Acid-etching induced metal cation competitive lattice occupancy of perovskite quantum dots for efficient pure-blue QLEDs

Abstract

Low efficiency and spectral instability caused by the surface defects have been considerable issues for the mixed-halogen blue emitting perovskite quantum dots light-emitting diodes (PeQLEDs). Here, an in situ surface passivation to perovskite quantum dots (PeQDs) is realized by introducing the metal cations competitive lattice occupancy assisted with acid-etching, in which the longchain, insulating and weakly bond surface ligands are removed by addition of octanoic acid (OTAC). Meanwhile, the dissolved A-site cations (Na⁺) compete with the protonated oleyl amine and are subsequently anchored to the surface vacancies. The preadded lead bromide, acting as inorganic ligands, demonstrates strong bonding to the uncoordinated surface ions. The as-synthesized PeQDs show the boosted photoluminescence quantum yield (PLQY) and superior stability with longer lifetime. As a result, the PeQLEDs (470 nm) based on the OTAC-Na PeQDs exhibit an external quantum efficiency of 8.42% in the mixed halogen PeQDs (CsPb(Br_xCl_1–x)₃). Moreover, the device exhibits superior spectra stability with negligible shift. Our competition mechanism in combination with in situ passivation strategy paves a new way for improving the performance of blue PeQLEDs.

Keywords

acid etching / blue PeQLEDs / high-efficiency / in situ passivation / spectral stability

RIGHTS & PERMISSIONS

2024 The Authors. Interdisciplinary Materials published by Wuhan University of Technology and John Wiley & Sons Australia, Ltd.