Highly Transparent PVA Hydrogel with Enhanced Mechanical Properties and Electrical Conductivity by Doping with Cyclohexane-1,2,3,4,5,6-Hexacarboxylic Acid

Hu Gao , Fangqiang Yang , Fei Jin , Hongliang Ge , Xianjun Zhu , Qiong Wu , Ying Wang , Hua Yang

Journal of Wuhan University of Technology Materials Science Edition ›› 2025, Vol. 40 ›› Issue (2) : 338 -343.

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Journal of Wuhan University of Technology Materials Science Edition ›› 2025, Vol. 40 ›› Issue (2) : 338 -343. DOI: 10.1007/s11595-025-3069-9
Advanced Materials

Highly Transparent PVA Hydrogel with Enhanced Mechanical Properties and Electrical Conductivity by Doping with Cyclohexane-1,2,3,4,5,6-Hexacarboxylic Acid

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Abstract

Polyvinyl alcohol (PVA) hydrogels doped with cyclohexane-1,2,3,4,5,6-hexacarboxylic acid (CHA) were successfully prepared during drying and swelling. Structural and morphological characterizations suggest the carboxyl and hydroxyl groups in the material undergo esterification during the preparation of the material, which contributes to the high transparency with 90% transmittance in the 400 to 800 nm range and robust mechanical properties of the material with a tensile strength at a break of 27.55 MPa. It is noteworthy that the bending and torsion angles exhibit a strong linear correlation with electrical resistance, enabling the monitoring of the bending motion state of each human body segment.

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Hu Gao, Fangqiang Yang, Fei Jin, Hongliang Ge, Xianjun Zhu, Qiong Wu, Ying Wang, Hua Yang. Highly Transparent PVA Hydrogel with Enhanced Mechanical Properties and Electrical Conductivity by Doping with Cyclohexane-1,2,3,4,5,6-Hexacarboxylic Acid. Journal of Wuhan University of Technology Materials Science Edition, 2025, 40(2): 338-343 DOI:10.1007/s11595-025-3069-9

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References

[1]

YangCH, SuoZG. Hydrogel Ionotronics[J]. Nat. Rev. Mater., 2018, 3: 125

[2]

LiuJJ, QuSX, SuoZG, et al.. Functional Hydrogel Coatings[J]. Natl. Sci. Rev., 2021, 8(2): nwaa254

[3]

YuHW, LuBY, ZhaoXH. Hydrogel Bioelectronics[J]. Chem. Soc. Rev., 2019, 48: 1 642

[4]

HuynhTP, HaickHS. Autonomous Flexible Sensors for Health Monitoring[J]. Adv. Mater., 2018, 30: 1 802 337

[5]

GaoW, OtaHK, KiriyaDK, et al.. Flexible Electronics toward Wearable Sensing[J]. Acc. Chem. Res., 2019, 52: 523

[6]

PengQG, ChenJS, WangT, et al.. Recent Advances in Designing Conductive Hydrogels for Flexible Electronics[J]. Infor. Mat., 2020, 2: 843

[7]

HeJR, ChenYF, LiPJ, et al.. Three-dimensional CNT/graphene-sulfur Hybrid Sponges with High Sulfur Loading as Superior-capacity Cathodes for Lithium-sulfur Batteries[J]. J. Mater. Chem. A, 2020, 8: 18 605

[8]

GeG, ZhangJJS, WangWJ, et al.. Stretchable, Transparent, and Self-Patterned Hydrogel-Based Pressure Sensor for Human Motions Detection[J]. Adv. Funct. Mater., 2018, 28: 1 802 576

[9]

ZhangJQ, WanLJ, GaoY, et al.. Highly Stretchable and Self-Healable MXene/Polyvinyl Alcohol Hydrogel Electrode for Wearable Capacitive Electronic Skin[J]. Adv. Electron. Mater., 2019, 5: 1 900 285

[10]

MachRD, LazarPT, OtyM, et al.. Single Atom Catalysts: Anchoring of Transition Metals to Graphene Derivatives as an Efficient Approach for Designing Single-Atom Catalysts[J]. Adv. Mater. Interfaces, 2021, 8: 2 170 110

