF/NH₂-MIL-88B(Fe) membranes towards highly-efficient oil/water emulsion separation. Journal of Membrane Science, 595: 117499

[140] Xie J , Liao Z , Zhang M , Ni L , Qi J , Wang C , Sun X , Wang L , Wang S , Li J . (2021). Sequential ultrafiltration-catalysis membrane for excellent removal of multiple pollutants in water. Environmental Science & Technology, 55(4): 2652–2661

[141] Xiong W , Zeng G , Yang Z , Zhou Y , Zhang C , Cheng M , Liu Y , Hu L , Wan J , Zhou C . . (2018). Adsorption of tetracycline antibiotics from aqueous solutions on nanocomposite multi-walled carbon nanotube functionalized MIL-53(Fe) as new adsorbent. Science of the Total Environment, 627: 235–244

[142] Xu L H , Li S H , Mao H , Li Y , Zhang A S , Wang S , Liu W M , Lv J , Wang T , Cai W W . . (2022). Highly flexible and superhydrophobic MOF nanosheet membrane for ultrafast alcohol-water separation. Science, 378(6617): 308–313

[143] Xue J , Xu M , Gao J , Zong Y , Wang M , Ma S . (2021). Multifunctional porphyrinic Zr-MOF composite membrane for high-performance oil-in-water separation and organic dye adsorption/photocatalysis. Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 628: 127288

[144] Yaghi O M , Li G , Li H . (1995). Selective binding and removal of guests in a microporous metal–organic framework. Nature, 378(6558): 703–706

[145] Yang Q , Xu Q , Jiang H L . (2017). Metal-organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis. Chemical Society Reviews, 46(15): 4774–4808

[146] Yang S , Zou Q , Wang T , Zhang L . (2018). Effects of GO and MOF@GO on the permeation and antifouling properties of cellulose acetate ultrafiltration membrane. Journal of Membrane Science, 569: 48–59

[147] Yang Y , Fu P , Li X , Su Z M , Xu N , Wang X . (2020). Co-based MOF for efficient degradation of RB in aqueous solutions by peroxymonosulfate activation. Inorganic Chemistry Communications, 122: 108282

[148] Yang Z , Guo H , Yao Z K , Mei Y , Tang C Y . (2019). Hydrophilic silver nanoparticles induce selective nanochannels in thin film nanocomposite polyamide membranes. Environmental Science & Technology, 53(9): 5301–5308

[149] Yang Z , Qian J , Shan C , Li H , Yin Y , Pan B . (2021). Toward selective oxidation of contaminants in aqueous systems. Environmental Science & Technology, 55(21): 14494–14514

[150] Yao Y , Wang C , Na J , Hossain M S A , Yan X , Zhang H , Amin M A , Qi J , Yamauchi Y , Li J . (2021). Macroscopic MOF architectures: effective strategies for practical application in water treatment. Small, 2021: 2104387

[151] Ye Z , Oriol R , Yang C , Sirés I , Li X Y . (2022). A novel NH₂-MIL-88B(Fe)-modified ceramic membrane for the integration of electro-Fenton and filtration processes: a case study on naproxen degradation. Chemical Engineering Journal, 433: 133457

[152] Yin H , Lau C Y , Rozowski M , Howard C , Xu Y , Lai T , Dose M E , Lively R P , Lind M L . (2017). Free-standing ZIF-71/PDMS nanocomposite membranes for the recovery of ethanol and 1-butanol from water through pervaporation. Journal of Membrane Science, 529: 286–292

[153] Yu D , Wu M , Hu Q , Wang L , Lv C , Zhang L . (2019). Iron-based metal-organic frameworks as novel platforms for catalytic ozonation of organic pollutant: Efficiency and mechanism. Journal of Hazardous Materials, 367: 456–464

[154] Yu L , Cao W , Wu S , Yang C , Cheng J . (2018). Removal of tetracycline from aqueous solution by MOF/graphite oxide pellets: preparation, characteristic, adsorption performance and mechanism. Ecotoxicology and Environmental Safety, 164: 289–296

[155] Zeng H , Yu Z , Shao L , Li X , Zhu M , Liu Y , Feng X , Zhu X . (2021). A novel strategy for enhancing the performance of membranes for dyes separation: Embedding PAA@UiO-66-NH₂ between graphene oxide sheets. Chemical Engineering Journal, 403: 126281

[156] Zhang B , Shan C , Hao Z , Liu J , Wu B , Pan B . (2019a). Transformation of dissolved organic matter during full-scale treatment of integrated chemical wastewater: molecular composition correlated with spectral indexes and acute toxicity. Water Research, 157: 472–482

[157] Zhang H , Chen S , Zhang H , Fan X , Gao C , Yu H , Quan X . (2019b). Carbon nanotubes-incorporated MIL-88B-Fe as highly efficient Fenton-like catalyst for degradation of organic pollutants. Frontiers of Environmental Science & Engineering, 13(2): 18

[158] Zhang H Z , Sun J Y , Zhang Z L , Xu Z L . (2021a). Hybridly charged NF membranes with MOF incorporated for removing low-concentration surfactants. Separation and Purification Technology, 258: 118069

[159] Zhang J , Xu Z , Mai W , Min C , Zhou B , Shan M , Li Y , Yang C , Wang Z , Qian X . (2013). Improved hydrophilicity, permeability, antifouling and mechanical performance of PVDF composite ultrafiltration membranes tailored by oxidized low-dimensional carbon nanomaterials. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 1(9): 3101

[160] Zhang R , Cao J , Liu Y , Guan J , He M , Jiang Z . (2020). Metal-organic framework-intercalated graphene oxide membranes for highly efficient oil/water separation. Industrial & Engineering Chemistry Research, 59(38): 16762–16771

[161] Zhang Y , Xiong M , Sun A , Shi Z , Zhu B , Macharia D K , Li F , Chen Z , Liu J , Zhang L . (2021b). MIL-101(Fe) nanodot-induced improvement of adsorption and photocatalytic activity of carbon fiber/TiO₂-based weavable photocatalyst for removing pharmaceutical pollutants. Journal of Cleaner Production, 290: 125782

[162] Zhao J , Lyu C , Zhang R , Han Y , Wu Y , Wu X . (2023). Self-cleaning and regenerable nano zero-valent iron modified PCN-224 heterojunction for photo-enhanced radioactive waste reduction. Journal of Hazardous Materials, 442: 130018

[163] Zhao P , Wang J , Han X , Liu J , Zhang Y , Van der Bruggen B . (2021). Zr-porphyrin metal–organic framework-based photocatalytic self-cleaning membranes for efficient dye removal. Industrial & Engineering Chemistry Research, 60(4): 1850–1858

[164] Zhou H C J , Kitagawa S . (2014). Metal-organic frameworks (MOFs). Chemical Society Reviews, 43(16): 5415–5418

[165] Zhou L , Li N , Owens G , Chen Z . (2019). Simultaneous removal of mixed contaminants, copper and norfloxacin, from aqueous solution by ZIF-8. Chemical Engineering Journal, 362: 628–637

[166] Zhou M , Wu Y N , Qiao J , Zhang J , Mcdonald A , Li G , Li F . (2013). The removal of bisphenol A from aqueous solutions by MIL-53(Al) and mesostructured MIL-53(Al). Journal of Colloid and Interface Science, 405(9): 157–163

[167] Zhu Z , Wang L , Xu Y , Li Q , Jiang J , Wang X . (2017). Preparation and characteristics of graphene oxide-blending PVDF nanohybrid membranes and their applications for hazardous dye adsorption and rejection. Journal of Colloid and Interface Science, 504: 429–439

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