Experimental study of Iranian heavy crude oil viscosity reduction by diluting with heptane, methanol, toluene, gas condensate and naphtha

Amir Hossein Saeedi Dehaghani , Mohammad Hasan Badizad

Petroleum ›› 2016, Vol. 2 ›› Issue (4) : 415 -424.

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Petroleum ›› 2016, Vol. 2 ›› Issue (4) :415 -424. DOI: 10.1016/j.petlm.2016.08.012
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Experimental study of Iranian heavy crude oil viscosity reduction by diluting with heptane, methanol, toluene, gas condensate and naphtha
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Abstract

Due to the high viscosity of heavy crude oils, production from these reservoirs is a demanding task. To tackle this problem, reducing oil viscosity is a promising approach. There are various methods to reduce viscosity of heavy oil: heating, diluting, emulsification, and core annular flow. In this study, dilution approach was employed, using industrial solvents and gas condensate. The viscosity of two Iranian heavy crude oils was measured by mixing with solvents at different temperatures. Dilution of both oil samples with toluene and heptane, resulted in viscosity reduction. However, their effect became less significant at higher concentrations of diluent. Because of forming hydrogen bonds, adding methanol to heavy crude oil resulted in higher viscosity. By adding condensate, viscosity of each sample reduced. Gas condensate had a greater impact on heavier oil; however, at higher temperatures its effect was reduced. Diluting with naphtha decreased heavy oil viscosity in the same way as n-heptane and toluene. Besides experimental investigation, different viscosity models were evaluated for prediction of heavy oil/solvent viscosity. It was recognized that Lederer' model is the best one.

Keywords

Heavy oil / Viscosity reduction / Dilution / Toluene / Methanol / n-Heptane / Naphtha / Gas condensate

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Amir Hossein Saeedi Dehaghani, Mohammad Hasan Badizad. Experimental study of Iranian heavy crude oil viscosity reduction by diluting with heptane, methanol, toluene, gas condensate and naphtha. Petroleum, 2016, 2(4): 415-424 DOI:10.1016/j.petlm.2016.08.012

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References

[1]

M.Z. Hasanvand, M.A. Ahmadi, R.M. Behbahani, Solving asphaltene precipitation issue in vertical wells via redesigning of production facilities, Petroleum 1 (2015) 139-145.

[2]

M. Mohammadpoor, F. Torabi, Extensive experimental investigation of the effect of drainage height and solvent type on the stabilized drainage rate in vapour extraction (VAPEX) process, Petroleum 1 (2015) 187-199.

[3]

M.H. Badizad, A.R. Zanganeh, A.H.S.D. Dehaghani, Simulation and assessment of surfactant injection in fractured reservoirs: a sensitivity analysis of some uncertain parameters, IJOGST 5 (2016) 13-26.

[4]

R.F. Meyer, Exploration for Heavy Crude Oil and Natural Bitumen, 1987.

[5]

O. Trevisan, F. Franca, A. Lisboa, O. Trevisan, F. Franca, A. Lisboa. Oil production in offshore fields: an overview of the Brazilian technology development program,in: Proceedings of the 1st world heavy oil conference, 2006.

[6]

L. Zhang, B. Youshu, L. Juyuan, L. Zheng, Z. Rifang, J. ZHANG, Movability of lacustrine shale oil: a case study of dongying sag, Jiyang depression, Bohai Bay basin, Pet. Explor. Dev. 41 (2014) 703-711.

[7]

W. Wei, W. Pengyu, K. Li, D. Jimiao, W. Kunyi, G. Jing, Prediction of the apparent viscosity of non-Newtonian water-in-crude oil emulsions, Pet. Explor. Dev. 40 (2013) 130-133.

[8]

R. Martínez-Palou, M. de Lourdes Mosqueira, B. Zapata-Rendón, E. Mar- Juárez, C. Bernal-Huicochea, J. de la Cruz Clavel-López, J. Aburto, Transportation of heavy and extra-heavy crude oil by pipeline: a review, J. Petrol Sci. Eng. 75 (2011) 274-282.

[9]

I. Henaut, J. Argillier, C. Pierre, M.Moan. Thermal flow properties of heavy oils, in: Offshore technology conference, offshore technology conference, 2003.

[10]

A. Saniere, I. Hénaut, J. Argillier, Pipeline transportation of heavy oils, a strategic, economic and technological challenge, Oil Gas Sci. Tech 59 (2004) 455-466.

[11]

J.J. Sheng, Status of surfactant EOR technology, Petroleum 1 (2015) 97-105.

[12]

H. Hu, Improving the efficiency of diluents for heavy oil pipeline transportation, in: Masters Abstracts International, 2008.

[13]

P. Gateau, I. Hénaut, L. Barré, J. Argillier, Heavy oil dilution, Oil Gas Sci. Tech 59 (2004) 503-509.

[14]

P. Luo, C. Yang, Y. Gu, Enhanced solvent dissolution into in-situ upgraded heavy oil under different pressures, Fluid Phase Equilib. 252 (2007) 143-151.

