Distribution of Na+ and Mechanical Properties of Hardened Body of Alkali-activated Cementitious Materials

Libo Bian , Zhi Tao , Xiufang Wang , Shaohui Wang , Kangjun Ye , Xingbo Hu

Journal of Wuhan University of Technology Materials Science Edition ›› 2023, Vol. 38 ›› Issue (4) : 849 -856.

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Journal of Wuhan University of Technology Materials Science Edition ›› 2023, Vol. 38 ›› Issue (4) : 849 -856. DOI: 10.1007/s11595-023-2768-3
Cementitious Materials

Distribution of Na+ and Mechanical Properties of Hardened Body of Alkali-activated Cementitious Materials

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Abstract

To explore the distribution of and the mechanical properties (compressive strength) of the hardened body of alkali slag-fly ash cementitious materials, this study was conducted by using the XRD, FT-IR, SEM/EDS, and other test methods in three conditions: airtight drying (AD), airtight immersion (AI), and airtight soaking (AS). The 1D distribution law of free of hardened body under standard curing conditions was explored. The experimental results show that under standard curing conditions, the 1D distribution of within 0 d-3 d shows a ∨-shaped distribution, within 3–7 d show a ∧-shaped distribution, and within 7–28 d tends to be balanced. The test results of leaching rate show that the free was the most stable under AD conditions and the hardened body bound the most by XRD, FTIR and SEM/EDS. And the compressive strength of the hardened body was the highest. The compressive strength of 28th reached 95.9 MPa. The definite distribution of provides an important reference for the strength development and durability evaluation of the hardened body of alkali-excited cementitious materials.

Keywords

alkali-activated cementitious materials / ion migration / leaching rate / curing condition / compressive strength

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Libo Bian, Zhi Tao, Xiufang Wang, Shaohui Wang, Kangjun Ye, Xingbo Hu. Distribution of Na+ and Mechanical Properties of Hardened Body of Alkali-activated Cementitious Materials. Journal of Wuhan University of Technology Materials Science Edition, 2023, 38(4): 849-856 DOI:10.1007/s11595-023-2768-3

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References

[1]

Lv W, Sun Z, Su Z. Study of Seawater Mixed One-part Alkali Activated GGBFS-fly Ash[J]. Cement and Concrete Composites, 2019, 106: 103 484.

[2]

Shi D, Zhang W, Ye J, et al. The Effect of Curing Conditions on the Properties, Reaction Products and Microstructure of Silica-calcium Slag-based Alkali-initiated Cementitious Materials[J]. Journal of The Chinese Ceramic Society, 2017, 45(08): 1 080-1 087.

[3]

Am A, Rs B, To C, et al. Fly Ash and Ground Granulated Blast Furnace Slag-based Alkali-activated Concrete: Mechanical, Transport and Microstructural Properties-Science Direct[J]. Construction and Building Materials, 2020, 257(10): 119548.1-119548.10.

[4]

Ye J, Zhang W. Research Progress of Nano-modified Alkali-initiated Gelling Materials[J]. Journal of The Chinese Ceramic Society, 2020, 48(08): 1 263-1 277.

[5]

Shi C. Strength, Pore Structure and Permeability of Alkali-activated Slag Mortars[J]. Cement & Concrete Research, 1996, 26(12): 1 789-1 799.

[6]

Zhu H. Preparation of Alkaline Slag-based Geopolymers and Research on High Temperature Performance[D], 2016 Guangxi: Guangxi University.

[7]

Palomo A, Macias A, Blanco MT, et al. Physical, Chemical and Mechanical Characterization of Geopolymers[C]. In: Proceeding of the 9th International Congress on the Chenistry of Cement, 1992: 505–511

[8]

Fu Y, Cai L, Wu Y. Freeze-thaw Cycle Test and Damage Mechanics Models of Alkali-activated Slag Concrete[J]. Construction & Building Materials, 2011, 25(7): 3 144-3 148.

[9]

Frantisek S, Lubomír K, Vít S, et al. Material and Structural Characterization of Alkali Activated Low-Calcium Brown Coal Fly Ash[J]. Journal of Hazardous Materials, 2009, 168(2–3): 711-720.

[10]

Zhang Z, Provwas JL, Ma X, et al. Efflorescence and Subflorescence Induced Microstructural and Mechanical Evolution in Fly Ash-based Geopolymers[J]. Cement and Concrete Composites, 2018, 92: 165-177.

[11]

Alzaza A, Mastali M, Kinnunen P, et al. Production of Lightweight Alkali Activated Mortars Using Mineral Wools[J]. Materials, 2019, 12(10): 1 695

[12]

Mastali M, Alzaza A, Shaad KM, et al. Using Carbonated BOF Slag Aggregates in Alkali-Activated Concretes[J]. Materials, 2019, 12(8): 1 288-1 291.

