PDF
Abstract
Flexible and stretchable electrochromic displays (ECDs) perform a crucial function in Internet of Things (IoT) systems, as they have shown superior eye-friendly, energy-saving, mechanical (flexibility and stretchability) properties. They can be integrated with IoT devices and successfully applied as wearable and intelligent electronics. Flexible and stretchable ECD technology has shown promising potential but is still in the early stage of development. A systematic overview from comprehensive perspectives of materials selection and modification, structure design, and advanced fabrication methods of this technology is necessary. In this review, we concentrate on the strategies in substrates, active layers, and electrolyte aspects to fabricate high-performance flexible and stretchable ECDs. We have systematically summarized the materials selection/modification and device structure design in these strategies. We also outline recent advances in flexible and stretchable ECDs based on processing methods for electrode patterns, active layer patterns, electrolyte patterns, and ECD pixels. Moreover, the interactive visual displays integrating ECD pixels with different sensors have been elaborated. Finally, we outline the future directions for developing flexible and stretchable ECDs, focusing on materials, methods, and applications. These prospects aim to overcome the limitations in pattern resolution, electrolyte uniformity, and pixel size/number and realize the manufacturable, commercialized, scalable, and robust flexible ECDs. This review can further promote the basic research and advanced fabrication of flexible ECDs and facilitate the advancement of multifunctional displays to satisfy the increasing demand for next-generation flexible electronics.
Keywords
Electrochromic displays
/
flexible electronics
/
pattern design
/
pixelated displays
Cite this article
Download citation ▾
Wenting Wu, Pooi See Lee.
Flexible and stretchable electrochromic displays: strategies, recent advances, and prospects.
Soft Science, 2024, 4(3): 29 DOI:10.20517/ss.2024.21
| [1] |
Cai G,Lee PS.Next-generation multifunctional electrochromic devices.Acc Chem Res2016;49:1469-76
|
| [2] |
Kim DY,Sung G.Stretchable and reflective displays: materials, technologies and strategies.Nano Converg2019;6:21 PMCID:PMC6584625
|
| [3] |
Rogers JA.Electronics. Toward paperlike displays.Science2001;291:1502-3
|
| [4] |
Manda R,Lim YJ.Self-supported liquid crystal film for flexible display and photonic applications.J Mol Liq2019;291:111314
|
| [5] |
Lee HE,Park JH.Micro light-emitting diodes for display and flexible biomedical applications.Adv Funct Mater2019;29:1808075
|
| [6] |
Kim S,Lee S.Low-power flexible organic light-emitting diode display device.Adv Mater2011;23:3511-6
|
| [7] |
Choi MK,Hyeon T.Flexible quantum dot light-emitting diodes for next-generation displays.npj Flex Electron2018;2:23
|
| [8] |
Sun J,Park H.Fully R2R-printed carbon-nanotube-based limitless length of flexible active-matrix for electrophoretic display application.Adv Electron Mater2020;6:1901431
|
| [9] |
Park CB,Lee JE,Yoo SS.Flexible electrophoretic display driven by solution-processed organic TFT with highly stable bending feature.Org Electron2014;15:3538-45
|
| [10] |
Li H,Jiang H,Yin X.Fabrication and evaluation of flexible electrowetting display with support pillars.Nanoscale Adv2020;2:4077-84 PMCID:PMC9417288
|
| [11] |
Peng CY,Li CW.Flexible photonic crystal material for multiple anticounterfeiting applications.ACS Appl Mater Interfaces2018;10:9858-64
|
| [12] |
Fang H,Wu W.Progress in flexible electrochromic devices.J Inorg Mater2021;36:140-51
|
| [13] |
Wu W,Ma H,Wang Q.Self-powered rewritable electrochromic display based on WO3-x film with mechanochemically synthesized MoO3-y nanosheets.ACS Appl Mater Interfaces2021;13:20326-35
|
| [14] |
Beaujuge PM.Color control in pi-conjugated organic polymers for use in electrochromic devices.Chem Rev2010;110:268-320
|
| [15] |
Singh J,Shrivas S,Dubey A.Comparative study of structures of electrochromic device for flexible electrochromic display. In: 2023 International Conference on Device Intelligence, Computing and Communication Technologies, (DICCT); 2023 Mar 17-18; Dehradun, India. IEEE; 2023. pp. 290-5.
