Competitive adsorption and desorption of copper and lead in some soil of North China

Fengjie ZHANG, Xiaoxia OU, Shuo CHEN, Chunqiu RAN, Xie QUAN

PDF(220 KB)
PDF(220 KB)
Front. Environ. Sci. Eng. ›› 2012, Vol. 6 ›› Issue (4) : 484-492. DOI: 10.1007/s11783-012-0423-x
RESEARCH ARTICLE
RESEARCH ARTICLE

Competitive adsorption and desorption of copper and lead in some soil of North China

Author information +
History +

Abstract

The competitive adsorption and desorption of Pb(II) and Cu(II) ions in the soil of three sites in North China were investigated using single and binary metal solutions with 0.01 mol·L-1 CaCl2 as background electrolyte. The desorption isotherms of Pb(II) and Cu(II) were similar to the adsorption isotherms, which can be fitted well by Freundlich equation (R2>0.96). The soil in the three sites had greater sorption capacities for Pb(II) than Cu(II), which was affected strongly by the soil characteristics. In the binary metal solution containing 1∶1 molar ratio of Pb(II) and Cu(II), the total amount of Pb(II) and Cu(II) adsorption was affected by the simultaneous presence of the two metal ions, indicating the existence of adsorption competition between the two metal ions. Fourier transform infrared (FT-IR) spectroscopy was used to investigate the interaction between soil and metal ions, and the results revealed that the carboxyl and hydroxyl groups in the soil were the main binding sites of metal ions.

Keywords

competitive adsorption / desorption / copper / lead / soil

Cite this article

Download citation ▾
Fengjie ZHANG, Xiaoxia OU, Shuo CHEN, Chunqiu RAN, Xie QUAN. Competitive adsorption and desorption of copper and lead in some soil of North China. Front Envir Sci Eng, 2012, 6(4): 484‒492 https://doi.org/10.1007/s11783-012-0423-x

