Additively manufactured Ti-6Al-4V/Ta bimetal: from neutron diffraction residual stress analysis to wear and bioproperty testings

Hao Wang , Ke Ma , Jincheng Tang , Jing Zhao , Hancong Chen , Yinghao Zhou , Xiaoping Luo , Jiazheng Hao , Lunhua He , Ming Yan

Microstructures ›› 2026, Vol. 5 ›› Issue (2) -2026036.

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Microstructures ›› 2026, Vol. 5 ›› Issue (2) -2026036. DOI: 10.20517/microstructures.2025.04
Research Article
Additively manufactured Ti-6Al-4V/Ta bimetal: from neutron diffraction residual stress analysis to wear and bioproperty testings
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Abstract

Powder bed fusion-laser beam prepared Ti-6Al-4V/Ta bimetals can be well-suited for advanced biomedical applications. However, a few issues remain unsolved, including (a) understanding of residual stress distribution and its level in as-printed bimetal; and (b) wear and bio properties of the bimetal. This study aims to address these points through a series of investigations, including residual stress analysis by neutron diffraction, printing optimization, and analysis of heat treatment effect on the properties. It was discovered that the residual stress is highly related to the temperature gradient and Young’s modulus. In the interface region of the as-printed bimetal, the residual stress was reduced and inverted compared to the as-printed Ta alone, changing from ~ (140-180) MPa (tensile) to ~ (30-70) MPa (compressive), which may have helped the Ta layer bond effectively with the Ti-6Al-4V matrix. Meanwhile, a high residual stress (~ 390 MPa) in the Ti-6Al-4V part of the as-printed bimetal justifies the need for heat treatment. After heat treatment, the bimetal exhibited good biocompatibility and much improved wear and corrosion resistance compared to Ti-6Al-4V alone. These improvements may be attributed to the formation of tantalum oxide during friction and corrosion processes. Ta layer can also improve the biocompatibility due to its intrinsic noncytotoxic feature.

Keywords

Powder bed fusion-laser beam / neutron diffraction / residual stress / bimetal

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Hao Wang, Ke Ma, Jincheng Tang, Jing Zhao, Hancong Chen, Yinghao Zhou, Xiaoping Luo, Jiazheng Hao, Lunhua He, Ming Yan. Additively manufactured Ti-6Al-4V/Ta bimetal: from neutron diffraction residual stress analysis to wear and bioproperty testings. Microstructures, 2026, 5(2): -2026036 DOI:10.20517/microstructures.2025.04

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References

[1]

Tang J,Yao X.From bio-inertness to osseointegration and antibacterial activity: A one-step micro-arc oxidation approach for multifunctional Ti implants fabricated by additive manufacturing.Mater Des2022;221:110962

[2]

Salehi M,Montazeri A.Comprehensive study of sub-micron porous titanium-zirconium scaffolds fabricated by liquid metal dealloying.J Alloys Compd2025;1010:177137

[3]

Long M.Titanium alloys in total joint replacement - a materials science perspective.Biomaterials1998;19:1621-39

[4]

Ungersboeck A,Pohler O,Wuest W.Tissue reaction to bone plates made of pure titanium: a prospective, quantitative clinical study.J Mater Sci: Mater Med1995;6:223-9

[5]

Wang K.The use of titanium for medical applications in the USA.Mater Sci Eng: A1996;213:134-7

[6]

Rieu J,Rabbe L,Chabrol C.Structural modifications induced by ion implantation in metals and polymers used for orthopaedic prostheses.Mater Sci Technol1992;8:589-93

[7]

Wang C,Rang J.Joint replacement materials and friction wear.J Biomed Eng1997;14:64-67. (in Chinese)

[8]

Levine BR,Poggie RA,Jacobs JJ.Experimental and clinical performance of porous tantalum in orthopedic surgery.Biomaterials2006;27:4671-81

[9]

Bermúdez M,Martínez-nicolás G.Erosion-corrosion of stainless steels, titanium, tantalum and zirconium.Wear2005;258:693-700

[10]

Charoenpong H.Effect of metal ions released from orthodontic mini-implants on osteoclastogenesis.Dent Med Probl2021;58:327-33

[11]

Asri RIM,Samykano M.Corrosion and surface modification on biocompatible metals: A review.Mater Sci Eng C Mater Biol Appl2017;77:1261-74

[12]

Matsuno H,Watari F,Kawasaki T.Biocompatibility and osteogenesis of refractory metal implants, titanium, hafnium, niobium, tantalum and rhenium.Biomaterials2001;22:1253-62

[13]

Zhou L,Li R,Wang G.Selective laser melting of pure tantalum: Densification, microstructure and mechanical behaviors.Mater Sci Eng: A2017;707:443-51

[14]

Yang Y,Wei W.Microstructure and mechanical properties of TiC/Ti6Al4V nanocomposites fabricated by gas-liquid reaction laser powder bed fusion.Mater Sci Eng: A2023;869:144829

[15]

Lei P,Zhang T.Porous tantalum structure integrated on Ti6Al4V base by laser powder bed fusion for enhanced bony-ingrowth implants: in vitro and in vivo validation.Bioact Mater2022;7:3-13 PMCID:PMC8367833

[16]

Lian F,Wu C,Tang J.Selective laser melting additive manufactured tantalum: effect of microstructure and impurities on the strengthening-toughing mechanism.Materials (Basel)2023;16:3161 PMCID:PMC10143127

[17]

Valentino GM,Lark A,Myers SH.Influence of laser processing parameters on the density-ductility tradeoff in additively manufactured pure tantalum.Addit Manuf Lett2023;4:100117

[18]

