Ameliorating the microstructure and mechanical properties of Al-Cu-Li alloy through aging temperature in a novel thermo-mechanical treatment

Xuanxi Xu , Xin Tong , Guohua Wu , Liang Zhang

Microstructures ›› 2025, Vol. 5 ›› Issue (4) : 2025089

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Microstructures ›› 2025, Vol. 5 ›› Issue (4) :2025089 DOI: 10.20517/microstructures.2024.143
Research Article

Ameliorating the microstructure and mechanical properties of Al-Cu-Li alloy through aging temperature in a novel thermo-mechanical treatment

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Abstract

Developing wrought aluminum-lithium alloys with high strength and ductility has been a longstanding objective in the aviation and aerospace industry. However, the conventional T8 thermo-mechanical treatment process faces challenges in overcoming the strength-ductility compromise in aluminum-lithium alloys. The precipitates-dislocation interaction is critical in governing the balance between strength and ductility. When the aging temperature exceeds 175 °C, the T1 phase thickens, making it difficult for slip dislocations to shear the coarser T1 phase. This results in severe matrix distortion near the precipitates, thereby reducing ductility. In contrast, aging at 150 °C promotes the formation of fine, shearable T1 phases, facilitating uniform plastic deformation across multiple slip planes and achieving a balance of high strength (~ 705 MPa) and ductility (~ 11.8%). Aging at 120 °C further improves ductility (~ 12.4%) due to the coexistence of sparse T1 phases and large amounts of Guinier-Preston (GP) zones, which promoted dislocation cross-slip. Our findings highlight the critical importance of precisely controlling the relative amount, size, and distribution of GP zones and T1 precipitates to achieve superior mechanical performance in Al-Cu-Li-Mg-Ag alloys.

Keywords

Al-Cu-Li alloy / precipitation / microstructure / mechanical properties

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Xuanxi Xu, Xin Tong, Guohua Wu, Liang Zhang. Ameliorating the microstructure and mechanical properties of Al-Cu-Li alloy through aging temperature in a novel thermo-mechanical treatment. Microstructures, 2025, 5(4): 2025089 DOI:10.20517/microstructures.2024.143

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References

[1]

Dursun T.Recent developments in advanced aircraft aluminium alloys.Mater Des (1980-2015)2014;56:862-71

[2]

Zhang X,Hu J.Recent advances in the development of aerospace materials.Prog Aerosp Sci2018;97:22-34

[3]

Xie Y,Guo X,Liang C.Modulation of precipitation behavior by dislocations and alloying for superior strength-ductility balance in Al-Cu-Li alloys.J Alloys Compd2025;1010:177334

[4]

Deng S,Zeng G.The precipitation evolution and mechanical properties of an Al-Cu-Li-Mg alloy during natural aging.J Mater Sci Technol2024;192:42-53

[5]

Yang X,Xue C.Enhancing strength and ductility of Al-Cu-Li alloys by microalloying both Er and Zr to promote complete transformation from δ’ (Al3Li) to T1 (Al2CuLi) precipitates.J Mater Res Technol2024;32:2913-30

[6]

Wang L,Ruan Y,Hu L.Influence of grain size on twinning behavior of WE43 magnesium alloy during room-temperature compression deformation.J Rare Earths2024;42:2285-92

[7]

Li S,Chen J.The effect of thermo-mechanical treatment on the formation of T1 phase and δ’/θ’/δ’ composite precipitate in an Al-Cu-Li-Mg alloy.Mater Charact2021;176:111123

[8]

Xu X,Zhang L.Effects of heat treatment and pre-stretching on the mechanical properties and microstructure evolution of extruded 2050 Al-Cu-Li alloy.Mater Sci Eng: A2022;845:143236

[9]

Lv P,Peng C.Improved strength and ductility of rapidly solidified 2195 alloy by pre-rolling combined with double aging and interrupted aging.Mater Sci Eng: A2023;873:145023

[10]

Xie B,Xu J.Effect of the aging process and pre-deformation on the precipitated phase and mechanical properties of 2195 Al-Li alloy.Mater Sci Eng: A2022;832:142394

[11]