|
| [16] |
Wu W,Ma H,Wang H.Electrochromic devices constructed with water-in-salt electrolyte enabling energy-saving and prolonged optical memory effect.Chem Eng J2022;446:137122
|
| [17] |
Eh AL,Cheng X,Lee PS.Recent advances in flexible electrochromic devices: prerequisites, challenges, and prospects.Energy Technol2018;6:33-45
|
| [18] |
Zhou L,Fang H,Wu L.Self-doped tungsten oxide films induced by in situ carbothermal reduction for high performance electrochromic devices.J Mater Chem C2020;8:13999-4006
|
| [19] |
Qian C,Guo X,Liu P.High-contrast energy-efficient flexible electrochromic devices based on viologen derivatives and their application in smart windows and electrochromic displayers.Sol Energy Mat Sol C2024;266:112669
|
| [20] |
Sun P,Li Y.Deep eutectic solvent-based gel electrolytes for flexible electrochromic devices with excellent high/low temperature durability.InfoMat2023;5:e12363
|
| [21] |
Xue W,Liu F,Yan M.Self-powered flexible multicolor electrochromic devices for information displays.Research2023;6:0227 PMCID:PMC10501365
|
| [22] |
Chen BH,Hu CW,Ho KC.Printed multicolor high-contrast electrochromic devices.ACS Appl Mater Interfaces2015;7:25069-76
|
| [23] |
Yu Z,Xia F.The characteristics of indium tin oxide films prepared on various buffer layer-coated polymer substrates.Surf Coat Tech2009;204:131-4
|
| [24] |
Ersman P, Lassnig R, Strandberg J, Dyreklev P. Flexible active matrix addressed displays manufactured by screen printing.Adv Eng Mater2021;23:2000771
|
| [25] |
Andersson Ersman P,Tu D.Monolithic integration of display driver circuits and displays manufactured by screen printing.Flex Print Electron2020;5:024001
|
| [26] |
Lv X,Yang Y.Flexible laterally-configured electrochromic supercapacitor with feasible patterned display.Chem Eng J2023;458:141453
|
| [27] |
Nair NM,Ray D.Silver nanowire-based printable electrothermochromic ink for flexible touch-display applications.ACS Appl Mater Interfaces2021;13:34550-60
|
| [28] |
Kim DS,Keum K.A stretchable patch of multi-color electrochromic devices for driving integrated sensors and displaying bio-signals.Nano Energy2023;113:108607
|
| [29] |
Zhao SQ,Ming Z.Highly flexible electrochromic devices enabled by electroplated nickel grid electrodes and multifunctional hydrogels.Opt Express2019;27:29547-57
|
| [30] |
Layani M,Foo WL.Nanostructured electrochromic films by inkjet printing on large area and flexible transparent silver electrodes.Nanoscale2014;6:4572-6
|
| [31] |
Huang L,Wu X.Hybrid Ag/Ni mesh/PH 1000 transparent electrodes for high performance flexible electrochromic devices with exceptional stability.Flex Print Electron2023;8:025021
|
| [32] |
Kim KW,Kim SH.Spray-coated transparent hybrid electrodes for high-performance electrochromic devices on plastic.Org Electron2018;62:151-6
|
| [33] |
Wang JL,Li HH,Yu SH.Large area co-assembly of nanowires for flexible transparent smart windows.J Am Chem Soc2017;139:9921-6
|
| [34] |
Jensen J,Kim I,Jo J.Fast switching ITO free electrochromic devices.Adv Funct Mater2014;24:1228-33
|
| [35] |
Xue R,Ning L.Fabrication of flexible electrochromic devices with degradable and fully recyclable features.ACS Biomater Sci Eng2022;8:1320-8
|
| [36] |
Huang Y,Ren J,Peng H.A transparent, conducting tape for flexible electronics.Nano Res2016;9:917-24
|
| [37] |
Kim D,Ko Y,Kim JH.A facile approach for constructing conductive polymer patterns for application in electrochromic devices and flexible microelectrodes.ACS Appl Mater Interfaces2016;8:33175-82
