Low-field NMR application in the characterization of CO₂ geological storage and utilization related to shale gas reservoirs: a brief review

Abstract

CO₂ geological storage and utilization (CGSU) is considered a far-reaching technique to meet the demand of increasing energy supply and decreasing CO₂ emissions. For CGSUs related to shale gas reservoirs, experimental investigations have attracted variable methodologies, among which low-field NMR (LF-NMR) is a promising method and is playing an increasingly key role in reservoir characterization. Herein, the application of this nondestructive, sensitive, and quick LF-NMR technique in characterizing CGSU behavior in shale gas reservoirs is reviewed. First, the basic principle of LF-NMR for ¹H-fluid detection is introduced, which is the theoretical foundation of the reviewed achievements in this paper. Then, the reviewed works are related to the LF-NMR-based measurements of CH₄ adsorption capacity and the CO₂-CH₄ interaction in shale, as well as the performance on CO₂ sequestration and simultaneous enhanced gas recovery from shale. Basically, the reviewed achievements have exhibited a large potential for LF-NMR application in CGSUs related to shale gas reservoirs, although some limitations and deficiencies still need to be improved. Accordingly, some suggestions are proposed for a more responsible development of the LF-NMR technique. Hopefully, this review is helpful in promoting the expanding application of the LF-NMR technique in CGSU implementation in shale gas reservoirs.

Graphical abstract

Keywords

CO₂/CH₄ competitive adsorption / shale gas reservoir / CO₂ geological storage / gas recovery enhancement / low-field NMR

References

[1] Abdussalam O, Trochu J, Fello N, Chaabane A (2021). Recent advances and opportunities in planning green petroleum supply chains: a model-oriented review.Int J Sustain Dev World Ecol, 28(6): 524–539

[2] Adeyilola A, Nordeng S, Onwumelu C, Nwachukwu F, Gentzis T (2020). Geochemical, petrographic and petrophysical characterization of the Lower Bakken Shale, Divide County, North Dakota.Int J Coal Geol, 224: 103477

[3] Borgia G C, Brown R J S, Fantazzini P (1998). Uniform-penalty inversion of multiexponential decay data.J Magn Reson, 132(1): 65–77

[4] Brown R J S, Chandler R, Jackson J A, Kleinberg R L, Miller M N, Paltiel Z, Prammer M G (2001). History of NMR well logging.Concepts Magn Reson, 13(6): 335–413

[5] Brown R J S, Fatt I (1956). Measurements of Fractional Wettability of Oil Fields’ Rocks by the Nuclear Magnetic Relaxation Method. Fall Meeting of the Petroleum Branch of AIME, October 14, Los Angeles, California

[6] Butler J P, Reeds J A, Dawson S V (1981). Estimating solutions of first kind integral equations with nonnegative constraints and optimal smoothing.SIAM J Numer Anal, 18(3): 381–397

[7] Carr H Y, Purcell E M (1954). Effects of diffusion on free precession in nuclear magnetic resonance experiments.Phys Rev, 94(3): 630–638

[8] Cheng H L M, Stikov N, Ghugre N R, Wright G A (2012). Practical medical applications of quantitative MR relaxometry.J Magn Reson Imaging, 36(4): 805–824

[9] Cheng L, Li D, Wang W, Liu J (2021). Heterogeneous transport of free CH₄ and free CO₂ in dual-porosity media controlled by anisotropic in situ stress during shale gas production by CO₂ flooding: implications for CO₂ geological storage and utilization.ACS Omega, 6(40): 26756–26765

[10] Coates G R, Xiao L, Prammer M G (1999). NMR Logging Principles and Applications. Houston (Texas): Gulf Publishing Company

[11] Cornillon P, Salim L C (2000). Characterization of water mobility and distribution in low- and intermediate-moisture food systems.Magn Reson Imaging, 18(3): 335–341

[12] Duguid A, Glier J, Heinrichs M, Hawkins J, Peterson R, Mishra S (2021). Practical leakage risk assessment for CO₂ assisted enhanced oil recovery and geologic storage in Ohio’s depleted oil fields.Int J Greenh Gas Control, 109: 103338

[13] Dunn K J, Bergman J D, Latorraca A G (2002). Nuclear Magnetic Resonance: Petrophysical and Logging Applications. In: Handbook of Geophysical Exploration. New York: Pergamon.