Wang X,Jiang J,Wang X.Quantitative analysis of the influences of pre-treatments on the microstructure evolution and mechanical properties during artificial ageing of an Al-Cu-Li-Mg-Ag alloy.Mater Sci Eng: A2020;782:139253

[12]

Zou Y,Wu X,Guo M.Synergetic effect of natural ageing and pre-stretching on the ageing behavior in T’/η’ phase-strengthened Al-Zn-Mg-Cu alloys.J Mater Sci Technol2023;146:240-51

[13]

Rodgers B.Quantification of the influence of increased pre-stretching on microstructure-strength relationships in the Al-Cu-Li alloy AA2195.Acta Materialia2016;108:55-67

[14]

Huang L,Li S,Huang J.Effects of pre-stretch on microstructure, mechanical properties and corrosion resistance of 2A14 aluminum alloy.Trans Nonferrous Met Soc China2024;34:1065-80

[15]

Dai W,Yao J,Cao F.Simultaneously improving the strength and ductility of an Ag-free 2195 Al-Li alloy by T8 treatment with cryogenic pre-rolling.J Alloys Compd2024;976:173214

[16]

Dong F,Yi Y.Effect of increased stretching deformation at cryogenic temperature on the precipitation behavior and mechanical properties of 2060 Al-Li alloy.Mater Sci Eng: A2022;834:142585

[17]

Xiao Y,Cui H,Kong C.Microstructure evolution, mechanical response, and corrosion resistance for a 2195 Al-Li alloy under different rolling reductions during cryorolling.J Alloys Compd2024;997:174973

[18]

Xu J,Xu Y.Effect of pulsed electromagnetic field treatment on dislocation evolution and subsequent artificial aging behavior of 2195 Al-Li alloy.Mater Charact2022;187:111872

[19]

Xie B,Xu J,Li J.Microstructure evolution and strengthening mechanism of Al-Li alloy during thermo-electromagnetic forming process.J Mater Process Technol2023;315:117922

[20]

Xu X,Tong X.Enhancing strength-ductility synergy in an extruded Al-Cu-Li-Mg-Ag alloy via homogeneous GP zones and dislocation configuration.Mater Des2024;239:112766

[21]

Xu X,Tong X.Achieving superior strength-ductility balance by tailoring dislocation density and shearable GP zone of extruded Al-Cu-Li alloy.Int J Plast2024;182:104135

[22]

Li S,Ming W,Chen J.Genetic structural phase evolution from Li-containing S-like phase precipitates towards S-phase in AlCuLiMg alloys.Acta Materialia2022;233:117997

[23]

Xu X,Zhang L.New insight into enhancing the comprehensive mechanical performance in non-stretched Al-Cu-Li-(Mg)-(Ag)-Mn-Zr alloys.Mater Lett2024;360:135899

[24]

Chen K,Cao Y.Enhanced strength and ductility in an Al–Cu–Li alloy via long-term ageing.Mater Sci Eng: A2021;811:141092

[25]

Chen X,Xi H,Wang Y.Effects of heat treatment on the microstructure and mechanical properties of extruded 2196 Al-Cu-Li alloy.MaterDes2020;192:108746

[26]

Costa Teixeira J, Cram D, Bourgeois L, Bastow T, Hill A, Hutchinson C. On the strengthening response of aluminum alloys containing shear-resistant plate-shaped precipitates.Acta Materialia2008;56:6109-22

[27]

Yang J,Ma P,Zhan L.Superposed hardening from precipitates and dislocations enhances strength-ductility balance in Al-Cu alloy.Int J Plast2022;158:103413

[28]

Chen B,Wang R.Effect of interfacial solute segregation on ductile fracture of Al-Cu-Sc alloys.Acta Materialia2013;61:1676-90

[29]

Cui S,Liu M,Zhao G.Precipitation behavior of an Al-Cu-Li-X alloy and competing relationships among precipitates at different aging temperatures.Mater Sci Eng: A2021;814:141125

[30]

Liu C,Ma P,Chen L.Enhanced age-hardening response at elevated temperature by natural-ageing-modified precipitation in an Al-Cu-Li-Mg alloy.Mater Charact2023;199:112791

[31]

