Microstructure and Properties of Vacuum Sintered Low Co Content WC Hard Materials

Xiaokui Jiang , Sizhuo Bao , Yi Cui , Yanling Dong , Weimin Wang

Journal of Wuhan University of Technology Materials Science Edition ›› 2025, Vol. 40 ›› Issue (4) : 1005 -1013.

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Journal of Wuhan University of Technology Materials Science Edition ›› 2025, Vol. 40 ›› Issue (4) : 1005 -1013. DOI: 10.1007/s11595-025-3138-0
Advanced Materials
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Microstructure and Properties of Vacuum Sintered Low Co Content WC Hard Materials

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Abstract

Low cobalt (Co) WC hard materials were prepared using vacuum sintering. The influences of Co content on the sintering densification behavior, grain growth characteristics, microstructure and mechanical properties of WC hard material were studied. The experimental results show that the addition of a small amount of Co significantly promotes the densification and reduces the sintering temperature. Meantime, the abnormal growth of WC grains was observed. When the sintering temperature is 1 300 °C and the content of Co is less than 1.0wt%, densed WC/Co hard material with fine grains is obtained. When the content of Co is 1wt%, the relative density, Vickers hardness, and flexural strength of WC material are 98.76±0.17%, 24.23±0.41 GPa, and 1 376±67 MPa, respectively. When the Co content is 0.25wt% and 0.5wt%, the optimal sintering temperature of the sample is 1 350 °C. Among them, the relative density, hardness, and flexural strength of WC-0.5wt% Co are 98.79±0.15%, 23.44±0.38 GPa, and 1 233±85 MPa, respectively.

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low cobalt content WC / sintering densification behavior / grain growth characteristics / mechanical properties

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Xiaokui Jiang, Sizhuo Bao, Yi Cui, Yanling Dong, Weimin Wang. Microstructure and Properties of Vacuum Sintered Low Co Content WC Hard Materials. Journal of Wuhan University of Technology Materials Science Edition, 2025, 40(4): 1005-1013 DOI:10.1007/s11595-025-3138-0

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References

[1]

FangZZ, WangX, RyuT, et al.. Synthesis, Sintering, and Mechanical Properties of Nanocrystalline Cemented Tungsten Carbide-A Review[J]. International Journal of Refractory Metals and Hard Materials, 2009, 27(2): 288-299

[2]

GarcíaJ, Collado CiprésV, BlomqvistA, et al.. Cemented Carbide Microstructures: A Review[J]. International Journal of Refractory Metals and Hard Materials, 2019, 80: 40-68

[3]

PellanM, LayS, MissiaenJ, et al.. A New Insight into the ∑=2 Grain Boundary Characteristics in WC Powder and in WC-Co Sintered Materials[J]. Acta Materialia, 2018, 155: 372-378

[4]

FangZZ, KoopmanMC, WangH. Cemented Tungsten Carbide Hardmetal-An Introduction[J]. Comprehensive Hard Materials, 2014, 1: 123-137

[5]

KimHC, ShonIJ, GarayJE, et al.. Consolidation and Properties of Binderless Sub-micron Tungsten Carbide by Field-activated Sintering[J]. International Journal of Refractory Metals & Hard Materials, 2004, 22(6): 257-264

[6]

TsaiK, HsiehC, LuH. Sintering of Binderless Tungsten Carbide[J]. Ceramics International, 2010, 36(2): 689-692

[7]

ChangL, JiangY, WangW, et al.. Ultrafine WC-0.5Co-xTaC Cemented Carbides Prepared by Spark Plasma Sintering[J]. International Journal of Refractory Metals and Hard Materials, 2019, 84104 994

[8]

KimH, OhD, ShonI. Synthesis of WC and Dense WC-xvol%Co Hard Materials by High-frequency Induction Heated Combustion Method[J]. International Journal of Refractory Metals and Hard Materials, 2004, 22(1): 41-49

[9]

ChangLF, RuHQ, ZhangMY, et al.. The Effect of Trace Co on Discharge Plasma Sintering of WC [J]. Journal of Ceramics, 2018, 39(05): 596-600

[10]

ChangL, JiangY, WangW, et al.. Ultrafine WC-0.5Co-xTaC Cemented Carbides Prepared by Spark Plasma Sintering[J]. International Journal of Refractory Metals and Hard Materials, 2019, 84104 994

