Studies of high-efficient and low-cost dye-sensitized solar cells
Qingqing MIAO, Mingxing WU, Wei GUO, Tingli MA
Studies of high-efficient and low-cost dye-sensitized solar cells
Dye-sensitized solar cell (DSSC) is a new type of photoelectric device. To commercialize DSSC successfully, it is necessary to further improve the efficiency of energy conversion and reduce its cost. Nitrogen-doped (N-doped) TiO2 photoanode, the carbon counter electrode (CE), and a new type of hybrid photoanode were investigated in this study. The conversion efficiency of the DSSC reached by 10.10% as the DSSC was fabricated with the N-doped photoanode, and this efficiency is much higher than that of the undoped-DSSC with 8.90%; as the low-cost carbon was used as CE, the efficiency of the DSSC was 7.50%, it was as samilar as that of Pt CE (7.47%); the hybrid DSSC with multilayer photoanode by the film-transfer technique achieved a panchromatic response and a superposed short circuit current density (JSC) by using two complementary dyes.
high-efficiency / dye-sensitized solar cell (DSSC) / hybrid / nitrogen-doped (N-doped) TiO2 / carbon counter electrode (CE)
[1] |
O’Regan B, Grätzel M. A low-cost, high-efficiency solar cell based on dye-sensitized TiO2 colloidal films. Nature, 1991, 353(6346): 737–740
CrossRef
Google scholar
|
[2] |
Yamaguchi T, Uchida Y, Agatsuma S, Arakawa H. Series-connected tandem dye-sensitized solar cell for improving efficiency to more than 10%. Solar Energy Materials and Solar Cells, 2009, 93(6-7): 733–736
CrossRef
Google scholar
|
[3] |
Inakazu F, Noma Y, Ogomi Y, Hayase S. Dye-sensitized solar cells consisting of dye-bilayer structure stained with two dyes for harvesting light of wide range of wavelength. Applied Physics Letters, 2008, 93(9): 093304
CrossRef
Google scholar
|
[4] |
Yanagida M, Komatsuzaki N O, Kurashigea M, Sayamaa K, Sugihara H. Optimization of tandem-structured dye-sensitized solar cell. Applied Physics Letters, 2010, 94(2): 297–302
|
[5] |
Kuang D B, Walter P, Nüesch F, Kim S, Ko J J, Comte P, Zakeeruddin S M, Nazeeruddin M K, Grätzel M. Co-sensitization of organic dyes for efficient ionic liquid electrolyte-based dye-sensitized solar cells. Langmuir, 2007, 23(22): 10906–10909
CrossRef
Pubmed
Google scholar
|
[6] |
Ehret A, Stuhl L, Spitler M T. Spectral sensitization of TiO2 nanocrystalline electrodes with aggregated cyanine dyes. Journal of Physical Chemistry B, 2001, 105(41): 9960–9965
CrossRef
Google scholar
|
[7] |
Yum J H, Jang S R, Walter P, Geiger T, Nüesch F, Kim S, Ko J, Grätzel M, Nazeeruddin M K. Efficient co-sensitization of nanocrystalline TiO2 films by organic sensitizers. Chemical Communications, 2007, (44): 4680–4682
CrossRef
Pubmed
Google scholar
|
[8] |
Clifford J N, Palomares E, Nazeeruddin M K, Thampi R, Grätzel M, Durrant J R. Multistep electron transfer processes on dye co-sensitized nanocrystalline TiO2 films. Journal of the American Chemical Society, 2004, 126(18): 5670–5671
CrossRef
Pubmed
Google scholar
|
[9] |
Choi H, Kim S, Kang S O, Ko J J, Kang M S, Clifford J, Forneli A, Palomares E, Nazeeruddin M K, Grätzel M. Stepwise co-sensitization of nanocrystalline TiO2 films utilizing Al2O3 layers in dye-sensitized solar cells. Angewandte Chemie International Edition, 2008, 47(43): 8259–8263
CrossRef
Google scholar
|
[10] |
Lee K, Park S W, Ko M J, Kim K, Park N G. Selective positioning of organic dyes in a mesoporous inorganic oxide film. Nature Materials, 2009, 8(8): 665–671
CrossRef
Pubmed
Google scholar
|
[11] |