[14] Fan C J, Yang L, Wang G, Huang Q M, Fu X, Wen H O (2021). Investigation on coal skeleton deformation in CO₂ injection enhanced CH₄ drainage from underground coal seam.Front Earth Sci (Lausanne), 9: 766011

[15] Fatah A, Bennour Z, Ben Mahmud H, Gholami R, Hossain M M (2020). A review on the influence of CO₂/shale interaction on shale properties: implications of CCS in shales.Energies, 13(12): 3200

[16] Fathi E, Akkutlu I Y (2014). Multi-component gas transport and adsorption effects during CO₂ injection and enhanced shale gas recovery.Int J Coal Geol, 123: 52–61

[17] Gensterblum Y, Busch A, Krooss B M (2014). Molecular concept and experimental evidence of competitive adsorption of H₂O, CO₂ and CH₄ on organic material.Fuel, 115: 581–588

[18] Godec M, Koperna G, Petrusak R, Oudinot A (2013). Potential for enhanced gas recovery and CO₂ storage in the Marcellus Shale in the Eastern United States.Int J Coal Geol, 118: 95–104

[19] Godec M, Koperna G, Petrusak R, Oudinot A (2014). Enhanced gas recovery and CO₂ storage in gas shales: a summary review of its status and potential.Energy Procedia, 63: 5849–5857

[20] Golub G H, Heath M, Wahba G (1979). Generalized cross-validation as a method for choosing a good ridge parameter.Technometrics, 21(2): 215–223

[21] Guo J C, Zhou H Y, Zeng J, Wang K J, Lai J, Liu Y X (2020). Advances in low-feld nuclear magnetic resonance (NMR) technologies applied for characterization of pore space inside rocks: a critical review.Petrol Sci, 17(5): 1281–1297

[22] Hatzakis E (2019). Nuclear magnetic resonance (NMR) spectroscopy in food science: a comprehensive review.Compr Rev Food Sci Food Saf, 18(1): 189–220

[23] Hirasaki G J, Lo S W, Zhang Y (2003). NMR properties of petroleum reservoir fluids.Magn Reson Imaging, 21(3–4): 269–277

[24] Hu T, Xu T F, Tian H L, Zhou B, Yang Y Z (2021). A study of CO₂ injection well selection in the naturally fractured undulating formation in the Jurong Oilfield, China.Int J Greenh Gas Control, 109: 103377

[25] Huang L, Ning Z F, Wang Q, Ye H T, Chen Z L, Sun Z, Sun F R, Qin H B (2018). Enhanced gas recovery by CO₂ sequestration in marine shale: a molecular view based on realistic kerogen model.Arab J Geosci, 11(15): 404

[26] Huang X, Li T T, Gao H, Zhao J S, Wang C (2019). Comparison of SO₂ with CO₂ for recovering shale resources using low-field nuclear magnetic resonance.Fuel, 245: 563–569

[27] Huang X, Xue J J, Li X (2020). Adsorption behavior of CH₄ and C₂H₆ on shale under the influence of CO₂ and flue gas.Energy Fuels, 34(5): 5689–5695

[28] Iddphonce R, Wang J J, Zhao L (2020). Review of CO₂ injection techniques for enhanced shale gas recovery: prospect and challenges.J Nat Gas Sci Eng, 77: 103240

[29] Keles C, Tang X, Schlosser C, Louk A K, Ripepi N S (2020). Sensitivity and history match analysis of a carbon dioxide “huff-and-puff” injection test in a horizontal shale gas well in Tennessee.J Nat Gas Sci Eng, 77: 103226

[30] Kirli M S, Fahrioglu M (2019). Sustainable development of Turkey: deployment of geothermal resources for carbon capture, utilization, and storage.Energy Sources Part A-Recovery Utilization Environmental Effects, 41(14): 1739–1751

[31] Lawson C L, Hanson R J (1974). Solving Least Squares Problems. Prentice-Hall

