Preparation and Properties of Aqueous SCNTs Dispersion based on A UV-curable Polymeric Dispersant

Abstract

A novel photosensitive copolymer P(SS-co-AA-g-GMA) (PSAG) was synthesized and utilized to noncovalently functionalize pristine single-walled carbon nanotubes (SCNTs). PSAG was highly effective for the solubilization of SCNTs in water and validated by UV-vis absorption spectra experiments, resulting in homogeneous and stable PSAG-SCNT aqueous dispersion. The microstructure of SCNTs was observed through Raman spectroscopy and transmission electron microscopy. In addition, compared with the two common polymeric dispersants of Triton X-100 and PSS, PSAG demonstrated more effective performances for dispersing SCNTs under identical conditions. Furthermore, the photosensitive PSAG-SCNTs can be crosslinked after UV irradiation, leading to significant improvement in the water resistance of SCNT films. UV-cured films can be transferred to plastic wrap to form a flexible film with high electrical conductivity.

Keywords

single-walled carbon nanotubes (SCNTs) / polymeric dispersant / UV-curable / conductive / water resistance

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