Development of mobile miniature natural gas liquefiers
Yanxing ZHAO, Maoqiong GONG, Haocheng WANG, Hao GUO, Xueqiang DONG
Development of mobile miniature natural gas liquefiers
With increasing consumption of natural gas (NG), small NG reservoirs, such as coalbed methane and oil field associated gas, have recently drawn significant attention. Owing to their special characteristics (e.g., scattered distribution and small output), small-scale NG liquefiers are highly required. Similarly, the mixed refrigerant cycle (MRC) is suitable for small-scale liquefaction systems due to its moderate complexity and power consumption. In consideration of the above, this paper reviews the development of mobile miniature NG liquefiers in Technical Institute of Physics and Chemistry (TIPC), China. To effectively liquefy the scattered NG and overcome the drawbacks of existing technologies, three main improvements, i.e., low-pressure MRC process driven by oil-lubricated screw compressor, compact cold box with the new designed heat exchangers, and standardized equipment manufacturing and integrated process technology have been made. The development pattern of “rapid cluster application and flexible liquefaction center” has been eventually proposed. The small-scale NG liquefier developed by TIPC has reached a minimum liquefaction power consumption of about 0.35 kW·h/Nm3. It is suitable to exploit small remote gas reserves which can also be used in boil-off gas reliquefaction and distributed peak-shaving of pipe networks.
natural gas / mobile miniature liquefiers / mixed refrigerant cycle / vapor liquid equilibrium / heat transfer
[1] |
Shi G, Jing Y, Wang S, Zhang X T. Development status of liquefied natural gas industry in China. Energy Policy, 2010, 38(11): 7457–7465
CrossRef
Google scholar
|
[2] |
Zhang G, Dou L, Xu Y. Opportunities and challenges of natural gas development and utilization in China. Clean Technologies and Environmental Policy, 2019, 21(6): 1193–1211
CrossRef
Google scholar
|
[3] |
Zou C, Zhao Q, Chen J, Li J, Yang Z, Sun Q, Lu J, Zhang G. Natural gas in China: development trend and strategic forecast. Natural Gas Industry B, 2018, 5(4): 380–390
CrossRef
Google scholar
|
[4] |
National Development and Reform Commission of the People’s Republic of China. Opinions on accelerating the utilization of natural gas. 2017–7–4, available at website of ndrc.gov.cn
|
[5] |
National Bureau of Statistics of the People’s Republic of China. The national economic and social development statistical bulletin in 2016. 2017–2–28, available at the website of stats.gov.cn
|
[6] |
National Bureau of Statistics. China Statistical Yearbook. 2018–5–29, available at the website of stats.gov.cn
|
[7] |
BP. BP statistical review of world energy. 2019–07–30, available at the website of BP company
|
[8] |
Miller S, Michalak A, Detmers R, Hasekamp O P, Bruhwiler L M P, Schwietzke S. China’s coal mine methane regulations have not curbed growing emissions. Nature Communications, 2019, 10(1): 303
CrossRef
Google scholar
|
[9] |
He T, Liu Z, Ju Y, Parvez A M. A comprehensive optimization and comparison of modified single mixed refrigerant and parallel nitrogen expansion liquefaction process for small-scale mobile LNG plant. Energy, 2019, 167: 1–12
CrossRef
Google scholar
|
[10] |
Qyyum M, Qadeer K, Lee M. Comprehensive review of the design optimization of natural gas liquefaction processes: current status and perspectives. Industrial & Engineering Chemistry Research, 2018, 57(17): 5819–5844
CrossRef
Google scholar
|
[11] |