|
| [38] |
Gao X,Wu M,Meng J.Multicolor electrochromic fabric with a simple structure of PEDOT:PSS/DMSO.Dyes Pigments2023;219:111642
|
| [39] |
Wang C,Cui P.Multicolor and multistage response electrochromic color-memory wearable smart textile and flexible display.ACS Appl Mater Interfaces2021;13:12313-21
|
| [40] |
Dubey A,Cochrane C.Textile based three-layer robust flexible and stable electrochromic display.IEEE Access2020;8:182918-29
|
| [41] |
Zhou Y,Wang H.Multicolor electrochromic fibers with helix-patterned electrodes.Adv Electron Mater2018;4:1800104
|
| [42] |
Zhu T,Chen J.Flexible electrochromic fiber with rapid color switching and high optical modulation.Nano Res2023;16:5473-9
|
| [43] |
Chen X,Deng J.Electrochromic fiber-shaped supercapacitors.Adv Mater2014;26:8126-32
|
| [44] |
Kang W,Chen J.Highly transparent conducting nanopaper for solid state foldable electrochromic devices.Small2016;12:6370-7
|
| [45] |
Sinha S,Yassin O.Electrochromic fabric displays from a robust, open-air fabrication technique.Adv Mater Technol2022;7:2100548
|
| [46] |
Li K,Wang H.Red, green, blue (RGB) electrochromic fibers for the new smart color change fabrics.ACS Appl Mater Interfaces2014;6:13043-50
|
| [47] |
Fan H,Liu X.Continuously processed, long electrochromic fibers with multi-environmental stability.ACS Appl Mater Interfaces2020;12:28451-60
|
| [48] |
Chou HH,Chortos A.A chameleon-inspired stretchable electronic skin with interactive colour changing controlled by tactile sensing.Nat Commun2015;6:8011 PMCID:PMC4560774
|
| [49] |
Yin L,Kim KN.A stretchable epidermal sweat sensing platform with an integrated printed battery and electrochromic display.Nat Electron2022;5:694-705
|
| [50] |
Kim Y,Im S.Design of intrinsically stretchable and highly conductive polymers for fully stretchable electrochromic devices.Sci Rep2020;10:16488 PMCID:PMC7536397
|
| [51] |
Matsuhisa N,O’Neill SJK.High-frequency and intrinsically stretchable polymer diodes.Nature2021;600:246-52
|
| [52] |
Cai G,Cheng X,Lee PS.Inkjet-printed metal oxide nanoparticles on elastomer for strain-adaptive transmissive electrochromic energy storage systems.Sci Technol Adv Mat2018;19:759-70
|
| [53] |
Wu W,Lv J.Self-powered and light-adaptable stretchable electrochromic display.Adv Energy Mater2023;13:2204103
|
| [54] |
Yan C,Wang J.Stretchable and wearable electrochromic devices.ACS Nano2014;8:316-22
|
| [55] |
Liu Q,Qiu W.Ultraflexible, stretchable and fast-switching electrochromic devices with enhanced cycling stability.RSC Adv2018;8:18690-7 PMCID:PMC9080614
|
| [56] |
Wu W,Ma H,Zhang W.Boosting transport kinetics of ions and electrons simultaneously by Ti3C2Tx (MXene) addition for enhanced electrochromic performance.Nanomicro Lett2020;13:20 PMCID:PMC8187520
|
| [57] |
Kim DS,Kim JW,Jung G.A stretchable array of high-performance electrochromic devices for displaying skin-attached multi-sensor signals.Chem Eng J2022;429:132289
|
| [58] |
Ding Y,Mei Z.Flexible inorganic all-solid-state electrochromic devices toward visual energy storage and two-dimensional color tunability.ACS Appl Mater Interfaces2023;15:15646-56
|
| [59] |
Park H,Hong SY.A skin-integrated transparent and stretchable strain sensor with interactive color-changing electrochromic displays.Nanoscale2017;9:7631-40
|
| [60] |
Santiago-Malagón S,Azizkhani H,Guirado G.A self-powered skin-patch electrochromic biosensor.Biosens Bioelectron2021;175:112879