References

[1]
Bhuiyan M A H, Parvez L, Islam M A, Dampare S B, Suzuki S. Heavy metal pollution of coal mine-affected agricultural soils in the northern part of Bangladesh. Journal of Hazardous Materials, 2010, 173(1-3): 384–392
CrossRef Pubmed Google scholar
[2]
Thévenot D R, Moilleron R, Lestel L, Gromaire M C, Rocher V, Cambier P, Bonté P, Colin J L, de Pontevès C, Meybeck M. Critical budget of metal sources and pathways in the Seine River basin (1994-2003) for Cd, Cr, Cu, Hg, Ni, Pb and Zn. The Science of the Total Environment, 2007, 375(1-3): 180–203
CrossRef Pubmed Google scholar
[3]
Jung M C. Contamination by Cd, Cu, Pb, and Zn in mine wastes from abandoned metal mines classified as mineralization types in Korea. Environmental Geochemistry and Health, 2008, 30(3): 205–217
CrossRef Pubmed Google scholar
[4]
Nriagu J O, Pacyna J M. Quantitative assessment of worldwide contamination of air, water and soils by trace metals. Nature, 1988, 333(6169): 134–139
CrossRef Pubmed Google scholar
[5]
Paulson A J. The transport and fate of Fe, Mn, Cu, Zn, Cd, Pb and SO4 in a groundwater plume and in downstream surface waters in the Coeur d'Alene Mining District, Idaho, U.S.A. Applied Geochemistry, 1997, 12(4): 447–464
CrossRef Google scholar
[6]
Chen K P, Jiao J J. Metal concentrations and mobility in marine sediment and groundwater in coastal reclamation areas: a case study in Shenzhen, China. Environmental Pollution, 2008, 151(3): 576–584
CrossRef Pubmed Google scholar
[7]
Lu S G, Xu Q F. Competitive adsorption of Cd, Cu, Pb and Zn by different soils of Eastern China. Environmental Geology, 2009, 57(3): 685–693
CrossRef Google scholar
[8]
Vasudevan D, Cooper E M, Van Exem O L. Sorption-desorption of ionogenic compounds at the mineral-water interface: study of metal oxide-rich soils and pure-phase minerals. Environmental Science & Technology, 2002, 36(3): 501–511
CrossRef Pubmed Google scholar
[9]
Vega F A, Covelo E F, Andrade M L. Competitive sorption and desorption of heavy metals in mine soils: influence of mine soil characteristics. Journal of Colloid and Interface Science, 2006, 298(2): 582–592
CrossRef Pubmed Google scholar
[10]
Scheinost A C, Abend S, Pandya K I, Sparks D L. Kinetic controls on Cu and Pb sorption by ferrihydrite. Environmental Science & Technology, 2001, 35(6): 1090–1096
CrossRef Pubmed Google scholar
[11]
Trivedi P, Axe L. Predicting divalent metal sorption to hydrous Al, Fe, and Mn oxides. Environmental Science & Technology, 2001, 35(9): 1779–1784
CrossRef Pubmed Google scholar
[12]
Srivastava P, Singh B, Angove M. Competitive adsorption behavior of heavy metals on kaolinite. Journal of Colloid and Interface Science, 2005, 290(1): 28–38
CrossRef Pubmed Google scholar
[13]
Jalali M, Moharrami S. Competitive adsorption of trace elements in calcareous soils of western Iran. Geoderma, 2007, 140(1-2): 156–163
CrossRef Google scholar
[14]
Covelo E F, Vega F A, Andrade M L. Simultaneous sorption and desorption of Cd, Cr, Cu, Ni, Pb, and Zn in acid soils I. selectivity sequences. Journal of Hazardous Materials, 2007, 147(3): 852–861
CrossRef Pubmed Google scholar
[15]
Serrano S, Garrido F, Campbell C G, García-González M T. Competitive sorption of cadmium and lead in acid soils of Central Spain. Geoderma, 2005, 124(1-2): 91–104
CrossRef Google scholar
[16]
Papageorgiou S K, Katsaros F K, Kouvelos E P, Kanellopoulos N K. Prediction of binary adsorption isotherms of Cu2+, Cd2+ and Pb2+ on calcium alginate beads from single adsorption data. Journal of Hazardous Materials, 2009, 162(2-3): 1347–1354
Pubmed
[17]
Wang S B, Terdkiatburana T, Tadé M O. Single and co-adsorption of heavy metals and humic acid on fly ash. Separation and Purification Technology, 2008, 58(3): 353–358
CrossRef Google scholar
[18]
El-Bayaa A A, Badawy N A, Alkhalik E A. Effect of ionic strength on the adsorption of copper and chromium ions by vermiculite pure clay mineral. Journal of Hazardous Materials, 2009, 170(2-3): 1204–1209
CrossRef Pubmed Google scholar
[19]
Vaughan T, Seo C W, Marshall W E. Removal of selected metal ions from aqueous solution using modified corncobs. Bioresource Technology, 2001, 78(2): 133–139
CrossRef Pubmed Google scholar
[20]
Entezari M H, Soltani T. Simultaneous removal of copper and lead ions from a binary solution by sono-sorption process. Journal of Hazardous Materials, 2008, 160(1): 88–93
CrossRef Pubmed Google scholar
[21]
Mohapatra H, Gupta R. Concurrent sorption of Zn(II), Cu(II) and Co(II) by Oscillatoria angustissima as a function of pH in binary and ternary metal solutions. Bioresource Technology, 2005, 96(12): 1387–1398
CrossRef Pubmed Google scholar
[22]
Mouni L, Merabet D, Robert D, Bouzaza A.Batch studies for the investigation of the sorption of the heavy metals Pb2+ and Zn2+ onto Amizour soil (Algeria). Geoderma, 2009, 154(1-2): 30–35
CrossRef Google scholar
[23]
Díaz-Barrientos E, Madrid L, Maqueda C, Morillo E, Ruiz-Cortés E, Basallote E, Carrillo M. Copper and zinc retention by an organically amended soil. Chemosphere, 2003, 50(7): 911–917