Kanoğlu M. Exergy analysis of multistage cascade refrigeration cycle used for natural gas liquefaction. International Journal of Energy Research, 2002, 26(8): 763–774
CrossRef
Google scholar
|
[12] |
Lee I, Tak K, Kwon H, Kim J, Ko D, Moon I. Design and optimization of a pure refrigerant cycle for natural gas liquefaction with subcooling. Industrial & Engineering Chemistry Research, 2014, 53(25): 10397–10403
CrossRef
Google scholar
|
[13] |
Andress D, Watkins R. Beauty of simplicity: Phillips optimized cascade LNG liquefaction process. AIP Conference Proceedings, 2004, 710: 91–100
CrossRef
Google scholar
|
[14] |
He T, Ju Y. Performance improvement of nitrogen expansion liquefaction process for small-scale LNG plant. Cryogenics, 2014, 61: 111–119
CrossRef
Google scholar
|
[15] |
He T, Ju Y. A novel conceptual design of parallel nitrogen expansion liquefaction process for small-scale LNG (liquefied natural gas) plant in skid-mount packages. Energy, 2014, 75: 349–359
CrossRef
Google scholar
|
[16] |
Chang H, Chung M, Lee S, Choe K H. An efficient multi-stage Brayton-JT cycle for liquefaction of natural gas. Cryogenics, 2011, 51(6): 278–286
CrossRef
Google scholar
|
[17] |
Yuan Z, Cui M, Xie Y, Li C. Design and analysis of a small-scale natural gas liquefaction process adopting single nitrogen expansion with carbon dioxide pre-cooling. Applied Thermal Engineering, 2014, 64(1–2): 139–146
CrossRef
Google scholar
|
[18] |
Chen S, Niu L, Zeng Q, Li X, Lou F, Chen L, Hou Y. Thermodynamic analysis on of skid-mounted coal-bed methane liquefaction device using cryogenic turbo-expander. IOP Conference Series, Materials Science and Engineering, 2017, 278(1): 012027
CrossRef
Google scholar
|
[19] |
Ancona M, Bianchi M, Branchini L, De Pascale A, Melino F. Performance increase of a small-scale liquefied natural gas production process by means of turbo-expander. Energy Procedia, 2017, 105: 4859–4865
CrossRef
Google scholar
|
[20] |
Swenson L K. Single mixed refrigerant, closed loop process for liquefying natural gas. US Patent, 05/739793, 1977
|
[21] |
Nogal F, Kim J, Perry S, Smith R. Optimal design of mixed refrigerant cycles. Industrial & Engineering Chemistry Research, 2008, 47(22): 8724–8740
CrossRef
Google scholar
|
[22] |
Chang H. A thermodynamic review of cryogenic refrigeration cycles for liquefaction of natural gas. Cryogenics, 2015, 72: 127–147
CrossRef
Google scholar
|
[23] |
Remeljej C, Hoadley A. An exergy analysis of small-scale liquefied natural gas (LNG) liquefaction processes. Energy, 2006, 31(12): 2005–2019
CrossRef
Google scholar
|
[24] |
Nguyen T, Rothuizen E, Markussen W, Elmegaard B. Thermodynamic comparison of three small-scale gas liquefaction systems. Applied Thermal Engineering, 2018, 128: 712–724
CrossRef
Google scholar
|
[25] |
Wang Q, Song Q, Zhang J, Liu R, Zhang S, Chen G. Experimental studies on a natural gas liquefaction process operating with mixed refrigerants and a rectifying column. Cryogenics, 2019, 99: 7–17
CrossRef
Google scholar
|
[26] |
Pillarella M, Liu Y N, Petrowski J, Bower R. The C3MR liquefaction cycle: versatility for a fast growing, ever changing LNG industry. In: Gas Technology Institute–15th International Conference and Exhibition on Liquified Natural Gas 2007, Barcelona, Spain, 2007, 1: 139–152
|
[27] |
Gaumer L, Newton C. Combined cascade and multicomponent refrigeration system and method. US Patent, 05/002447, 1973
|
[28] |
Castillo L, Majzoub Dahouk M, Di Scipio S, Dorao C A. Conceptual analysis of the precooling stage for LNG processes. Energy Conversion and Management, 2013, 66: 41–47
