Performance of activated carbon coated graphite bipolar electrodes on capacitive deionization method for salinity reduction

Hossein D. Atoufi , Hasti Hasheminejad , David J. Lampert

Front. Environ. Sci. Eng. ›› 2020, Vol. 14 ›› Issue (6) : 99

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Front. Environ. Sci. Eng. ›› 2020, Vol. 14 ›› Issue (6) : 99 DOI: 10.1007/s11783-020-1278-1
RESEARCH ARTICLE
RESEARCH ARTICLE

Performance of activated carbon coated graphite bipolar electrodes on capacitive deionization method for salinity reduction

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Abstract

• Graphite bipolar electrodes act as an appropriate bed for the CDI process.

• Activated carbon Coating improves the application of the electrodes.

• CDI is an environmentally friendly method to apply for brackish water.

• Initial concentration is the most important parameter in the CDI method.

• CDI process in a batch-mode setup needs more development.

This research investigates a capacitive deionization method for salinity reduction in a batch reactor as a new approach for desalination. Reductions of cost and energy compared with conventional desalination methods are the significant advantages of this approach. In this research, experiments were performed with a pair of graphite bipolar electrodes that were coated with a one-gram activated carbon solution. After completing preliminary tests, the impacts of four parameters on electrical conductivity reduction, including (1) the initial concentration of feed solution, (2) the duration of the tests, (3) the applied voltage, and (4) the pH of the solution, were examined. The results show that the maximum efficiency of electrical conductivity reduction in this laboratory-scale reactor is about 55%. Furthermore, the effects of the initial concentration of feed solution are more significant than the other parameters. Thus, using the capacitive deionization method for water desalination with low and moderate salt concentrations (i.e., brackish water) is proposed as an affordable method. Compared with conventional desalination methods, capacitive deionization is not only more efficient but also potentially more environmentally friendly.

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Keywords

Capacitive deionization (CDI) / Desalination / Electrical conductivity (EC) / Graphite bipolar electrode / Activated carbon coated (ACC)

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Hossein D. Atoufi, Hasti Hasheminejad, David J. Lampert. Performance of activated carbon coated graphite bipolar electrodes on capacitive deionization method for salinity reduction. Front. Environ. Sci. Eng., 2020, 14(6): 99 DOI:10.1007/s11783-020-1278-1

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References

[1]

Ahirrao D J, Tambat S, Pandit A B, Jha N (2019). Sweet-lime-peels-derived activated-carbon-based electrode for highly efficient supercapacitor and flow-through water desalination. ChemistrySelect, 4(9): 2610–2625

[2]

Ahmed M A, Tewari S (2018). Capacitive deionization: Processes, materials and state of the technology. Journal of Electroanalytical Chemistry, 813: 178–192

[3]

AlMarzooqi F A, Al Ghaferi A A, Saadat I, Hilal N (2014). Application of capacitive deionisation in water desalination: A review. Desalination, 342: 3–15

[4]

Ban A, Schafer A, Wendt H (1998). Fundamentals of electrosorption on activated carbon for wastewater treatment of industrial effluents. Journal of Applied Electrochemistry, 28(3): 227–236

[5]

Bao W, Tang X, Guo X, Choi S, Wang C, Gogotsi Y, Wang G (2018). Porous cryo-dried MXene for efficient capacitive deionization. Joule, 2(4): 778–787

[6]

Blair J W, Murphy G W (1960) Electrochemical demineralization of water with porous electrodes of large surface area. In: Saline Water Conversion. Washington, DC: American Chemical Society, 206–223

[7]

Design Expert Software (2015) Design Expert Software, Version 9, User’s Guide

[8]

Dutta S, Huang S Y, Chen C, Chen J E, Alothman Z A, Yamauchi Y, Hou C H, Wu K C W (2016). Cellulose framework directed construction of hierarchically porous carbons offering high-performance capacitive deionization of brackish water. ACS Sustainable Chemistry & Engineering, 4(4): 1885–1893

[9]

Gustafsson J, Mikkola P, Jokinen M, Rosenholm J B (2000). The influence of pH and NaCl on the zeta potential and rheology of anatase dispersions. Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 175(3): 349–359

[10]

Han L, Karthikeyan K G, Anderson M A, Wouters J J, Gregory K B (2013). Mechanistic insights into the use of oxide nanoparticles coated asymmetric electrodes for capacitive deionization. Electrochimica Acta, 90: 573–581

[11]

Khajouei G, Mortazavian S, Saber A, Zamani Meymian N, Hasheminejad H (2019). Treatment of composting leachate using electro-Fenton process with scrap iron plates as electrodes. International Journal of Environmental Science and Technology, 16(8): 4133–4142

[12]

Laxman K, Myint M T Z, Al Abri M, Sathe P, Dobretsov S, Dutta J (2015). Desalination and disinfection of inland brackish ground water in a capacitive deionization cell using nanoporous activated carbon cloth electrodes. Desalination, 362: 126–132

[13]

Li L, Zou L, Song H, Morris G (2009). Ordered mesoporous carbons synthesized by a modified sol–gel process for electrosorptive removal of sodium chloride. Carbon, 47(3): 775–781

[14]

Liu D, Huang K, Xie L, Tang H L (2015). Relation between operating parameters and desalination performance of capacitive deionization with activated carbon electrodes. Environmental Science. Water Research & Technology, 1(4): 516–522