|
| [61] |
Kim DS,Hong SY.Low power stretchable active-matrix red, green, blue (RGB) electrochromic device array of poly(3-methylthiophene)/Prussian blue.Appl Surf Sci2019;471:300-8
|
| [62] |
Liu G,Wang J,Li Z.Employing polyaniline/viologen complementarity to enhance coloration and charge dissipation in multicolor electrochromic display with wide modulation range.J Colloid Interface Sci2024;655:493-507
|
| [63] |
Zhou F,Liu S,Wang M.Water-based additive-free chromic inks for printing of flexible photochromics and electrochromics.ACS Appl Mater Interfaces2023;15:49418-26
|
| [64] |
Wu C,Tan J.Electrochromic conjugated polymers containing benzotriazole and thiophene performing sub-second response time and 916 cm2 C-1 superb coloration efficiency.Sol Energy Mat Sol C2023;257:112355
|
| [65] |
Yin L,Sempionatto JR.A passive perspiration biofuel cell: high energy return on investment.Joule2021;5:1888-904
|
| [66] |
Zhang J,Higuchi M.Flexible multicolor rewritable paper coated with metallosupramolecular polymers for electrochromic printing and natural erasing by humidity.ACS Appl Polym Mater2023;5:6950-7
|
| [67] |
Mortimer RJ,Reynolds JR.Electrochromic organic and polymeric materials for display applications.Displays2006;27:2-18
|
| [68] |
Rao A,Hu J.Fabry-Perot cavity tunable multicolor flexible electrochromic device based on porous filter membrane.J Alloys Compd2023;969:172310
|
| [69] |
Wang Z,Cong S.Towards full-colour tunability of inorganic electrochromic devices using ultracompact fabry-perot nanocavities.Nat Commun2020;11:302 PMCID:PMC6965179
|
| [70] |
Chen J,Chen Z,Zhao Z.Fabry-Perot cavity-type electrochromic supercapacitors with exceptionally versatile color tunability.Nano Lett2020;20:1915-22
|
| [71] |
Brooke R,Iandolo D,Crispin X.Controlling the electrochromic properties of conductive polymers using UV-light.J Mater Chem C2018;6:4663-70
|
| [72] |
Zhang L,Yang P.Flexible pseudocapacitive electrochromics via inkjet printing of additive-free tungsten oxide nanocrystal ink.Adv Energy Mater2020;10:2000142
|
| [73] |
Moon HC,Lodge TP.Multicolored, low-power, flexible electrochromic devices based on ion gels.ACS Appl Mater Interfaces2016;8:6252-60
|
| [74] |
Di Noto V, Lavina S, Giffin GA, Negro E, Scrosati B. Polymer electrolytes: present, past and future.Electrochim Acta2011;57:4-13
|
| [75] |
Wu W,Wu L,Wang H.Temperature-dependent electrochromic devices for energy-saving dual-mode displays.ACS Appl Mater Interfaces2023;15:4113-21
|
| [76] |
Wu C,Huang K,Lin J.A photoelectrochromic device based on gel electrolyte with a fast switching rate.Sol Energy Mat Sol C2012;99:148-53
|
| [77] |
Fang H,Ma H.Dual-function biomimetic eyes based on thermally-stable organohydrogel electrolyte.Chem Eng J2022;438:135383
|
| [78] |
Chen D,Xu T,Chen H.Micropatterned PEDOT with enhanced electrochromism and electrochemical tunable diffraction.ACS Appl Mater Interfaces2021;13:58011-8
|
| [79] |
Pietsch M,Held M,Wieczorek A.Biodegradable inkjet-printed electrochromic display for sustainable short-lifecycle electronics.J Mater Chem C2020;8:16716-24
|
| [80] |
Thakur VK,Ma J,Lu X.Hybrid materials and polymer electrolytes for electrochromic device applications.Adv Mater2012;24:4071-96
|
| [81] |
Eh ALS,Lee PS.Advances in polymer electrolytes for electrochromic applications. In: Mortimer RJ, Rosseinsky DR, Monk PMS, editors. Electrochromic materials and devices. Wiley; 2013. pp. 289-310.
