Insights into lithium adsorption by coal-bearing strata kaolinite

Yu CHEN, Hao ZHAO, Mingzhe XIA, Hongfei CHENG

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Front. Earth Sci. ›› 2023, Vol. 17 ›› Issue (1) : 251-261. DOI: 10.1007/s11707-022-0989-y
RESEARCH ARTICLE
RESEARCH ARTICLE

Insights into lithium adsorption by coal-bearing strata kaolinite

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Abstract

The sharp increase in the demand for lithium (Li) for high-energy-storage battery materials due to its high specific energy and low negative chemical potential render Li a geopolitically significant resource. It is urgent to develop a low-cost, efficient method to improve lithium extraction. Herein, Li ion (Li+) adsorption in coal-bearing strata kaolinite (CSK) was studied. The effects of pre-activation acid leaching (meta-kaolinite/H2SO4, MK-HS) and dimethyl sulfoxide intercalation (coal-bearing strata kaolinite/dimethyl sulfoxide, CSK-DMSO) on the Li+ adsorption capacity were studied under the same adsorption conditions. The results indicated that the adsorption was completed in 60 min under alkaline conditions (pH = 8.5), a high solution concentration (400 mg/L), and a low dosage (1 g/100 mL); and the comprehensive adsorption capacity is MK-HS > CSK-DMSO > CSK. Furthermore, the DMSO intercalation caused the interlayer spacing of the CSK to increase, which provided more space for Li+ to enter and increase the adsorption capacity. After thermal pre-activation and acid leaching, structural failure and lattice collapse resulted in the presence of more micropores in the MK-HS, which resulted in a 10-fold increase in its specific surface area and caused coordination bond changes (Al(VI) to Al(IV)) and leaching of aluminum (Al) from the lattice. It is proposed that these structural changes greatly improve the activity of CSK so that Li+ cannot only adsorb onto the surface and between the layers but can also enter the lattice defects, which results in the MK-HS having the best adsorption performance. Combined with the adsorption kinetics analysis, the adsorption methods of CSK and two modified materials include physical adsorption and chemical adsorption. In this study, the adsorption capacity of CSK and its modified products to Li were explored, providing a new option for the reuse of CSK and the extraction of Li.

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Keywords

coal-bearing strata kaolinite / lithium / adsorption / modification

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Yu CHEN, Hao ZHAO, Mingzhe XIA, Hongfei CHENG. Insights into lithium adsorption by coal-bearing strata kaolinite. Front. Earth Sci., 2023, 17(1): 251‒261 https://doi.org/10.1007/s11707-022-0989-y