[15]

Liu P, Yan T, Shi L, Park H S, Chen X, Zhao Z, Zhang D (2017a). Graphene-based materials for capacitive deionization. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 5(27): 13907–13943

[16]

Liu P, Yan T, Zhang J, Shi L, Zhang D (2017b). Separation and recovery of heavy metal ions and salt ions from wastewater by 3D graphene-based asymmetric electrodes via capacitive deionization. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 5(28): 14748–14757

[17]

Montgomery D C (2012) Design and Analysis of Experiments, 8th ed. Hoboken: John Wiley & Sons

[18]

Montgomery D C (2017) Design and Analysis of Experiments, 13th ed. Hoboken: John Wiley & Sons

[19]

Ohshima H, Furusawa K (1998) Electrical phenomena at interfaces: Fundamentals: Measurements, and applications, 2nd ed. Boca Raton: CRC Press

[20]

Oren Y, Soffer A (1983). Water desalting by means of electrochemical parametric pumping. Journal of Applied Electrochemistry, 13(4): 473–487

[21]

Pekala R W, Farmer J C, Alviso C T, Tran T D, Mayer S T, Miller J M, Dunn B (1998). Carbon aerogels for electrochemical applications. Journal of Non-Crystalline Solids, 225: 74–80

[22]

Porada S, Weinstein L, Dash R, van der Wal A, Bryjak M, Gogotsi Y, Biesheuvel P M (2012). Water desalination using capacitive deionization with microporous carbon electrodes. ACS Applied Materials & Interfaces, 4(3): 1194–1199

[23]

Raymundo‐Piñero E, Leroux F, Béguin F (2006). A high-performance carbon for supercapacitors obtained by carbonization of a seaweed biopolymer. Advanced Materials, 18(14): 1877–1882

[24]

Ryoo M W, Seo G (2003). Improvement in capacitive deionization function of activated carbon cloth by titania modification. Water Research, 37(7): 1527–1534

[25]

Saber A, Mortazavian S, James D E, Hasheminejad H (2017). Optimization of collaborative photo-fenton oxidation and coagulation for the treatment of petroleum refinery wastewater with scrap iron. Water, Air, and Soil Pollution, 228(8): 312

[26]

Saboorian-Jooybari H, Chen Z (2019). Calculation of re-defined electrical double layer thickness in symmetrical electrolyte solutions. Results in Physics, 15: 102501

[27]

Shi W, Zhou X, Li J, Meshot E R, Taylor A D, Hu S, Kim J H, Elimelech M, Plata D L (2018). High-performance capacitive deionization via manganese oxide-coated, vertically aligned carbon nanotubes. Environmental Science & Technology Letters, 5(11): 692–700

[28]

Singh K, Porada S, de Gier H D, Biesheuvel P M, de Smet L C P M (2019). Timeline on the application of intercalation materials in Capacitive Deionization. Desalination, 455: 115–134

[29]

Tsouris C, Mayes R, Kiggans J, Sharma K, Yiacoumi S, DePaoli D, Dai S (2011). Mesoporous carbon for capacitive deionization of saline water. Environmental Science & Technology, 45(23): 10243–10249

[30]

Wang M, Xu X, Tang J, Hou S A, Hossain M S, Pan L, Yamauchi Y (2017a). High performance capacitive deionization electrodes based on ultrathin nitrogen-doped carbon/graphene nano-sandwiches. Chemical Communications, 53(78): 10784–10787

[31]

Wang S, Li X, Zhao H, Quan X, Chen S, Yu H (2018). Enhanced adsorption of ionizable antibiotics on activated carbon fiber under electrochemical assistance in continuous-flow modes. Water Research, 134: 162–169

[32]

Wang Z, Dou B, Zheng L, Zhang G, Liu Z, Hao Z (2012). Effective desalination by capacitive deionization with functional graphene nanocomposite as novel electrode material. Desalination, 299: 96–102

[33]

Wang Z, Xu X, Kim J, Malgras V, Mo R, Li C, Lin Y, Tan H, Tang J, Pan L, Bando Y, Yang T, Yamauchi Y (2019). Nanoarchitectured metal–organic framework/polypyrrole hybrids for brackish water desalination using capacitive deionization. Materials Horizons, 6(7): 1433–1437

[34]

Wang Z, Yan T, Chen G, Shi L, Zhang D (2017b). High salt removal capacity of metal–organic gel derived porous carbon for capacitive deionization. ACS Sustainable Chemistry & Engineering, 5(12): 11637–11644

[35]

Xing F, Li T, Li J, Zhu H, Wang N, Cao X (2017). Chemically exfoliated MoS2 for capacitive deionization of saline water. Nano Energy, 31: 590–595

[36]

Xu P, Drewes J E, Heil D, Wang G (2008). Treatment of brackish produced water using carbon aerogel-based capacitive deionization technology. Water Research, 42(10–11): 2605–2617

[37]

Xu X, Allah A E, Wang C, Tan H, Farghali A A, Khedr M H, Malgras V, Yang T, Yamauchi Y (2019). Capacitive deionization using nitrogen-doped mesostructured carbons for highly efficient brackish water desalination. Chemical Engineering Journal, 362: 887–896

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