[11]

LiG, LiCG, LiGD, et al.. Development of Conductive Hydrogels for Fabricating Flexible Strain Sensors[J]. Small, 2022, 18: 2 101 518

[12]

AdelniaHS, EnsandoostRZ, MoonshiSB, et al.. Freeze/thawed Polyvinyl Alcohol Hydrogels: Present, Past and Future[J]. Eur. Polym. J., 2022, 164: 110 974

[13]

GregoryJH, BaranySD. Adsorption and Flocculation by Polymers and Polymer Mixtures[J]. Adv. Colloid Interface Sci., 2022, 305: 102 705

[14]

ZhouZX, QianCH, YuanWZ. Self-healing, Anti-freezing, Adhesive and Remoldable Hydrogel Sensor with Ion-liquid Metal Dual Conductivity for Biomimetic Skin[J]. Compos. Sci. Technol., 2021, 203: 108 608

[15]

ShinSH, LeeWJ, KimSM, et al.. Ion-conductive Self-healing Hydrogels based on an Interpenetrating Polymer Network for a Multimodal Sensor[J]. Chemical Engineering Journal, 2019, 371: 452-460

[16]

WuJ, SunYM, WuZX, et al.. Carbon Nanocoil-Based Fast-Response and Flexible Humidity Sensor for Multifunctional Applications[J]. ACS Appl. Mater. Interfaces, 2019, 11: 47 358

[17]

ZhouY, WanCG, YangYS, et al.. Highly Stretchable, Elastic, and Ionic Conductive Hydrogel for Artificial Soft Electronics[J]. Adv. Func. Mater., 2019, 29: 1 806 220

[18]

Ye YH, Zhang YF, Chen Y, et al. Cellulose Nanofibrils Enhanced, Strong, Stretchable, Freezing-Tolerant Ionic Conductive Organohy-drogel for Multi-Functional Sensors[J]. Adv. Funct. Mater., 2020: 2 003 430

[19]

ChenLG, ChangXH, WangH, et al.. Stretchable and Transparent Multimodal Electronic-skin Sensors in Detecting Strain, Temperature, and Humidity[J]. Nano Energy, 2022, 96: 107 077

[20]

HuRF, ZhaoJ, WangYH, et al.. A highly Stretchable, Self-healing, Recyclable and Interfacial Adhesion gel: Preparation, Characterization and Applications[J]. Chem. Eng. J., 2019, 360: 334

[21]

CashJJ, KuboTH, DobbinsDJ, et al.. Maximizing the Symbiosis of Static and Dynamic Bonds in Self-healing Boronic Ester Networks[J]. Polym. Chem., 2020, 11: 4 787

[22]

ChoSW, HwangSY, ParkJY, et al.. Recent progress in Self-healing Polymers and Hydrogels based on Reversible Dynamic B-O bonds: Boronic/Boronate Esters, Borax, and Benzoxaborole[J]. J. Mater. Chem. A, 2021, 9: 14630-14655

[23]

ZhangSW, HanDD, DingZX, et al.. Fabrication and Characterization of One Interpenetrating Network Hydrogel Based on Sodium Alginate and Polyvinyl Alcohol[J]. J. Wuhan Univ. Technol.-Mater. Sci. Ed., 2019, 34(3): 744-751

[24]

ZhangS, ZhangYH, LiB, et al.. One-Step Preparation of a Highly Stretchable, Conductive, and Transparent Poly(vinyl alcohol)-Phytic Acid Hydrogel for Casual Writing Circuits[J]. ACS Appl. Mater. Interfaces, 2019, 11: 32 441

[25]

YangZ, PangY, HanXL, et al.. Textile Strain Sensor with Negative Resistance Variation for Human Motion Detection[J]. ACS Nano, 2018, 12: 9134-9141

[26]

WeiHG, KongDS, LiT, et al.. Solution-Processable Conductive Composite Hydrogels with Multiple Synergetic Networks toward Wearable Pressure/Strain Sensors[J]. ACS Sens., 2021, 6: 2 938

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