Properties of La1-xCexCoO3 system perovskite-type catalysts for diesel engine exhaust removal

Abstract

A series of complex oxide La_1-xCe_xCoO₃ catalysts was synthesized at a low temperature through a combustion process, in which x is among 0, 0.1, 0.2, 0.4 and 0.6 corresponding to the quantity of La³⁺ partial substitution by Ce⁴⁺. The catalysts were characterized for phase composition using chemical analysis and X-ray diffraction. The catalytic activity of the catalysts in removal of NO_x, total hydrocarbon (THC) and particulate matter (PM) from diesel exhaust gases were examined in detail using temperature-programmed reaction technique. The results show that after partial substitution of La³⁺ with Ce⁴⁺, the oxygen vacancy concentration increases significantly and a Co³⁺-Co²⁺ system is formed. Consequently, the catalytic activity in the removal of THC and NO_x is significantly improved. But for the PM, the effect is not so obvious. The possible catalytic mechanism for this was presented. It is also worth noting that the doped catalysts showed good stability.

Keywords

perovskite, catalysis, diesel engine, doped