|
| [82] |
Jensen J.From the bottom up - flexible solid state electrochromic devices.Adv Mater2014;26:7231-4
|
| [83] |
Poh WC,Wu W,Lee PS.Rapidly photocurable solid-state poly(ionic liquid) ionogels for thermally robust and flexible electrochromic devices.Adv Mater2022;34:e2206952
|
| [84] |
Bai Z,Fang R.Divalent viologen cation-based ionogels facilitate reversible intercalation of anions in PProDOT-Me2 for flexible electrochromic displays.Adv Funct Mater2024;34:2312587
|
| [85] |
Song R,Zhang Y,Xiong S.Novel electrochromic materials based on chalcogenoviologens for smart windows, E-price tag and flexible display with improved reversibility and stability.Chem Eng J2021;422:130057
|
| [86] |
Kim J.Flexible and transparent electrochromic displays with simultaneously implementable subpixelated ion gel-based viologens by multiple patterning.Adv Funct Mater2019;29:1808911
|
| [87] |
Gu C,Zhang YM.Emerging electrochromic materials and devices for future displays.Chem Rev2022;122:14679-721 PMCID:PMC9523732
|
| [88] |
Kim JW,Jeong YR.Self-healing strain-responsive electrochromic display based on a multiple crosslinked network hydrogel.Chem Eng J2022;430:132685
|
| [89] |
Viñuales A,Cabañero G,Tena-zaera R.Incorporating paper matrix into flexible devices based on liquid electrochromic mixtures: Enhanced robustness, durability and multi-color versatility.Sol Energy Mat Sol C2017;167:22-7
|
| [90] |
Gu C,Jia A.A strategy of stabilization via active energy-exchange for bistable electrochromic displays.CCS Chem2022;4:2757-67
|
| [91] |
Lang AW,Reynolds JR.Paper-based electrochromic devices enabled by nanocellulose-coated substrates.Adv Funct Mater2019;29:1903487
|
| [92] |
Li S,Li Y.Dynamically transflective multicolor modulation via single metal-dielectric inorganic electrochromic electrode.Giant2024;17:100229
|
| [93] |
Moon HC,Frisbie CD.Solution processable, electrochromic ion gels for sub-1 V, flexible displays on plastic.Chem Mater2015;27:1420-5
|
| [94] |
Kim J,Myoung J.Rollable and transparent subpixelated electrochromic displays using deformable nanowire electrodes with improved electrochemical and mechanical stability.Chem Eng J2020;387:124145
|
| [95] |
Brooke R,Crispin X,Engquist I.Greyscale and paper electrochromic polymer displays by UV patterning.Polymers2019;11:267 PMCID:PMC6419265
|
| [96] |
Freitag K,Nilsson M,Beni V.Screen printed reflective electrochromic displays for paper and other opaque substrates.ACS Appl Opt Mater2023;1:578-86 PMCID:PMC9973558
|
| [97] |
Andersson Ersman P,Nilsson M.Electrochromic displays screen printed on transparent nanocellulose-based substrates.Adv Photon Res2023;4:2200012
|
| [98] |
Brooke R,Wijeratne K.Electrochromic displays manufactured by a combination of vapor phase polymerization and screen printing.Adv Mater Technol2022;7:2200054
|
| [99] |
Brooke R,Majee S,Dahlin A.All-printed multilayers and blends of poly(dioxythiophene) derivatives patterned into flexible electrochromic displays.Macro Mater Eng2023;308:2200453
|
| [100] |
Zhang CJ,Kremer MP.Additive-free MXene inks and direct printing of micro-supercapacitors.Nat Commun2019;10:1795 PMCID:PMC6470171
|
| [101] |