Song C,Zou Z,Xu K.Pure tantalum manufactured by laser powder bed fusion: influence of scanning speed on the evolution of microstructure and mechanical properties.Int J Refract Met Hard Mater2022;107:105882

[19]

Livescu V,Gray GT,Morrow BM.Additively manufactured tantalum microstructures.Materialia2018;1:15-24

[20]

Gao H,Jin X.Porous tantalum scaffolds: Fabrication, structure, properties, and orthopedic applications.Mater Des2021;210:110095

[21]

Wauthle R,Amin Yavari S.Additively manufactured porous tantalum implants.Acta Biomater2015;14:217-25

[22]

Walker J,Lesko CC.Multi-material laser powder bed fusion additive manufacturing in 3-dimensions.Manuf Lett2022;31:74-7

[23]

Lesko C,Middendorf J.Functionally graded titanium-tantalum in the horizontal direction using laser powder bed fusion additive manufacturing.JOM2021;73:2878-84

[24]

Traxel KD.Modeling and experimental validation of additively manufactured tantalum-titanium bimetallic interfaces.Mater Des2021;207:109793

[25]

Huang S,de Looze G,Yeong WY.Laser powder bed fusion of titanium-tantalum alloys: compositions and designs for biomedical applications.J Mech Behav Biomed Mater2020;108:103775

[26]

Yan JJ,Li HX.Selective laser melting of H13: microstructure and residual stress.J Mater Sci2017;52:12476-85

[27]

Shabalin IL.Tantalum. In Ultra-high temperature materials I: Carbon (graphene/graphite) and refractory metals, Springer,2014; pp. 387-450.

[28]

Balla VK,Bose S.Direct laser processing of a tantalum coating on titanium for bone replacement structures.Acta Biomater2010;6:2329-34 PMCID:PMC2862814

[29]

Ren Y,Fu X,Chen J.Microstructure and deformation behavior of Ti-6Al-4V alloy by high-power laser solid forming.Acta Materialia2017;132:82-95

[30]

Tang Y,Peng Y,Long J.Dynamic restoration and texture evolution of pure tantalum during warm deformation.Int J Refract Met Hard Mater2023;115:106279

[31]

Yan M.An overview of densification, Microstructure and mechanical property of additively manufactured Ti-6Al-4V - comparison among selective laser melting, electron beam melting, laser metal deposition and selective laser sintering, and with conventional powder. In: Lakshmanan A, editor.Sintering Techniques of Materials,2015

[32]

Pant P,Luzin V.Mapping of residual stresses in as-built Inconel 718 fabricated by laser powder bed fusion: A neutron diffraction study of build orientation influence on residual stresses.Addit Manuf2020;36:101501

[33]

Nycz A,Noakes M.Effective residual stress prediction validated with neutron diffraction method for metal large-scale additive manufacturing.Mater Des2021;205:109751

[34]

Heeling T,Wegener K.Melt pool simulation for the evaluation of process parameters in selective laser melting.Addit Manuf2017;14:116-25

[35]

Menon N.Prediction of melt pool geometry by fusing experimental and simulation data.Int J Mech Sci2024;263:108786

[36]

Chen C,Yang S.Effect of the thickness of Ti intermediate layer on the microstructure and mechanical properties of the W/Ta multilayer composites.J Alloys Compd2021;867:158910

[37]

Standardization Administration of China. GB/T 8546-2017: Titanium clad stainless steel plate, Beijing: Standards Press of China; 2017.

[38]

Zhou YL,Akahori T.Effects of Ta content on young’s modulus and tensile properties of binary Ti-Ta alloys for biomedical applications.Mater Sci Eng: A2004;371:283-90

[39]

Sing SL,Wiria FE.Selective laser melting of titanium alloy with 50 wt% tantalum: Microstructure and mechanical properties.J Alloys Compd2016;660:461-70

[40]

Song M. L..Effect of laser selective melting process and subsequent heat treatment on the microstructure and properties of Ti-6Al-4V alloy, Shandong University, Master Degree Thesis, Shandong University, Jinan, Shandong, 2021.

[41]

Schmidt AA,Grabherr O.Transient wear simulation based on three-dimensional finite element analysis for a dry running tilted shaft-bushing bearing.Wear2018;408-9:171-9

[42]

Lin K,Gu D.Active screen plasma nitriding of laser powder bed fusion processed 316L stainless steel for the application of fuel cell bipolar plates.Virtual Phys Prototyp2023;18:e2225490

[43]

Shuai C,Feng P.Biodegradation mechanisms of selective laser-melted Mg- x Al-Zn alloy: grain size and intermetallic phase.Virtual Phys Prototyp2018;13:59-69

[44]

Gui N,Myers DE,Tang HP.The effect of ordered and partially ordered surface topography on bone cell responses: a review.Biomater Sci2018;6:250-64

[45]

Burkov AA,Krutikova VO.Electrospark Deposition of Ti-Ta coatings on Ti6Al4V titanium alloy: oxidation resistance and wear properties.Phys Mesomech2024;27:618-26

[46]

Zhao D,Li Y.Improvement on mechanical properties and corrosion resistance of titanium-tantalum alloys in-situ fabricated via selective laser melting.J Alloys Compd2019;804:288-98

[47]

Becker T,Ritchie R.An approximate method for residual stress calculation in functionally graded materials.Mech Mater2000;32:85-97

[48]

National Center for Biotechnology Information, 2024. Atomic Radius in the Periodic Table of Elements. Available from: https://pubchem.ncbi.nlm.nih.gov/periodic-table/atomic-radius (accessed 2025-6-5)

[49]

Tang M,Beuth JL.Prediction of lack-of-fusion porosity for powder bed fusion.Addit Manuf2017;14:39-48

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