Impact of hierarchical martensitic structure on deformation twinning in titanium alloys during additive manufacturing

Hao Wang , Xingdong Dan , Qi Chao , Nima Haghdadi , Zibin Chen , Sophie Primig , Wei Xu , Simon Ringer , Xiaozhou Liao

Microstructures ›› 2026, Vol. 6 ›› Issue (3) -2026047.

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Microstructures ›› 2026, Vol. 6 ›› Issue (3) -2026047. DOI: 10.20517/microstructures.2025.144
Research Article
Impact of hierarchical martensitic structure on deformation twinning in titanium alloys during additive manufacturing
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Abstract

A fully hierarchical martensitic microstructure is the common feature of additively manufactured α-type Ti alloys due to the rapid cooling rate inherent to the fabrication process. However, how this hierarchy governs defect formation within α laths under cyclic thermal loadings remains poorly understood. Here, we present a systematic electron microscopy investigation of a Ti-6Al-4V fabricated by laser powder-bed fusion. The as-fabricated microstructure consists of fine α′ martensite organised into multilevel lath hierarchies inherited from prior β grains. Deformation twinning is found to be strongly dependent on the martensitic hierarchy. Two types of twins are identified based on their thickness and interactions with martensitic laths. Twins that link to the endpoints of fine martensitic plates laths, i.e., linked twins, are consistently thicker than non-linked twins within lath interiors. Such twin structures enhance the room temperature tensile performance, enabling a simultaneous improvement in tensile strength, ductility, and work-hardening capability. These results demonstrate that hierarchical martensite actively governs twin formation in additively manufactured Ti alloys, elucidating the microstructural origin of their superior mechanical properties and providing guidance for microstructural optimization.

Keywords

Additive manufacturing / Ti alloys / deformation twinning / electron microscopy

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Hao Wang, Xingdong Dan, Qi Chao, Nima Haghdadi, Zibin Chen, Sophie Primig, Wei Xu, Simon Ringer, Xiaozhou Liao. Impact of hierarchical martensitic structure on deformation twinning in titanium alloys during additive manufacturing. Microstructures, 2026, 6(3): -2026047 DOI:10.20517/microstructures.2025.144

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References

[1]

Herzog D,Wycisk E.Additive manufacturing of metals.Acta Mater.2016;117:371-92

[2]

Elambasseril J,Mendis S.Effect of powder characteristics on layer density, defects, and tensile properties of Ti-6Al-4V via laser powder bed fusion: establishing benchmark parameters for quality.Prog. Addit. Manuf.2025;10:7449-70

[3]

Wang YM,McKeown JT.Additively manufactured hierarchical stainless steels with high strength and ductility.Nat. Mater.2018;17:63-71

[4]

Liu L,Zhong Y.Dislocation network in additive manufactured steel breaks strength-ductility trade-off.Mater. Today2018;21:354-61

[5]

Tan Q,Liang G.High performance plain carbon steels obtained through 3D-printing.Nat. Commun.2024;15:10077 PMCID:PMC11582704

[6]

Ren J,Zhao D.Strong yet ductile nanolamellar high-entropy alloys by additive manufacturing.Nature2022;608:62-8

[7]

Zhu T.Mechanical behaviour of additively manufactured metals.Nat. Mater.2026;25:373-85

[8]

Qian M,Brandt M.Additive manufacturing and postprocessing of Ti-6Al-4V for superior mechanical properties.MRS Bull.2016;41:775-84

[9]

Medvedev A,Piegert S.A novel metric for design of microstructure and mechanical properties in PBF-LB/M Ti6Al4V alloy.J. Mater. Process. Technol.2025;344:119031

[10]

Xu W,Sun S.Additive manufacturing of strong and ductile Ti-6Al-4V by selective laser melting via in situ martensite decomposition.Acta Mater.2015;85:74-84

[11]