[32] Li J, Wu Q Z, Lu J, Jin W J (2018). To quantitatively determine the adsorption and free methane volume content in shale gas core based on NMR technique. Well Logging Techn, 42(3): 315–320 (in Chinese)

[33] Li L G, Li C, Kang T H (2019). Adsorption/desorption behavior of CH₄ on shale during the CO₂ Huff-and-Puff process.Energy Fuels, 33(6): 5147–5152

[34] Lin T, Liu X, Zhang J, Bai Y, Liu J, Zhang Y, Zhao Y, Cheng X, Lv J, Yang H (2021). Characterization of multi-component and multi-phase fluids in the Upper Cretaceous oil shale from the Songliao Basin (NE China) using T₁–T₂ NMR correlation maps. Petrol Sci Technol, 39 (23–24): 1060–1070

[35] Liu D Q, Li Y L, Agarwal R K (2016). Numerical simulation of long-term storage of CO₂ in Yanchang shale reservoir of the Ordos Basin in China.Chem Geol, 440: 288–305

[36] Liu D Q, Li Y L, Yang S, Agarwal R K (2021a). CO₂ sequestration with enhanced shale gas recovery.Energy Sources Part A-Recovery Utilization and Environmental Effects, 43(24): 3227–3237

[37] Liu F Y, Ellett K, Xiao Y T, Rupp J A (2013). Assessing the feasibility of CO₂ storage in the New Albany Shale (Devonian-Mississippian) with potential enhanced gas recovery using reservoir simulation.Int J Greenh Gas Control, 17: 111–126

[38] Liu J, Xie L, Elsworth D, Gan Q (2019a). CO₂/CH₄ competitive adsorption in shale: implications for enhancement in gas production and reduction in carbon emissions.Environ Sci Technol, 53(15): 9328–9336

[39] Liu J, Xie L, Yao Y, Gan Q, Zhao P, Du L (2019b). Preliminary study of influence factors and estimation model of the enhanced gas recovery stimulated by carbon dioxide utilization in shale.ACS Sustain Chem & Eng, 7(24): 20114–20125

[40] Liu J, Xie L Z, He B, Gan Q, Zhao P (2021b). Influence of anisotropic and heterogeneous permeability coupled with in-situ stress on CO₂ sequestration with simultaneous enhanced gas recovery in shale: quantitative modeling and case study.Int J Greenh Gas Control, 104: 103208

[41] Liu J, Yao Y, Liu D, Elsworth D (2017). Experimental evaluation of CO₂ enhanced recovery of adsorbed-gas from shale.Int J Coal Geol, 179: 211–218

[42] Liu X, Zhang J, Bai Y, Zhang Y, Zhao Y, Cheng X, Lv J, Yang H, Liu J (2020a). Pore structure petrophysical characterization of the Upper Cretaceous oil shale from the Songliao Basin (NE China) using low-field NMR.J Spectrosc, 2020: 1–11

[43] Liu Y L, Wang C (2018). Determination of the absolute adsorption isotherms of CH₄ on shale with low-field nuclear magnetic resonance.Energy Fuels, 32(2): 1406–1415

[44] Liu Z S, Liu D M, Cai Y D, Yao Y B, Pan Z J, Zhou Y F (2020b). Application of nuclear magnetic resonance (NMR) in coalbed methane and shale reservoirs: a review.Int J Coal Geol, 218: 103261

[45] Luo X R, Ren X J, Wang S Z (2019). Supercritical CO₂-water-shale interactions and their effects on element mobilization and shale pore structure during stimulation.Int J Coal Geol, 202: 109–127

[46] Levitt M H (2015). Nuclear spin relaxation.Resonance, 20(11): 986–994

[47] Martin A (1995). Nuclear-magnetic-resonance imaging — technology for the 21st-century.Oilfield Rev, 7(3): 19–33

[48] McPhee C, Reed J, Zubizarreta I (2015). Nuclear Magnetic Resonance (NMR).Develop Petroleum Sci, 64: 655–669

[49] Meiboom S, Gill D (1958). Modified spin-echo method for measuring nuclear relaxation times.Rev Sci Instrum, 29(8): 688–691