Dürr M, Bamedi A, Yasuda A, Nelles G. Tandem dye-sensitized solar cell for improved power conversion Efficiencies. Applied Physics Letters, 2004, 84(17): 3397–3399
CrossRef
Google scholar
|
[12] |
Murayama M, Mori T. Novel tandem cell structure of dye-sensitized solar cell for improvement in photocurrent. Thin Solid Films, 2008, 516(9): 2716–2722
CrossRef
Google scholar
|
[13] |
Usagawa J, Pandey S S, Hayase S, Mitsuru K, Yoshihiro Y. Tandem dye-sensitized solar cells fabricated on glass rod without transparent conductive layers. Applied Physics Express, 2009, 2(6): 062203
CrossRef
Google scholar
|
[14] |
Noma Y, Lizuka K, Ogomi Y, Pandey S S, Hayase S. Preparation of double dye-layer structure of dye-sensitized solar cells from cocktail solutions for harvesting light in wide range of wavelengths. Japanese Journal of Applied Physics, 2009, 48(2): 020213
CrossRef
Google scholar
|
[15] |
Nakamura I, Negishi N, Kutsuna S, Iharab T, Sugiharac S, Takeuchi K. Role of oxygen vacancy in the plasma-treated TiO2 photocatalyst with visible light activity for NO removal. Journal of Molecular Catalysis A: Chemical, 2000, 161(1-2): 205–212
CrossRef
Google scholar
|
[16] |
Ihara T, Miyoshi M, Iriyama Y, Matsumotoc O, Sugihara S. Visible-light-active titanium oxide photocatalyst realized by an oxygen-deficient structure and by nitrogen doping. Applied Catalysis B: Environmental, 2003, 42(4): 403–409
CrossRef
Google scholar
|
[17] |
Irie H, Watanabe Y, Hashimoto K. Nitrogen-concentraion dependence on photocatalytic activity of TiO2-xNx powders. Journal of Physical Chemistry B, 2003, 107(23): 5483–5486
CrossRef
Google scholar
|
[18] |
Mrowetz M, Balcerski W, Colussi A J, Hoffmann M R. Oxidative power of nitrogen-doped TiO2 photocatalysts under visible illumination. Journal of Physical Chemistry B, 2004, 108(45): 17269–17273
CrossRef
Google scholar
|
[19] |
Ma T, Akiyama M, Abe E, Imai I. High-efficiency dye-sensitized solar cell based on a nitrogen-doped nanostructured titania electrode. Nano Letters, 2005, 5(12): 2543–2547
CrossRef
Pubmed
Google scholar
|
[20] |
Kong Z X, Zhou H Z, Cui J N, Ma T L, Yang X C, Sun L C. A new class of organic dyes based on acenaphthopyrazine for dye-sensitized solar cells. Journal of Photochemistry and Photobiology A Chemistry, 2010, 213(2-3): 152–157
CrossRef
Google scholar
|
[21] |
Ma T, Kida T, Akiyama M, Inoue K, Tsunematsu S, Yao K, Noma H, Abe E. Preparation and properties of nanostructured TiO2 electrode by a polymer organic-medium screen-printing technique. Electrochemistry Communications, 2003, 5(4): 369–372
CrossRef
Google scholar
|
[22] |
Yang L, Wu L Q, Wu M X, Xin G, Lin H, Ma T. High-efficiency flexible dye-sensitized solar cells fabricated by a novel friction-transfer technique. Electrochemistry Communications, 2010, 12(7): 1000–1003
CrossRef
Google scholar
|
[23] |
Ma T, Kida T, Akiyama M, Inoue K, Tsunematsu S, Yao K, Noma H, Abe E. Preparation and properties of nanostructured TiO2 electrode by a polymer organic-medium screen-printing technique. Electrochemistry Communications, 2003, 5(4): 369–372
CrossRef
Google scholar
|
[24] |
Wang H, Wang A Q, Wang X D, Zhang T. One-pot synthesized MoC imbedded in ordered mesoporous carbon as a catalyst for N2H4 decomposition. Chemical Communications, 2008, (22): 2565–2567
CrossRef
Pubmed
Google scholar
|
[25] |
Liang C D, Dai S. Synthesis of mesoporous carbon materials via enhanced hydrogen-bonding interaction. Journal of the American Chemical Society, 2006, 128(16): 5316–5317
CrossRef
Pubmed
Google scholar
|
/
〈 | 〉 |