[13]

Nguyen QH, Lorente S, Duhart-Barone A, et al. Porous Arrangement and Transport Properties of Geopolymers[J]. Construction and Building Materials, 2018, 191(DEC.10): 853-865.

[14]

Kang SP, Kwon SJ. Effects of Red Mud and Alkali-activated Slag Cement on Efflorescence in Cement Mortar[J]. Construction and Building Materials, 2017, 133(FEB.15): 459-467.

[15]

Pratt PL, Wang SD, Pu XC, et al. Alkali-activated Slag Cement and Concrete: A Review of Properties and Problems[J]. Advances in Cement Research, 2015, 7(27): 93-102.

[16]

Li F. Research on Inhibitory Measures of Efflorescence in Geopolymer Materials[D], 2015 Jinan: University of Jinan.

[17]

Zhang Z, Provwas JL, Reid A, et al. Fly Ash-based Geopolymers: The Relationship between Composition, Pore Structure and Efflorescence[J]. Cement & Concrete Research, 2014, 64: 30-41.

[18]

Wang J, Zhou T, Xu D, et al. Effect of Nano-silica on the Efflorescence of Waste based Alkali-activated Inorganic Binder[J]. Construction & Building Materials, 2018, 167: 381-390.

[19]

Xiao X, Liu Y L, Dai JG, et al. Inhibiting Efflorescence Formation on Fly Ash-based Geopolymer via Silane Surface Modification[J]. Cement and Concrete Composites, 2018, 94: 43-52.

[20]

Chen Lijun, Wang Dejun, Kong Lingwei, et al. Research on R/Al Control Method of Alkali-activated Cementitious Materials[J]. Journal of Wuhan University of Technology, 35(05): 23–28

[21]

Rui D, Lijun C, Yinshan J. The Control Methods of R/Al of Alkali-activated Cementing Material-The Experimental Verification of R/Al Calculation Method of Alkali-activated Cementing Materials[J]. IPPTA: Quarterly Journal of Indian Pulp and Paper Technical Association, 2018, 30(8): 939-947.

[22]

Ding R, Chen L, Jiang Y. Application of R/Al Ratio in Preparation of Alkali Activated Cementitious Materials in Chemical Industry based on Industrial Waste Esidue Treatment[J]. Chemical Engineering Transactions, 2018, 71: 1 489-1 494.

[23]

Cui C, Peng H, Liu Y, et al. Influence of Slag Content and Activator Modulus on Room Temperature Solidification of Metakaolin Base Polymer[J]. Journal of Building Materials, 2017, 020(004): 535-542.

[24]

Ding R. Research on Alkali-activated Oil Shale Slag-slag Composite Cementitious Material and Its Quality Control Method[D], 2019 Jilin: Jilin University.

[25]

Hwang CL, Yehualaw MD, Vo DH, et al. Development of High-strength Alkali-activated Pastes Containing High Volumes of Waste Brick and Ceramic Powders[J]. Construction and Building Materials, 2019, 218(SEP.10): 519-529.

[26]

Chen W, Peng R, Straub C, et al. Promoting the Performance of One-part Alkali-activated Slag Using Fine Lead-zinc Mine Tailings[J]. Construction and Building Materials, 2020, 236: 117 745.

[27]

Huang G, Yang K, Sun Y, et al. Influence of NaOH Content on the Alkali Conversion Mechanism in MSWI Bottom Ash Alkali-activated Mortars[J]. Construction and Building Materials, 2020, 248: 118 582.

[28]

Tchakoute HK, Ruescher CH, Kong S, et al. Geopolymer Binders from Metakaolin Using Sodium Waterglass from Waste Glass and Rice Husk Ash as Alternative Activators: A Comparative Study[J]. Construction & Building Materials, 2016, 114(jul.1): 276-289.

[29]

Ismail I, Bernal SA, Provis JL, et al. Modification of Phase Evolution in Alkali-activated Blast Furnace Slag by the Incorporation of Fly Ash[J]. Cement and Concrete Composites, 2014, 45: 125-135.

[30]

A F-J, Palomo A, Criado M. Microstructure Development of Alkali-activated Fly Ash Cement: A Descriptive Model[J]. Cement & Concrete Research, 2005, 35(6): 1 204-1 209.

[31]

A A M, B R S, C T O, et al. Fly Ash and Ground Granulated Blast Furnace Slag-based Alkali-activated Concrete: Mechanical, Transport and Microstructural Properties-ScienceDirect[J]. Construction and Building Materials, 257

[32]

Sun K, Peng X, Wang S, et al. Effect of Nano-SiO2 on the Efflorescence of an Alkali-activated Metakaolin Mortar[J]. Construction and Building Materials, 2020, 253: 118 952.

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