Luminescent BODIPY-based Porous Organic Polymer for CO₂ Adsorption

Abstract

Luminescent porous materials have shown various applications such as electronic devices, gas adsorption, energy materials and photocatalysis. Consequently, we designed and prepared a new type borondipyrromethene (BODIPY) based porous organic polymer (POP) by using Sonogashira coupling reaction. This POP-1 exhibits high thermal stability with moderate surface area. In addition, POP-1 is highly emissive in a solid state. Due to enrichment of different kinds of heteroatoms in the skeleton of the porous polymer, POP-1 selectively captures carbon dioxide (CO₂) with relative high adsorption selectivity of CO₂/N₂.

Keywords

porous organic polymer / luminescent / boron-dipyrromethene(BODIPY) / CO₂ adsorption / selectively capture

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