CrossRef
Google scholar
|
[29] |
Gong M, Wu J, Sun Z, Liu J, Hu Q. Development and performance test of a small trailer-mounted moveable natural gas liquefier. Energy Conversion and Management, 2012, 57: 148–153
CrossRef
Google scholar
|
[30] |
Castillo L, Dorao C. On the conceptual design of pre-cooling stage of LNG plants using propane or an ethane/propane mixture. Energy Conversion and Management, 2013, 65: 140–146
CrossRef
Google scholar
|
[31] |
Newton C. Dual mixed refrigerant natural gas liquefaction with staged compression. US Patent, 4525185, 1985
|
[32] |
Gadhiraju V, Timmerhaus Klaus D. Rizzuto C. Cryogenic Mixed Refrigerant Processes. New York: Springer, 2008
|
[33] |
Khan M S, Karimi I, Lee M. Evolution and optimization of the dual mixed refrigerant process of natural gas liquefaction. Applied Thermal Engineering, 2016, 96: 320–329
CrossRef
Google scholar
|
[34] |
Hwang J, Roh M, Lee K. Determination of the optimal operating conditions of the dual mixed refrigerant cycle for the LNG FPSO topside liquefaction process. Computers & Chemical Engineering, 2013, 49: 25–36
CrossRef
Google scholar
|
[35] |
Bukowski J D, Liu Y N, Pillarella M R, Boccella S J, Kennington W A. Natural gas liquefaction technology for floating LNG facilities. In: 17th International Conference & Exhibition on Liquefied Natural Gas 2013 (LNG 2013), Houston, TX, USA, 2013, 2: 1342–1353
|
[36] |
Chang H, Park J, Gwak K, Choe K H. Nitrogen expander cycles for large capacity liquefaction of natural gas. AIP Conference Proceedings, 2014, 1573: 1652–1657
CrossRef
Google scholar
|
[37] |
Khan M, Karimi I, Wood D. Retrospective and future perspective of natural gas liquefaction and optimization technologies contributing to efficient LNG supply: a review. Journal of Natural Gas Science and Engineering, 2017, 45: 165–188
CrossRef
Google scholar
|
[38] |
He T, Karimi I, Ju Y. Review on the design and optimization of natural gas liquefaction processes for onshore and offshore applications. Chemical Engineering Research & Design, 2018, 132: 89–114
CrossRef
Google scholar
|
[39] |
Maytal B, Pfotenhauer J. Mixed coolant cryocooling. In: Miniature Joule-Thomson Cryocooling. New York: Springer, 2013, 277–334
|
[40] |
Gong M, Wu J, Luo E. Performances of the mixed-gases Joule–Thomson refrigeration cycles for cooling fixed-temperature heat loads. Cryogenics, 2004, 44(12): 847–857
CrossRef
Google scholar
|
[41] |
Peng D, Robinson D. A new two-constant equation of state. Industrial & Engineering Chemistry Fundamentals, 1976, 15(1): 59–64
CrossRef
Google scholar
|
[42] |
Redlich O, Kwong J. On the thermodynamics of solutions. V. An equation of state. Fugacities of gaseous solutions. Chemical Reviews, 1949, 44(1): 233–244
CrossRef
Google scholar
|
[43] |
Soave G. Equilibrium constants from a modified Redlich-Kwong equation of state. Chemical Engineering Science, 1972, 27(6): 1197–1203
CrossRef
Google scholar
|
[44] |
Nguyen T, Elmegaard B. Assessment of thermodynamic models for the design, analysis and optimisation of gas liquefaction systems. Applied Energy, 2016, 183: 43–60
CrossRef
Google scholar
|
[45] |
Austbø B. Use of optimization in evaluation and design of liquefaction processes for natural gas. Dissertation for the Doctoral Degree. Trondheim: Norwegian University of Science and Technology, 2015
|
[46] |
Dauber F, Span R. Modelling liquefied-natural-gas processes using highly accurate property models. Applied Energy, 2012, 97: 822–827
CrossRef
Google scholar
|
[47] |