Xu W,Pateras A,Brandt M.In situ tailoring microstructure in additively manufactured Ti-6Al-4V for superior mechanical performance.Acta Mater.2017;125:390-400

[12]

Zhang J,Bayat M.Achieving high ductility in a selectively laser melted commercial pure-titanium via in-situ grain refinement.Scr. Mater.2021;191:155-60

[13]

Liu Y,Tan Q,Li M.Mechanical performance of simple cubic architected titanium alloys fabricated via selective laser melting.Opt. Laser Technol.2021;134:106649

[14]

Zhang J,Sha G.Designing against phase and property heterogeneities in additively manufactured titanium alloys.Nat. Commun.2022;13:4660 PMCID:PMC9363443

[15]

Pan D,Liu L.Enhanced strength and ductility of nano-TiBw-reinforced titanium matrix composites fabricated by electron beam powder bed fusion using Ti6Al4V-TiBw composite powder.Addit. Manuf.2022;50:102519

[16]

Kumar S,Nandwana P,Yan C.Role of thermo-mechanical gyrations on the α/β interface stability in a Ti6Al4V AM alloy.Scr. Mater.2021;204:114134

[17]

Shao Z,Li P,Tan H.Mechanism of corrosion protection in reinforced Ti-6Al-4V alloy by wire arc additive manufacturing using magnetic arc oscillation.Mater. Charact.2023;199:112844

[18]

Wu B,Shao D.Enhanced corrosion performance in Ti-6Al-4V alloy produced via wire-arc directed energy deposition with magnetic arc oscillation.Addit. Manuf.2023;66:103465

[19]

Huang D,Chen H,Zhang M.Effects of processing parameters on a β-solidifying TiAl alloy fabricated by laser-based additive manufacturing.Microstructures2022;2:2022019

[20]

Yang J,Yin J,Wang Z.Formation and control of martensite in Ti-6Al-4V alloy produced by selective laser melting.Mater. Des.2016;108:308-18

[21]

Chen M,Van Petegem S.A quantitative study of thermal cycling along the build direction of Ti-6Al-4V produced by laser powder bed fusion.Mater. Des.2023;225:111458

[22]

Nishiyama Z.1 - Introduction to martensite and martensitic transformation. Martensitic Transformation. Elsevier; 1978. pp. 1-13.

[23]

Porter DA,Sherif MY.Phase transformations in metals and alloys, 4th ed. Boca Raton: CRC Press; 2021.

[24]

Qu S,Fu J,Zhang B.High-precision laser powder bed fusion processing of pure copper.Addit. Manuf.2021;48:102417

[25]

Liu Y,Guan S.Microstructure and mechanical behavior of additively manufactured CoCrFeMnNi high-entropy alloys: Laser directed energy deposition versus powder bed fusion.Acta Mater.2023;250:118884

[26]

Li YF,Ranabhat J.Formation mechanism and mechanical properties of surface nanocrystallized Ti-6Al-4V alloy processed by surface mechanical attrition treatment.Rare Metals2017;42:1343-52

[27]

Chao Y,Xu Z.Improving superficial microstructure and properties of the laser-processed ultrathin kerf in Ti-6Al-4V alloy by water-jet guiding.J. Mater. Sci. Technol.2023;156:32-53

[28]

Lu F,Liu E.Advancements in understanding the microstructure and properties of additive manufacturing Ti-6Al-4V alloy: a comprehensive review.J. Alloys Compd.2025;1027:180543

[29]

Randle V,Hu Y.Five-parameter grain boundary analysis of a titanium alloy before and after low-temperature annealing.Scr. Mater.2008;58:183-6

[30]

Burgers W.On the process of transition of the cubic-body-centered modification into the hexagonal-close-packed modification of zirconium.Physica1934;1:561-86

[31]

Farabi E,Rohrer GS.Five-parameter intervariant boundary characterization of martensite in commercially pure titanium.Acta Mater.2018;154:147-60

[32]