[15]

R. Urquhart, Heavy oil transportation-present and future, J. Can. Pet. Technol. 25 (1986).

[16]

J. Jimenez. The field performance of SAGD projects in Canada, in: International petroleum technology conference, 2008.

[17]

H. Nourozieh, M. Kariznovi, J. Abedi, Viscosity measurement and modeling for mixtures of Athabasca bitumen/hexane, J. Petroleum Sci. Eng. 129 (2015) 159-167.

[18]

J.F.P. Bassane, C.M. Sad, D.M. Neto, F.D. Santos, M. Silva, F.C. Tozzi, P.R. Filgueiras, E.V. de Castro, W. Rom-ao, M.F. Santos, Study of the effect of temperature and gas condensate addition on the viscosity of heavy oils, J. Petrol Sci. Eng. 142 (2016) 163-169.

[19]

P. Luo, Y. Gu, Characterization of a heavy oilepropane system in the presence or absence of asphaltene precipitation, Fluid Phase Equilib. 277 (2009) 1-8.

[20]

P. Luo, X. Wang, Y. Gu, Characterization of asphaltenes precipitated with three light alkanes under different experimental conditions, Fluid Phase Equilib. 291 (2010) 103-110.

[21]

P. Luo, Y. Gu, Effects of asphaltene content and solvent concentration on heavy oil viscosity, in: SPE International Thermal Operations and Heavy Oil Symposium, Society of Petroleum Engineers, 2005.

[22]

J. Argillier, C. Coustet, I. Henaut, Heavy oil rheology as a function of asphaltene and resin content and temperature, in: SPE International Thermal Operations and Heavy Oil Symposium and International Horizontal Well Technology Conference, Society of Petroleum Engineers, 2002.

[23]

J. Argillier, L. Barre, F. Brucy, J. Dournaux, I. Henaut, R. Bouchard, Influence of asphaltenes content and dilution on heavy oil rheology, in: SPE International Thermal Operations and Heavy Oil Symposium, Society of Petroleum Engineers, 2001.

[24]

M. Rahmes, W. Nelson, Viscosity blending relationships of heavy petroleum oils, Anal. Chem. 20 (1948) 912-915.

[25]

M. Cannon, M. Fenske, Viscosity measurement, Industrial Eng. Chem. Anal. Ed. 10 (1938) 297-301.

[26]

C.W.N. Garland, W. Joseph, D.P. Shoemaker, Experiments in Physical Chemistry. Experiments in Physical Chemistry. Series, 2003.

[27]

S.W. Hasan, M.T. Ghannam, N. Esmail, Heavy crude oil viscosity reduction and rheology for pipeline transportation, Fuel 89 (2010) 1095-1100.

[28]

C.M. Hansen, Hansen Solubility Parameters:A User's Handbook. Hansen Solubility Parameters: A User's Handbook. Series, CRC press, 2007.

[29]

S. Mortazavi-Manesh, J.M. Shaw, Effect of diluents on the rheological properties of Maya crude oil, Energy Fuels 30 (2016) 766-772.

[30]

M. Vafaie-Sefti, S. Mousavi-Dehghani, Application of association theory to the prediction of asphaltene deposition: deposition due to natural depletion and miscible gas injection processes in petroleum reservoirs, Fluid Phase Equilib. 247 (2006) 182-189.

[31]

A.H.S. Dehaghani, M.H. Badizad, Thermodynamic modeling of gas hydrate formation in presence of thermodynamic inhibitors with a new association equation of state, Fluid Phase Equilib. 427 (2016) 328-339.

[32]

J. Argillier, I. Henaut, J.-P. Heraud, P. Glenat, Heavy oil dilution, in: SPE International Thermal Operations and Heavy Oil Symposium, Society of Petroleum Engineers, 2005.

[33]

O.C. Mullins, H. Sabbah, J.l. Eyssautier, A.E. Pomerantz, L. Barré, A.B. Andrews, Y. Ruiz-Morales, F. Mostowfi, R. McFarlane, L. Goual, Advances in asphaltene science and the YeneMullins model, Energy Fuels 26 (2012) 3986-4003.

[34]

K. Pedersen, P. Thomassen, A. Fredenslund, Characterization of Gas Condensate Mixtures, American Institute of Chemical Engineers, New York, NY, 1988.

[35]

S. Arrhenius, Über die Dissociation der in Wasser gelösten Stoffe. Über die Dissociation der in Wasser gelösten Stoffe, Verlag von Wilhelm Engelmann, 1887.

[36]

J. Kendall, K.P. Monroe,The viscosity of liquids. Ii. The viscositycomposition curve for ideal liquid mixtures. 1, J. Am. Chem. Soc. 39 (1917) 1787-1802.

[37]

E. Bingham,The variable pressure method for the measurement of viscosity, Proc. Am. Soc. Test. Mater. 18 (1918) 10.

[38]

C. Walther, The evaluation of viscosity data, Erdol Teer 7 (1931) 382-384.

[39]

C. Cragoe, Changes in the viscosity of liquids with temperature, pressure and composition, in: 1st World Petroleum Congress, World Petroleum Congress, 1933.

[40]

E. Lederer,Viscosity of mixtures with and without diluents, Proc. World Pet. Cong Lond. 2 (1933) 526-528.

[41]

https://en.wikipedia.org.

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