[50] Middleton R S, Carey J W, Currier R P, Hyman J D, Kang Q J, Karra S, Jimenez-Martinez J, Porter M L, Viswanathan H S (2015). Shale gas and non-aqueous fracturing fluids: opportunities and challenges for supercritical CO₂.Appl Energy, 147: 500–509

[51] Pereira P, Ribeiro C, Carneiro J (2021). Identification and characterization of geological formations with CO₂ storage potential in Portugal.Petrol Geosci, 27(3): petgeo2020–123

[52] Qiu S, Lei T, Wu J T, Bi S S (2021). Energy demand and supply planning of China through 2060.Energy, 234: 121193

[53] Rani S, Prusty B K, Pal S K (2020). Characterization of shales from Damodar valley coalfields for CH₄ recovery and CO₂ sequestration.Environ Techn & Innov, 18: 100739

[54] Seevers D O (1966). A Nuclear Magnetic Method for Determining The Permeability Of Sandstones. SPWLA 7th Annual Logging Symposium. Society of Professional Well Log Analysts Transactions, Tulsa, Oklahoma, 1–14

[55] Shi J L, Shen G F, Zhao H Y, Sun N N, Song X H, Guo Y T, Wei W, Sun Y H (2018). Porosity at the interface of organic matter and mineral components contribute significantly to gas adsorption on shales.J CO₂ Utilization, 28: 73–82

[56] Straley C, Vinegar H, Morriss C (1994). Core analysis by low field NMR.1994 International Symposium of the Society of Core Analysts, Proceedings: 43–56

[57] Streich R, Becken M, Ritter O (2010). Imaging of CO₂ storage sites, geothermal reservoirs, and gas shales using controlled-source magnetotellurics: Modeling studies.Geochemistry, 70: 63–75

[58] Sun H, Yao J, Gao S H, Fan D Y, Wang C C, Sun Z X (2013). Numerical study of CO₂ enhanced natural gas recovery and sequestration in shale gas reservoirs.Int J Greenh Gas Control, 19: 406–419

[59] Sun H Y, Zhao H, Qi N, Li Y (2017). Molecular insights into the enhanced shale gas recovery by carbon dioxide in Kerogen Slit Nanopores.J Phys Chem C, 121(18): 10233–10241

[60] Sun X X, Yao Y B, Liu D M, Zhou Y F (2018). Investigations of CO₂-water wettability of coal: NMR relaxation method.Int J Coal Geol, 188: 38–50

[61] Tang J P, Tian H N, Ma Y, Sun S J, Li W J (2017). Experimental study on desorption characteristics of gas in coal shale based on NMR technology. J Liaoning Technical U (Natural Science Edition), 36(3): 282–287 (in Chinese)

[62] Testamanti M N, Rezaee R (2019). Considerations for the acquisition and inversion of NMR T₂ data in shales.J Petrol Sci Eng, 174: 177–188

[63] Tian F, Li T T, Huang X, Dang H L (2020). Adsorption behavior of CH₄, C₂H₆, and CO₂ on moisture-equilibrated shale.Energy Fuels, 34(8): 9492–9497

[64] van Beek T A (2021). Low-field benchtop NMR spectroscopy: status and prospects in natural product analysis.Phytochem Anal, 32(1): 24–37

[65] Wang J, Zhang Y, Xie J (2020). Influencing factors and application prospects of CO₂ flooding in heterogeneous glutenite reservoirs.Sci Rep, 10(1): 1839

[66] Wang Q B (2019). Effects of clay mineral characteristics on shale adsorbed gas:based on the experimental analysis of shale samples in Longmaxi Formation of Dingshan Area, Southeast Sichuan. J Chongqing U Sci Techn (Natural Sciences Edition), 21(3): 20–24 (in Chinese)

[67] Wang X Q, Zhai Z Q, Jin X, Wu S T, Li J M, Sun L, Liu X D (2016). Molecular simulation of CO₂/CH₄ competitive adsorption in organic matter pores in shale under certain geological conditions.Pet Explor Dev, 43(5): 841–848

[68] Wang X Y, Xie J, Chen X J (2021). Applications of non-invasive and novel methods of low-field nuclear magnetic resonance and magnetic resonance imaging in aquatic products.Front Nutr, 8: 651804