CrossRef Pubmed Google scholar
[24]
Merdy P, Gharbi L T, Lucas Y. Pb, Cu and Cr interactions with soil: sorption experiments and modeling. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2009, 347(1-3): 192–199
CrossRef Google scholar
[25]
Pehlivan E, Ozkan A M, Dinç S, Parlayici S. Adsorption of Cu2+ and Pb2+ ion on dolomite powder. Journal of Hazardous Materials, 2009, 167(1-3): 1044–1049
CrossRef Pubmed Google scholar
[26]
Wang F, Pan G X, Li L Q. Effects of free iron oxyhydrates and soil organic matter on copper sorption-desorption behavior by size fractions of aggregates from two paddy soils. Journal of Environmental Sciences-China, 2009, 21(5): 618–624
CrossRef Pubmed Google scholar
[27]
Usman R A. The relative adsorption selectivities of Pb, Cu, Zn, Cd and Ni by soils developed on shale in New Valley, Egypt. Geoderma, 2008, 144(1-2): 334–343
CrossRef Google scholar
[28]
De Matos A T, Fontes M P F, da Costa L M, Martinez M A. Mobility of heavy metals as related to soil chemical and mineralogical characteristics of Brazilian soils. Environmental pollution, 2001, 111(3): 429–435
CrossRef Pubmed Google scholar
[29]
Lee S Z, Chang L Z, Yang H H, Chen C M, Liu M C. Adsorption characteristics of lead onto soils. Journal of Hazardous Materials, 1998, 63(1): 37–49
CrossRef Google scholar
[30]
Dyer J A, Trivedi P, Scrivner N C, Sparks D L. Lead sorpion onto ferrihydrite. 2. Surface complexation modeling. Environmental Science & Technology, 2003, 37(5): 915–922
CrossRef Pubmed Google scholar
[31]
Viventsova Ruth E, Kumpiene J, Gunneriusson L, Holmgren A. Changes in soil organic matter composition and quantity with distance to a nickel smelter — a case study on the Kola Peninsula, NW Russia. Geoderma, 2005, 127(3-4): 216–226
CrossRef Google scholar
[32]
Futalan C M, Kan C C, Dalida M L, Hsien K J, Pascua C, Wan M W. Comparative and competitive adsorption of copper, lead, and nickel using chitosan immobilized on bentonite. Carbohydrate Polymers, 2011, 83(2): 528–536
CrossRef Google scholar
[33]
Arias M, Pérez-Novo C, Osorio F, López E, Soto B. Adsorption and desorption of copper and zinc in the surface layer of acid soils. Journal of Colloid and Interface Science, 2005, 288(1): 21–29
CrossRef Pubmed Google scholar
[34]
Trivedi P, Axe L, Dyer J. Adsorption of metal ions onto goethite: single-adsorbate and competitive systems. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2001, 191(1-2): 107–121
CrossRef Google scholar
[35]
Arias M, Pérez-Novo C, López E, Soto B. Competitive adsorption and desorption of copper and zinc in acid soils. Geoderma, 2006, 133(3-4): 151–159
CrossRef Google scholar
[36]
Singh A, Kumar D, Gaur J P. Copper(II) and lead(II) sorption from aqueous solution by non-living Spirogyra neglecta. Bioresource Technology, 2007, 98(18): 3622–3629
CrossRef Pubmed Google scholar
[37]
Flogeac K, Guillon E, Aplincourt M. Competitive sorption of metal ions onto a north-eastern France soil. Isotherms and XAFS studies. Geoderma, 2007, 139(1-2): 180–189
CrossRef Google scholar
[38]
Oh S, Kwak M Y, Shin W S. Competitive sorption of lead and cadmium onto sediments. Chemical Engineering Journal, 2009, 152(2-3): 376–388
CrossRef Google scholar
[39]
Ma L, Xu R K, Jiang J. Adsorption and desorption of Cu(II) and Pb(II) in paddy soils cultivated for various years in the subtropical China. Journal of Environmental Sciences-China, 2010, 22(5): 689–695
CrossRef Pubmed Google scholar
[40]
Qiu W, Zheng Y. Removal of lead, copper, nickel, cobalt, and zinc from water by a cancrinite-type zeolite synthesized from fly ash. Chemical Engineering Journal, 2009, 145(3) 483–488
CrossRef Google scholar
[41]
Arias M, Barral M T, Mejuto J C. Enhancement of copper and cadmium adsorption on kaolin by the presence of humic acids. Chemosphere, 2002, 48(10): 1081–1088
CrossRef Pubmed Google scholar
[42]
Sposito G. The Surface Chemistry of Soil. New York: Oxford University Press, 1984
[43]
Wan Y, Bao Y Y, Zhou Q X. Simultaneous adsorption and desorption of cadmium and tetracycline on cinnamon soil. Chemosphere, 2010, 80(7): 807–812
CrossRef Pubmed Google scholar
[44]
Lim S F, Zheng Y M, Zou S W, Chen J P. Characterization of copper adsorption onto an alginate encapsulated magnetic sorbent by a combined FT-IR, XPS, and mathematical modeling study. Environmental Science & Technology, 2008, 42(7): 2551–2556
CrossRef Pubmed Google scholar
[45]
Iqbal M, Saeed A, Zafar S I. FTIR spectrophotometry, kinetics and adsorption isotherms modeling, ion exchange, and EDX analysis for understanding the mechanism of Cd2+ and Pb2+ removal by mango peel waste. Journal of Hazardous Materials, 2009, 164(1): 161–171
CrossRef Pubmed Google scholar

Acknowledgements

This work was gratefully acknowledged from the National Basic Research Program of China (No. 2007CB407302) and Young Independent Research Foundation of Dalian Nationalities University (No. DC11035).

RIGHTS & PERMISSIONS

2014 Higher Education Press and Springer-Verlag Berlin Heidelberg
AI Summary AI Mindmap
PDF(220 KB)

Accesses

Citations

Detail

Sections
Recommended

/