Solution properties and self-association of multi-blocks like copolymer P(AM/AA) prepared by template copolymerization

Abstract

The association and properties of multi-block like copolymers (TP) of acrylamide (AM) and acrylic acid (AA) prepared by template copolymerization in aqueous solution were studied. The results showed that the copolymers of this type exhibited a significant structure effect compared with that of similar random copolymers (CP) obtained by copolymerization in the absence of template. Decreasing the value of pH or adding Ca²⁺ ion to the copolymer solution will make phase separation occur. The TEM images demonstrated that the phase separation caused by Ca²⁺ ion was due to the formation of extensively intermolecular cross-linking. With the increase of the pH value of copolymer solution, the changes of the solution viscosity was similar with that of homopolyacrylic acid, which originally increased and then decreased. But the increase range of template copolymer was higher than that of homopolyacrylic acid. TEM images indicated that at the maximal viscosity the copolymer obtained in the presence of template formed coiled aggregates.

Keywords

Template copolymer P(AM/AA), structure effect, association, phase-separation