Dissolution kinetics of copper from multi-metal copper alloy roasted in oxygen

Wei-hong Lu , Zhou-lan Yin , Zhi-ying Ding , Yang Liu

Journal of Central South University ›› 2017, Vol. 24 ›› Issue (2) : 335 -340.

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Journal of Central South University ›› 2017, Vol. 24 ›› Issue (2) : 335 -340. DOI: 10.1007/s11771-017-3435-7
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Dissolution kinetics of copper from multi-metal copper alloy roasted in oxygen

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Abstract

A kinetic study on the sulfuric acid leaching of multi-metal oxide, which is the product of multi-metal copper alloy with iron trioxide roasted in oxygen, was carried out. The effects of leaching time, stirring speed, sulfuric acid concentration, reaction temperature, and particle size of the multi-metal oxide on the kinetics and mechanism of copper extraction were studied. It was found that the reaction kinetic model about the copper extraction from multi-metal oxide follows the mixed kinetic shrinking core mode: 1/3ln(1–X)+(1–X)–1/3–1=680.5C(H2SO4)0.4297dP–0.75115exp(–Ea/RT)t.

Keywords

leaching kinetic / multi-metal copper alloy / roasting

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Wei-hong Lu, Zhou-lan Yin, Zhi-ying Ding, Yang Liu. Dissolution kinetics of copper from multi-metal copper alloy roasted in oxygen. Journal of Central South University, 2017, 24(2): 335-340 DOI:10.1007/s11771-017-3435-7

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References

[1]

ThompsonW T, BaleC W, PeltonA DFacility for theanalysis of chemical thermodynamics (FACTSage) [EB/OL], 2012

[2]

Chaidez FelixA, Romero SerranoA, HernandezramirezaA, Perez LabeaM, Almaguer GuzmanI, Benavides PerezR, Flores FavelaM. Effect of copper, sulfur, arsenic and antimony on silver distribution in phases of lead blast furnace [J]. Transactions of Nonferrous Metals Society of China, 2014, 24: 1202-1209

[3]

QuS-l, DongZ-q, ChenTao. Study on gold collection in matte with oxygen enriched bottom blowing smelting process [J]. Nonferrous Metals (Extractive Metallurgy), 2013, 6: 40-42

[4]

LiuL, YanH-j, ZhouJ-m, GaoQ, ZhangZ-y, LiuF-k, CuiZ-xiang. Mechanism of copper smelting process by oxygen bottom blowing and microanalysis of smelting products [J]. The Chinese Journal of Nonferrous Metals, 2012, 22(7): 2116-2124

[5]

ZhangL, LinG-m, BinW-d, LiY-x, LiX-bin. Research on oxygen side blow reduction furnace and high lead slag liquid reduction process [C]//. The 2nd Bath Smelting Technology and Equipment Symposium, 2011Xi’anChina Nonferrous Metal Society Heavy Metal Metallurgy Academy Committee275-280

[6]

Perez LabraM, Romero SerranoA, HernandezRAMIREZA, Almaguer GuzmanI, BenavidesPERRZR. Distribution of lead and silver under lead blast furnace conditions [J]. Revista de Metalurgia de Madrid, 2012, 48(3): 213-222

[7]

JinB-j, YangX-w, ShenQ-feng. Pressure oxidative leaching of lead-containing copper matte [J]. Hydrometallurgy, 2009, 96: 57-61

[8]

JinB-j, YangX-w, ShenQ-feng. Kinetics of copper dissolution during pressure oxidative leaching of lead-containing copper matte [J]. Hydrometallurgy, 2009, 99: 119-123

[9]

RaghavanR, MohananP K. Hydrometallurgical treatment of copper matte generated at a lead smelter for simultaneous recovery of copper, lead and silver [J]. Bull Electrochem, 2000, 16(1): 44-48

[10]

BurzynskaL, GumowskaW, RudnikE. Influence of the composition of Cu–Co–Fe alloys on their dissolution in ammoniacal solutions [J]. Hydrometallurgy, 2004, 71: 447-455

[11]

ParkK H, MohapatraD, ReddyR. A study on the acidified ferric chloride leaching of a complex (Cu–Ni–Co–Fe) matte [J]. Separation and Purification Technology, 2006, 51: 332-337

[12]

ParkK H, MohapatraD, KimI H, GuoX Y. Dissolution behaviour of a complex Cu–Ni–Co–Fe matte in CuCl2–NaCl–HCl leaching medium [J]. Separation and Purification Technology, 2007, 56: 303-310

[13]

RademanJ A M, LorenzenL, van DeventerJ S J. The leaching characteristics of Ni–Cu matte in the acid–oxygen pressure leach process at Impala Platinum [J]. Hydrometallurgy, 1999, 52: 231-252

[14]

AltundoganH S, TümenF. Metal recovery from copper converter slag byroasting with ferric sulphate [J]. Hydrometallurgy, 1997, 44: 261-267

[15]

ArslanC, ArslanF. Recovery of copper, cobalt and zinc from copper smelter and converter slags [J]. Hydrometallurgy, 2002, 67: 1-7

[16]

DickinsonC F, HealG R. Solid-liquid diffusion controlled rate equations [J]. Thermochimica Acta, 1999, 340(99): 89-103

[17]

LiuZ-x, YinZ-l, HuH-p, ChenQ-y. Leaching kinetics of low-grade copper ore with high-alkality gangues in ammonia-ammonium sulphate solution [J]. Journal of Central South University, 2012, 19(1): 79-84

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