Oxidation performance of graphite material in reactors

LUO Xiaowei, YU Xinli, YU Suyuan

PDF(69 KB)
PDF(69 KB)
Front. Energy ›› 2008, Vol. 2 ›› Issue (4) : 471-474. DOI: 10.1007/s11708-008-0074-6

Oxidation performance of graphite material in reactors

  • LUO Xiaowei, YU Xinli, YU Suyuan
Author information +
History +

Abstract

Graphite is used as a structural material and moderator for high temperature gas-cooled reactors (HTGR). When a reactor is in operation, graphite oxidation influences the safety and operation of the reactor because of the impurities in the coolant and/or the accident conditions, such as water ingress and air ingress. In this paper, the graphite oxidation process is introduced, factors influencing graphite oxidation are analyzed and discussed, and some new directions for further study are pointed out.

Cite this article

Download citation ▾
LUO Xiaowei, YU Xinli, YU Suyuan. Oxidation performance of graphite material in reactors. Front. Energy, 2008, 2(4): 471‒474 https://doi.org/10.1007/s11708-008-0074-6

References

1. Blanchard A . Appendix2: The Thermal Oxidation of Graphite, Irradiation Damage in GraphiteDue to Fast Neutrons in Fission and Fusion Systems. IAEA Report, IAEA-TECDOC-1154, Vienna. 2000
2. Velasquez C, Hightower G, Burnette R . The Oxidation of H-451 Graphite by Steam, Part 1: ReactionKinetics. General Atmotics Report GA-A14951. 1978
3. Katscher W, Moorman R . Graphite Corrosion underSevere HTR Accident Condition. IAEA Specialists' Meeting on GraphiteComponent Structural Design.JAERI Tokai, Japan, 1986, 182–188
4. Hinssen H K, Katcher W, Moorman R . Kinetics der Graphite/Sauerstoff in Porendiffusionsbereich. Jül Report Jül–1875. 1983
5. O'Brien M H, Merrill B J, Ygaki S N . Combustion Testing and Thermal Modeling of Proposed CITGraphite Tile Materials. Report EGG-FSP-8255. 1988
6. Robin J C . Graphite Oxidation in High Temperature Reactors―ExperimentalProgram. Report CEA/DER/STR/LECP. 2002
7. Nonal J P . Graphite in High Temperature Reactors. Report CEA/DMN/SEMI/LM2E. 2001
8. Schneider P . Muticomponentisothermal diffusion and forced flow of gases in capillaries. Chemical Engineering Science, 1978, 33(10): 1311–1319. doi:10.1016/0009-2509(78)85112-4
9. Mason E A, Malinauskas A P . Gas Transport in Porous Media:the Dusty-Gas Model. Amsterdam: Elsevier, 1983
10. Mays T J, Mcenaney B, Kelly B T . Gaseous diffusion and pore structure in nuclear graphite. Specialists Meeting on Graphite Moderator LifecycleBehaviour, Bath, 1995, 329–335
11. Hashitani H, Yoshida H, Adach T . Spectrophotometric determination of ammonium nitrogenby using thymol. Bunseki Kagaku, 1968, 17: 1136–1139
12. Thrower P A, Mathew G K, McGinnis N J . Influence of oxidation on the structure and strengthof graphite-2 materials of different impurity content. Carbon, 1982, 20(6): 465–471. doi:10.1016/0008-6223(82)90082-3
13. Nomura S, Imai H, Fuji K, et al.. Relation between gasification rates and gasdesorption behavior with metallic impurities of carbon and grapohitematerials for the HTTR. Specialists' Meetingon the Status of Graphite Development for Gas Cooled Reactors, Tokai,Ibaraki (Japan), 1991, 159–168
14. Qiu Xueliang, Zhang Shichao, He Jun, et al.. Oxidation behaviour of the matrix materials. Specialists Meeting on Graphite Moderator LifecycleBehaviour, Bath (United Kingdom), 1995, 351–362
15. Chang H W, Rhee S K . Oxidation of carbon derivedfrom phenolic resin. Carbon, 1978, 16(1): 17–20. doi:10.1016/0008-6223(78)90109-4
16. Virgiliev Y U S, Cherednik F M, Ostrovsky V S . Chemistry of Solid Fuel. New York: Allerton Press, 1974
17. Vavilin A I, Kulikov E T, Mozzherin S I, et al.. Corrosion test of matrix graphites. Specialists' Meeting on the Status of GraphiteDevelopment for Gas Cooled Reactors, Tokai, Ibaraki (Japan), 1991, 183–192
18. Luo Xiaowei, Robin J-C, Yu Suyuan . Theoretical analysis of mass transfer and reaction ina porous medium applied to the gasification of graphite by water vapor. Nuclear Engineering and Design, 2006, 236(9): 938–947. doi:10.1016/j.nucengdes.2005.09.011
19. Richards M B, Gillespie A G, Hanson D L . In-pile corrosion of grade h-451 graphite by stream,behaviour of gas cooled reactor fuel under accident conditions. Proceedings of a Specialists Meeting Held in OakRidge, 1990, 157–162
20. Su J L, Perlmutter D D . Effect of pore structureon the particle ignition during exothermic gasification reactions. AIChE J, 1985, 31(2): 157–160. doi:10.1002/aic.690310121
AI Summary AI Mindmap
PDF(69 KB)

Accesses

Citations

Detail

Sections
Recommended

/