[69] Washburn K E (2014). Relaxation mechanisms and shales.Concepts Magn Reson Part A Bridg Educ Res, 43A(3): 57–78

[70] Xie H P, Li X C, Fang Z M, Wang Y F, Li Q, Shi L, Bai B, Wei N, Hou Z M (2014). Carbon geological utilization and storage in China: current status and perspectives.Acta Geotech, 9(1): 7–27

[71] Xie Y C, Hou Z M, Liu H J, Cao C, Qi J G (2021). The sustainability assessment of CO₂ capture, utilization and storage (CCUS) and the conversion of cropland to forestland program (CCFP) in the Water-Energy-Food (WEF) framework towards China’s carbon neutrality by 2060.Environ Earth Sci, 80(14): 468

[72] Xu H, Tang D Z, Zhao J L, Li S (2015). A precise measurement method for shale porosity with low-field nuclear magnetic resonance: a case study of the Carboniferous-Permian strata in the Linxing area, eastern Ordos Basin, China.Fuel, 143: 47–54

[73] Yang Y, Liu S M (2020). Review of shale gas sorption and its models.Energy Fuels, 34(12): 15502–15524

[74] Yao Y B, Liu D M (2012). Comparison of low-field NMR and mercury intrusion porosimetry in characterizing pore size distributions of coals.Fuel, 95(1): 152–158

[75] Yao Y B, Liu D M, Liu J G, Xie S B (2015). Assessing the water migration and permeability of large intact bituminous and anthracite coals using NMR relaxation spectrometry.Transp Porous Media, 107(2): 527–542

[76] Yao Y B, Liu D M, Xie S B (2014). Quantitative characterization of methane adsorption on coal using a low-field NMR relaxation method.Int J Coal Geol, 131: 32–40

[77] Yao Y B, Liu J, Liu D M, Chen J Y, Pan Z J (2019). A new application of NMR in characterization of multiphase methane and adsorption capacity of shale.Int J Coal Geol, 201: 76–85

[78] Yin T T, Liu D M, Cai Y D, Zhou Y F, Yao Y B (2017). Size distribution and fractal characteristics of coal pores through nuclear magnetic resonance cryoporometry.Energy Fuels, 31(8): 7746–7757

[79] Zhang T, Ellis G S, Ruppel S C, Milliken K, Yang R (2012). Effect of organic-matter type and thermal maturity on methane adsoption in shale-gas systems.Org Geochem, 47(6): 120–131

[80] Zhao G, Wang C (2019). Influence of CO₂ on the adsorption of CH₄ on shale using low-field nuclear magnetic resonance technique.Fuel, 238: 51–58

[81] Zhao P, He B, Zhang B, Liu J (2022). Porosity of gas shale: is the NMR-based measurement reliable?.Petrol Sci, 19(2): 509–517

[82] Zhao P, Xie L, He B, Liu J (2020). Strategy optimization on industrial CO₂ sequestration in the depleted Wufeng-Longmaxi Formation Shale in the northeastern Sichuan Basin, SW China: from the perspective of environment and energy.ACS Sustain Chem & Eng, 8(30): 11435–11445

[83] Zhao P, Xie L Z, He B, Liu J (2021). Anisotropic permeability influencing the performance of free CH₄ and free CO₂ during the process of CO₂ sequestration and enhanced gas recovery (CS-EGR) from Shale.ACS Sustain Chem & Eng, 9(2): 914–926

[84] Zhou G Z, Hu Z M, Gu Z B, Chang J, Duan X G, Liu X G, Zhan H M (2021). Low-field NMR investigation of the dynamic adsorption–desorption process of shale gas.Energy Fuels, 35(6): 4762–4774

[85] Zhou J P, Yang K, Tian S F, Zhou L, Xian X F, Jiang Y D, Liu M H, Cai J C (2020). CO₂-water-shale interaction induced shale microstructural alteration.Fuel, 263: 116642

[86] Zhou W N, Wang H B, Yang Y Y, Liu X L (2019). Adsorption Mechanism of CO₂/CH₄ in Kaolinite Clay: insight from molecular simulation.Energy Fuels, 33(7): 6542–6551

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