[11]

ShiXL, ShaoGQ, DuanXL, et al.. Mechanical Properties, Phases and Microstructure of Ultrafine Hardmetals Prepared by WC-6.29Co Nanocrystalline Composite Powder[J]. Materials Science and Engineering: A, 2005, 392(1): 335-339

[12]

El-EskandaranyMS, MahdayA, AhmedHA, et al.. Synthesis and Characterizations of Ball-milled Nanocrystalline WC and Nanocomposite WC-Co Powders and Subsequent Consolidations[J]. Journal of Alloys and Compounds, 2000, 312(1–2): 315-325

[13]

GaoJX, FanJL. Research on Carbon Blending of Pressure Sintering Non bonded Ultra Fine Hard Alloy WC-0.27VC-0.53Cr3C2[J]. Powder Metallurgy Technology, 2012, 30: 334-340

[14]

YinfangW, XionghanT, LihuaL. Manufacture of ‘Both High’ Ultrafine Cemented Carbide[C]. International Conference on Hot Isostatic Pressing, 1999

[15]

LinXWPreparation and Performance Study of Ultra Fine Grained WC Hard Alloy with Few, Non Bonded Phases, 2012, Guangzhou. South China University of Technology. [D]

[16]

XiaoMD, XiaoW, JiangJL. Co Phase Structure of WC Co Hard Alloy [J]. Powder Metallurgy Materials Science and Engineering, 2010, 15(06): 611-614

[17]

ChaSI, HongSH. Microstructures of Binderless Tungsten Carbides Sintered by Spark Plasma Sintering Process[J]. Materials Science and Engineering: A, 2003, 356(1): 381-389

[18]

JianhongY, ZhongjianZ. Globe Developing Status on Cemented Carbide Composite Roll[C]. Zhuzhou International Conference on Cemented Carbides, 2012

[19]

LuZ, DuJ, SunY, et al.. Effect of Ultrafine WC Contents on the Microstructures, Mechanical Properties and Wear Resistances of Regenerated Coarse Grained WC-10Co Cemented Carbides[J]. International Journal of Refractory Metals and Hard Materials, 2021, 97105 516

[20]

PoetschkeJ, RichterV, GestrichT, et al.. Grain Growth during Sintering of Tungsten Carbide Ceramics[J]. International Journal of Refractory Metals and Hard Materials, 2014, 43: 309-316

[21]

CarrollDF. Sintering and Microstructural Development in WC/Co-based Alloys Made with Superfine WC Powder[J]. International Journal of Refractory Metals and Hard Materials, 1999, 17: 123-132

[22]

MannessonK, JeppssonJ, BorgenstamA, et al.. Carbide Grain Growth in Cemented Carbides[J]. Acta Materialia, 2011, 59(5): 1 912-1 923

[23]

BaoR, YiJH, YangYJ. Research on Microwave Sintering of Ultra Fine WC-Co Hard Alloy[J]. Powder Metallurgy Industry, 2010, 20: 22-26

[24]

SunJ, SimonSL. The Melting Behavior of Aluminum Nanoparticles[J]. Thermochimica Acta, 2007, 463: 32-40

[25]

XieMWThe Influence of Ultra fine Raw Material Characteristics and Wet Grinding Process on the Microstructure and Properties of WC-Co Hard Alloy, 2013, Changsha. Central South University. [D]

[26]

ZhuT, ZhangJ, AnD, et al.. Oscillatory Pressure Sintering: A New Method for Preparing WC-Co Cemented Carbides[J]. Journal of Alloys and Compounds, 2020, 816152 521

[27]

ChaSI, LeeKH, RyuHJ, et al.. Analytical Modeling to Calculate the Hardness of Ultra-fine WC-Co Cemented Carbides[J]. Materials Science and Engineering: A, 2008, 489(1): 234-244

[28]

LiZ, WangJJ, LinCG. The Influence of Microstructure of WC Co Ultrafine Hard Alloy on Its Properties[J]. Cemented Carbide, 2009, 26(03): 188-193

[29]

GurlandJ. The Fracture Strength of Sintered Tungsten Carbide-cobalt Alloys in Relation to Composition and Particle Spacing[J]. Transactions of the Metallurgical Society of Aime, 1963, 2271 146

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Wuhan University of Technology and Springer-Verlag GmbH Germany, Part of Springer Nature

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