Guo Y,Wilkinson A.Slip band-grain boundary interactions in commercial-purity titanium.Acta Mater.2014;76:1-12

[33]

Wang H,Yang L.Introducing transformation twins in titanium alloys: an evolution of α-variants during additive manufacturing.Mater. Res. Lett.2020;9:119-26

[34]

Agnew S,Calhoun C.Connections between the basal I1 “growth” fault and <c+a?.Acta Mater.2015;82:255-65

[35]

Clausen B,Brown D.Reorientation and stress relaxation due to twinning: modeling and experimental characterization for Mg.Acta Mater.2008;56:2456-68

[36]

Beyerlein I,Tomé C.Effect of microstructure on the nucleation of deformation twins in polycrystalline high-purity magnesium: a multi-scale modeling study.J. Mech. Phys. Solids2011;59:988-1003

[37]

Li Y,Cao Y,Zhu Y.Grain size effect on deformation twin thickness in a nanocrystalline metal with low stacking-fault energy.J. Mater. Res.2019;34:2398-405

[38]

Lloyd JT.A dislocation-based model for twin growth within and across grains.Proc. Math. Phys. Eng. Sci.2018;474:20170709 PMCID:PMC5832837

[39]

Christian J.Deformation twinning.Prog. Mater. Sci.1995;39:1-157

[40]

Li K,Liu Y.Strengthening layer with nano-twins in titanium alloy induced by laser surface re-melting: mechanism of high strength and ductility.Mater. Charact.2023;196:112632

[41]

Zhang T,Yang T.In situ design of advanced titanium alloy with concentration modulations by additive manufacturing.Science2021;374:478-82

[42]

Vrancken B,Kruth J.Heat treatment of Ti6Al4V produced by Selective Laser Melting: microstructure and mechanical properties.J. Alloys Compd.2012;541:177-85

[43]

Lu L,Huang X.Revealing the maximum strength in nanotwinned copper.Science2009;323:607-10

[44]

Lu L,Chen X,Lu K.Ultrahigh strength and high electrical conductivity in copper.Science2004;304:422-6

[45]

Lu K,Suresh S.Strengthening materials by engineering coherent internal boundaries at the nanoscale.Science2009;324:349-52

[46]

Wen T,Wang R.Modelling of dislocations, twins and crack-tips in HCP and BCC Ti.Int. J. Plast.2023;166:103644

[47]

Zhang Z,Wang Z.Dislocation mechanisms and 3D twin architectures generate exceptional strength-ductility-toughness combination in CrCoNi medium-entropy alloy.Nat. Commun.2017;8:14390 PMCID:PMC5321736

[48]

Wang H,Yang R.Atomic modelling of crack initiation on twin boundaries in α-titanium under external tensile loading along various orientations.Philos. Mag. Lett.2014;94:779-85

[49]

Zhao S,Yu Q,Ritchie RO.Cryoforged nanotwinned titanium with ultrahigh strength and ductility.Science2021;373:1363-8

[50]

Lin X.Achieving strength-ductility synergy in zirconium via ultra-dense twin-twin networks.Acta Mater.2024;269:119825

[51]

Huang S,Zhao Y.Toughening effects of Mo and Nb addition on impact toughness and crack resistance of titanium alloys.J. Mater. Sci. Technol.2021;79:147-64

[52]

Vilaro T,Bartout JD.As-fabricated and heat-treated microstructures of the Ti-6Al-4V alloy processed by selective laser melting.Metall. Mater. Trans. A2011;42:3190-9

[53]

Su J,Liu J.Revealing the decomposition mechanisms of dislocations and metastable α' phase and their effects on mechanical properties in a Ti-6Al-4V alloy.J. Mater. Sci. Technol.2022;107:136-48

[54]

Pedrazzini S,Ackerman AK.Effect of substrate bed temperature on solute segregation and mechanical properties in Ti-6Al-4V produced by laser powder bed fusion.Metall. Mater. Trans. A2023;54:3069-85

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