Yuan Z, Cui M, Song R, Xie Y. Evaluation of prediction models for the physical parameters in natural gas liquefaction processes. Journal of Natural Gas Science and Engineering, 2015, 27: 876–886
CrossRef
Google scholar
|
[48] |
Zhao Y, Dong X, Gong M, Guo H, Shen J, Wu J. Apparatus for low-temperature investigations: phase equilibrium measurements for systems containing ammonia. Journal of Chemical & Engineering Data, 2016, 61(11): 3883–3889
CrossRef
Google scholar
|
[49] |
Dong X, Gong M, Shen J, Wu J. Vapor-liquid equilibria of the trans-1, 3, 3, 3-tetrafluoropropene (R1234ze (E))+isobutane (R600a) system at various temperatures from (258.150 to 288.150) K. Journal of Chemical & Engineering Data, 2012, 57(2): 541–544
CrossRef
Google scholar
|
[50] |
Guo H, Gong M, Dong X, Wu J. A static analytical apparatus for vapour pressures and (vapour+ liquid) phase equilibrium measurements with an internal stirrer and view windows. Journal of Chemical Thermodynamics, 2014, 76: 116–123
CrossRef
Google scholar
|
[51] |
Gong M, Li H, Guo H, Dong X, Wu J F. Apparatus for accurate density measurements of fluids based on a magnetic suspension balance. AIP Conference Proceedings, 2012, 1434(57): 1857–1864
CrossRef
Google scholar
|
[52] |
Zhong Q, Dong X, Zhao Y, Wang J, Zhang H, Li H, Guo H, Shen J, Gong M. Adiabatic calorimeter for isochoric specific heat capacity measurements and experimental data of compressed liquid R1234yf. Journal of Chemical Thermodynamics, 2018, 125: 86–92
CrossRef
Google scholar
|
[53] |
Wu J F, Gong M Q, Liu J L, Luo E C, Qi Y F, Hu Q C. A new type mixture refrigeration auto-cascade cycle with partial condensation and separation reflux exchanger and its preliminary experimental test. Advances in Cryogenic Engineering, 2002, 613(1): 887–892
CrossRef
Google scholar
|
[54] |
Gong M Q, Wu J F, Luo E C, Qi Y F, Hu Q C, Zhou Y. Further development of the mixture refrigeration cycle with a dephlegmation separator. In: Ross R G, eds. Cryocoolers. Boston: Springer, 2003: 603–608
|
[55] |
Li M, Gong M, Guo H, Sun Z, Wu J. Steady-state thermodynamic simulation and structural design of the dephlegmator used in mixed-refrigerant Joule-Thomson refrigerators. Applied Thermal Engineering, 2016, 106: 480–492
CrossRef
Google scholar
|
[56] |
Wu J, Gong M, Luo E. A mixed refrigerants Joule-Throttling cryogenic refrigeration cycle system with a dephlegmator. China Patent, ZL 00136709.9, 200 (in Chinese)
|
[57] |
Wu J, Gong M, Dong X,
|
[58] |
Gong M, Wu J, Luo E. Principle and Application of Mixed-Refrigerant Joule Thompson Refrigeration Technology. Beijing: China Science and Technology Press, 2014 (in Chinese)
|
[59] |
Sun Z, Gong M, Li Z, Wu J. Nucleate pool boiling heat transfer coefficients of pure HFC134a, HC290, HC600a and their binary and ternary mixtures. International Journal of Heat and Mass Transfer, 2007, 50(1–2): 94–104
CrossRef
Google scholar
|
[60] |
Zou X, Gong M, Chen G, Sun Z H, Zhang Y, Wu J F. Experimental study on saturated flow boiling heat transfer of R170/R290 mixtures in a horizontal tube. International Journal of Refrigeration, 2010, 33(2): 371–380
CrossRef
Google scholar
|
[61] |
Zhuang X, Gong M, Zou X, Chen G F, Wu J F. Experimental investigation on flow condensation heat transfer and pressure drop of R170 in a horizontal tube. International Journal of Refrigeration, 2016, 66: 105–120
CrossRef
Google scholar
|
[62] |
Chen H, Chen G, Zou X, Yao Y, Gong M. Experimental investigations on bubble departure diameter and frequency of methane saturated nucleate pool boiling at four different pressures. International Journal of Heat and Mass Transfer, 2017, 112: 662–675
