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Abstract
Hydrogen is a clean energy carrier. Converting abundant coal sources and green biomass energy into hydrogen effectively and without any pollution promotes environmental protection. The co-gasification performance of coal and a model compound of biomass, carboxymethylcellulose (CMC) in supercritical water (SCW), were investigated experimentally. The influences of temperature, pressure and concentration on hydrogen production from co-gasification of coal and CMC in SCW under the given conditions (20–25 MPa, 650vH, 15–30 s) are discussed in detail. The experimental results show that H2, CO2 and CH4 are the main gas products, and the molar fraction of hydrogen reaches in excess of 60%. The higher pressure and higher CMC content facilitate hydrogen production; production is decreased remarkably given a longer residence time.
Keywords
hydrogen production, coal, CMC, supercritical water, co-gasification
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YAN Qiuhui, GUO Liejin, LIANG Xing, ZHANG Ximin.
Hydrogen production from co-gasification of coal and biomass in supercritical water by continuous flow thermal-catalytic reaction system.
Front. Energy, 2007, 1 (3) : 327-330 DOI:10.1007/s11708-007-0048-0
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