Allen SM.Foil thickness measurements from convergent-beam diffraction patterns.Philos Mag A1981;43:325-35

[32]

Dorin T,Chaix JM,Geuser F.Size distribution and volume fraction of T1 phase precipitates from TEM images: direct measurements and related correction.Micron2015;78:19-27

[33]

Wu M,Xiao D.Influence of thermal exposure on the microstructure evolution and mechanical behaviors of an Al-Cu-Li alloy.Mater Des2023;227:111767

[34]

Tsivoulas D.The effect of Mn and Zr dispersoid-forming additions on recrystallization resistance in Al-Cu-Li AA2198 sheet.Acta Materialia2014;77:1-16

[35]

Guo Y,Lu D.Characterization of Al3Zr precipitation via double-step homogenization and recrystallization behavior after subsequent deformation in 2195 Al-Li alloy.Mater Charact2021;182:111549

[36]

Ivanov R,De Geuser F.Clustering kinetics during natural ageing of Al-Cu based alloys with (Mg, Li) additions.Acta Materialia2018;157:186-95

[37]

Li Z,Chen H.θ’’’ precipitate phase, GP zone clusters and their origin in Al-Cu alloys.J Alloys Compd2023;930:167396

[38]

Zhang P,Bian J.Solute cluster evolution during deformation and high strain hardening capability in naturally aged Al-Zn-Mg alloy.Acta Materialia2021;207:116682

[39]

Chen Y,Hutchinson C.The effect of interrupted aging on the yield strength and uniform elongation of precipitation-hardened Al alloys.Acta Materialia2013;61:5877-94

[40]

Xu X,Zhang L.Regulation of precipitation behavior among T1, S’, and θ’ phases in Al-Cu-Li-(Mg-Ag) alloys by optimizing Ag/Mg ratios.Mater Sci Eng: A2023;876:145158

[41]

Dong Y,Tang J,Sun Q.The effects of temperature on the creep-aging behavior and mechanical properties of AA2050-T34 alloy.Mater Sci Eng: A2020;796:140010

[42]

Sun J,Zhang L,Liu L.Microstructure characteristics of an ultra-high strength extruded Al-4.7Cu-1Li-0.5Mg-0.1Zr-1Zn alloy during heat treatment.J Alloys Compd2020;813:152216

[43]

Ott N,Yan Y.Evolution of grain boundary precipitates in an Al-Cu-Li Alloy during aging.Metall Mater Trans A2017;48:51-6

[44]

Jiang L,Cheng PM.Microalloying ultrafine grained Al alloys with enhanced ductility.Sci Rep2014;4:3605 PMCID:PMC3884224

[45]

Lin J,Wang Y.Effect of La addition on microstructure, mechanical behavior, strengthening and toughening mechanisms of cast Mg-Gd-Zn alloy.Mater Sci Eng: A2023;866:144688

[46]

Bailey JE.The dislocation distribution, flow stress, and stored energy in cold-worked polycrystalline silver.Philos Mag1960;5:485-97

[47]

Dorin T,Geuser FD.Quantification and modelling of the microstructure/strength relationship by tailoring the morphological parameters of the T1 phase in an Al-Cu-Li alloy.Acta Materialia2014;75:134-46

[48]

Huang Y,Zheng Z.A conventional thermo-mechanical process of Al-Cu-Mg alloy for increasing ductility while maintaining high strength.Scripta Materialia2011;64:382-5

[49]

Chan K.A fracture model for hydride-induced embrittlement.Acta Metallurgica et Materialia1995;43:4325-35

[50]

Ashby MF.The deformation of plastically non-homogeneous materials.Philos Mag-J Theor Exp Appl Phys1970;21:399-424

[51]

Zeng G,Deng S.Detailed investigation on microstructure and strengthening contribution of Al-xCu-1.3Li-X alloy sheets.Mater Charact2023;205:113278

[52]

Deschamps A,De Geuser F,Weyland M.The influence of precipitation on plastic deformation of Al-Cu-Li alloys.Acta Materialia2013;61:4010-21

[53]

Noell PJ,Boyce BL.The mechanisms of ductile rupture.Acta Materialia2018;161:83-98

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