CrossRef
Google scholar
|
[63] |
Gong M, Wu Y, Ding L, Cheng K, Wu J. Visualization study on nucleate pool boiling of ethane, isobutane and their binary mixtures. Experimental Thermal and Fluid Science, 2013, 51: 164–173
CrossRef
Google scholar
|
[64] |
Yang Z, Gong M, Chen G, Zou X, Shen J. Two-phase flow patterns, heat transfer and pressure drop characteristics of R600a during flow boiling inside a horizontal tube. Applied Thermal Engineering, 2017, 120: 654–671
CrossRef
Google scholar
|
[65] |
Zhuang X, Gong M, Chen G, Zou X, Shen J. Two-phase flow pattern map for R170 in a horizontal smooth tube. International Journal of Heat and Mass Transfer, 2016, 102: 1141–1149
CrossRef
Google scholar
|
[66] |
Gong M, Song Q, Chen G, Zhuang X, Yang Z, Yao Y. Boiling heat transfer characteristics for methane, ethane and their binary mixtures. Heat Transfer Engineering, 2020, 41(1): 1–16
CrossRef
Google scholar
|
[67] |
Song Q, Chen G, Xue H, Zhao Y, Gong M. R14 flow condensation heat transfer performance: measurements and modeling based on two-phase flow patterns. International Journal of Heat and Mass Transfer, 2019, 136: 298–311
CrossRef
Google scholar
|
[68] |
Tang Q, Chen G, Yang Z, Shen J, Gong M Q. Numerical investigation on gas flow heat transfer and pressure drop in the shell side of spiral-wound heat exchangers. Science China. Technological Sciences, 2018, 61(4): 506–515
CrossRef
Google scholar
|
[69] |
Zou X, Gong M, Wu J. A spiral tube heat exchanger with a variable diameter tube winding. China Patent, ZL 201510351126.8, 2017 (in Chinese)
|
[70] |
Chen G, Gong M, Wu J. A plate-fin heat exchanger. China Patent, ZL 201510385761.8, 2017 (in Chinese)
|
[71] |
Gong M, Wu J, Chen G. A reentrant flow plate-fin heat exchanger. China Patent, ZL 201310192611.6, 2015 (in Chinese)
|
[72] |
Wu J, Gong M, Dong X, Shen J. A variable channel cross-sectional heat exchange. China Patent, ZL201210290661.3, 2015 (in Chinese)
|
[73] |
Gong M, Wu J, Chen G, Dong X. A plate-fin heat exchanger with fluid flow back in the channel. China Patent, ZL201210553623.2, 2014 (in Chinese)
|
[74] |
Li J, Gong M, Tang Q, Sun Z, Zou X, Chen G, Wu J. Design of coiled-wound heat exchanger in small plant of LNG. CIESC Journal, 2015, 66: 108–115 (in Chinese)
|
[75] |
Song Q, Zhang J, Zhao Z, Luo J, Wang Q, Chen G. Development of natural gas liquefaction processes using mixed refrigerants: a review of featured process configurations and performance. Journal of Zhejiang University–Science A, 2019, 20(10): 727–780
CrossRef
Google scholar
|
[76] |
Kountz K J, Kriha K, Liss W E,
|
[77] |
Nekså P, Brendeng E, Drescher M, Norberg B. Development and analysis of a natural gas reliquefaction plant for small gas carriers. Journal of Natural Gas Science and Engineering, 2010, 2(2–3): 143–149
CrossRef
Google scholar
|
[78] |
Li K. Researches and practices of a small-scale liquefied natural gas apparatus. China Petroleum and Chemical Standard and Quality, 2012, 9: 100–101
|
[79] |
Wang H. The research of the liquefaction technology in Shanxi Dingbian LNG plant. Refrigeration, 2013, 32(3): 23–29 (in Chinese)
|
[80] |
Wang Q, Song Q, Zhang J, Liu R, Zhang S, Chen G. Performance analyses on four configurations of natural gas liquefaction process operating with mixed refrigerants and a rectifying column. Cryogenics, 2019, 97: 13–21
CrossRef
Google scholar
|
[81] |
Liu Y M, Li D J. Natural gas liquefaction technology in Taian Shenran LNG plant. Cryogenics and Superconductivity, 2009, 11: 3–10
|
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〈 | 〉 |