McManus D,Withers F.Water-based and biocompatible 2D crystal inks for all-inkjet-printed heterostructures.Nat Nanotechnol2017;12:343-50
|
| [102] |
Zhang Y,Zhao F.Inkjet printing for smart electrochromic devices.FlexMat2024;1:23-45
|
| [103] |
Cai G,Layani M.Direct inkjet-patterning of energy efficient flexible electrochromics.Nano Energy2018;49:147-54
|
| [104] |
Chen J,Eh AL.Scalable inkjet printing of electrochromic smart windows for building energy modulation.Adv Energy Sustain Res2022;3:2100172
|
| [105] |
Zhan Y,Cheng X.Ti-Doped WO3 synthesized by a facile wet bath method for improved electrochromism.J Mater Chem C2017;5:9995-10000
|
| [106] |
Cai G,Cheng X.Inkjet printed large area multifunctional smart windows.Adv Energy Mater2017;7:1602598
|
| [107] |
Cai G,Cui M.Inkjet-printed all solid-state electrochromic devices based on NiO/WO3 nanoparticle complementary electrodes.Nanoscale2016;8:348-57
|
| [108] |
Reinhardt K,Eberstein M.The importance of shear thinning, thixotropic and viscoelastic properties of thick film pastes to predict effects on printing performance. In: 2017 21st European Microelectronics and Packaging Conference (EMPC) & Exhibition; 2017 Sep 10-13; Warsaw, Poland. IEEE; 2017. p. 1-7.
|
| [109] |
Li X,Kim KW,Moon HC.Voltage-tunable dual image of electrostatic force-assisted dispensing printed, tungsten trioxide-based electrochromic devices with a symmetric configuration.ACS Appl Mater Interfaces2020;12:4022-30
|
| [110] |
Wang Q,Liu H.Chinese brushes: from controllable liquid manipulation to template-free printing microlines.Nano Res2015;8:97-105
|
| [111] |
Aller Pellitero M, del Campo FJ. Electrochromic sensors: innovative devices enabled by spectroelectrochemical methods.Curr Opin Electroche2019;15:66-72
|
| [112] |
Jang JE,Noh CH.P-167: 4.5” Electrochromic display with passive matrix driving.Symp Digest Tech Papers2008;39:1826-9
|
| [113] |
Ersman P, Kawahara J, Berggren M. Printed passive matrix addressed electrochromic displays.Org Electron2013;14:3371-8
|
| [114] |
Preston C,Nguyen NT.Intrinsically stretchable integrated passive matrix electrochromic display using PEDOT:PSS ionic liquid composite.ACS Appl Mater Interfaces2023;15:28288-99 PMCID:PMC10273228
|
| [115] |
Andersson Ersman P,Strandberg J.All-printed large-scale integrated circuits based on organic electrochemical transistors.Nat Commun2019;10:5053 PMCID:PMC6838054
|
| [116] |
Cao X,Liu Y.Fully screen-printed, large-area, and flexible active-matrix electrochromic displays using carbon nanotube thin-film transistors.ACS Nano2016;10:9816-22
|
| [117] |
Koo J,Kim SY.Low-power, deformable, dynamic multicolor electrochromic skin.Nano Energy2020;78:105199
|
| [118] |
Linderhed U,Ersman PA,Tybrandt K.Fully screen printed stretchable electrochromic displays.Flex Print Electron2021;6:045014
|
| [119] |
Howard EL,Shen DE,Pinheiro C.Cost-effective, flexible, and colorful dynamic displays: removing underlying conducting layers from polymer-based electrochromic devices.ACS Appl Mater Interfaces2021;13:16732-43
|
| [120] |
Bi S,Han X.Ultra-fast-responsivity with sharp contrast integrated flexible piezo electrochromic based tactile sensing display.Nano Energy2022;102:107629
|