References

[1]
Adebowale K O, Unuabonah I E, Olu-Owolabi B I (2006). The effect of some operating variables on the adsorption of lead and cadmium ions on kaolinite clay.J Hazard Mater, 134(1–3): 130–139
CrossRef Pubmed Google scholar
[2]
Bhattacharyya K (2008). Kaolinite and montmorillonite as adsorbents for Fe(III), Co(II) and Ni(II) in aqueous medium. Appl Clay Sci, 41(1–2): 1–9
CrossRef Google scholar
[3]
Bhattacharyya K G, Gupta S S (2006). Kaolinite, montmorillonite, and their modified derivatives as adsorbents for removal of Cu(II) from aqueous solution.Separ Purif Tech, 50(3): 388–397
CrossRef Google scholar
[4]
Bulut Y, Tez Z (2007). Removal of heavy metals from aqueous solution by sawdust adsorption.J Environ Sci (China), 19(2): 160–166
CrossRef Pubmed Google scholar
[5]
Cao Z, Jia Y, Wang Q, Cheng H (2021). High-efficiency photo-Fenton Fe/g-C3N4/kaolinite catalyst for tetracycline hydrochloride degradation.Appl Clay Sci, 212: 106213
CrossRef Google scholar
[6]
Cheng H, Hou X, Liu Q, Li X, Frost R L (2015). New insights into the molecular structure of kaolinite–methanol intercalation complexes. Appl Clay Sci, 109–110: 55–63
CrossRef Google scholar
[7]
Cheng H, Huang Y, Zhu Z, Dong L, Zha J, Yu M (2021a). Enhanced PbCl2 adsorption capacity of modified kaolin in the furnace using a combined method of thermal pre-activation and acid impregnation.Chem Eng J, 414: 128672
CrossRef Google scholar
[8]
Cheng H, Liu Q, Cui X, Zhang Q, Zhang Z, Frost R L (2012a). Mechanism of dehydroxylation temperature decrease and high temperature phase transition of coal-bearing strata kaolinite intercalated by potassium acetate.J Colloid Interface Sci, 376(1): 47–56
CrossRef Pubmed Google scholar
[9]
Cheng H, Liu Q, Xu P, Hao R (2018). A comparison of molecular structure and de-intercalation kinetics of kaolinite/quaternary ammonium salt and alkylamine intercalation compounds.J Solid State Chem, 268: 36–44
CrossRef Google scholar
[10]
Cheng H, Liu Q, Yang J, Ma S, Frost R L (2012b). The thermal behavior of kaolinite intercalation complexes—a review.Thermochim Acta, 545: 1–13
CrossRef Google scholar
[11]
Cheng H, Liu Q, Zhang J, Yang J, Frost R L (2010). Delamination of kaolinite-potassium acetate intercalates by ball-milling.J Colloid Interface Sci, 348(2): 355–359
CrossRef Pubmed Google scholar
[12]
Cheng H, Zhou Y, Feng Y, Geng W, Liu Q, Guo W, Jiang L (2017). Electrokinetic energy conversion in self-assembled 2D nanofluidic channels with Janus Nanobuilding Blocks.Adv Mater, 29(23): 1700177
CrossRef Pubmed Google scholar
[13]
Cheng M, Yao C, Su Y, Liu J, Xu L, Hou S (2021b). Synthesis of membrane-type graphene oxide immobilized manganese dioxide adsorbent and its adsorption behavior for lithium ion.Chemosphere, 279: 130487
CrossRef Pubmed Google scholar
[14]
Grosjean C, Miranda P H, Perrin M, Poggi P (2012). Assessment of world lithium resources and consequences of their geographic distribution on the expected development of the electric vehicle industry.Renew Sustain Energy Rev, 16(3): 1735–1744
CrossRef Google scholar
[15]
Gupta S S, Bhattacharyya K G (2005). Interaction of metal ions with clays: I. A case study with Pb(II). Appl Clay Sci, 30(3–4): 199–208
CrossRef Google scholar
[16]
Harvianto G R, Kim S H, Ju C S (2016). Solvent extraction and stripping of lithium ion from aqueous solution and its application to seawater.Rare Met, 35(12): 948–953
CrossRef Google scholar
[17]
He K, Zeng G, Chen A, Huang Z, Peng M, Huang T, Chen G (2019). Graphene hybridized polydopamine-kaolin composite as effective adsorbent for methylene blue removal. Compos, Part B Eng, 161: 141–149
CrossRef Google scholar
[18]
Jia X, Cheng H, Zhou Y, Zhang S, Liu Q (2019). Time-efficient preparation and mechanism of methoxy-grafted kaolinite via acid treatment and heating.Appl Clay Sci, 174: 170–177
CrossRef Google scholar
[19]
Jiang M, Jin X, Lu X Q, Chen Z (2010). Adsorption of Pb(II), Cd(II), Ni(II) and Cu(II) onto natural kaolinite clay. Desalination, 252(1–3): 33–39
CrossRef Google scholar
[20]
Li J, Wang J (2019). Comprehensive utilization and environmental risks of coal gangue: a review.J Clean Prod, 239: 117946
CrossRef Google scholar
[21]
Li X, Deng Z, Li J (2017). Extraction of lithium from salt lake brine with kaolinite. Chemical Indus Eng Progress, 36(6): 2057–2063 (in Chinese)
[22]
Liu L, Wang D, Liu X, Li J, Dai H, Yan W (2017). The main types, distribution features and present situation of exploration and development for domestic and foreign lithium mine. Geo China, 44(002): 263–278 (in Chinese)
[23]
Luo Q, Dong M, Nie G, Liu Z, Wu Z, Li J (2021). Extraction of lithium from salt lake brines by granulated adsorbents.Colloids Surf A Physicochem Eng Asp, 628: 127256
CrossRef Google scholar
[24]
Makó É, Kovács A, Katona R, Kristóf T (2016). Characterization of kaolinite-cetyltrimethylammonium chloride intercalation complex synthesized through eco-friend kaolinite-urea pre-intercalation complex.Colloids Surf A Physicochem Eng Asp, 508: 265–273
CrossRef Google scholar
[25]
Paranthaman M P, Li L, Luo J, Hoke T, Ucar H, Moyer B A, Harrison S (2017). Recovery of Lithium from geothermal brine with Lithium-Aluminum layered double hydroxide chloride sorbents.Environ Sci Technol, 51(22): 13481–13486
CrossRef Pubmed Google scholar
[26]
Peng H, Cui C, Cai C, Li S and Zhang X (2014). Research on influence of calcination temperature on metakaolin reactivity and its determination. Bull Chinese Ceramic Soc, 33(8): 2078–2084+2094 (in Chinese)
[27]
Razmjou A, Asadnia M, Hosseini E, Habibnejad Korayem A, Chen V (2019). Design principles of ion selective nanostructured membranes for the extraction of lithium ions.Nat Commun, 10(1): 5793
CrossRef Pubmed Google scholar
[28]
Sen Gupta S, Bhattacharyya K G (2008). Immobilization of Pb(II), Cd(II) and Ni(II) ions on kaolinite and montmorillonite surfaces from aqueous medium.J Environ Manage, 87(1): 46–58
CrossRef Pubmed Google scholar
[29]
Sun Y, Wang Q, Wang Y H, Yun R P, Xiang X (2021). Recent advances in magnesium/lithium separation and lithium extraction technologies from salt lake brine.Separ Purif Tech, 256: 117807
CrossRef Google scholar
[30]
Suraj G, Iyer C, Lalithambika M (1998). Adsorption of cadmium and copper by modified kaolinites.Appl Clay Sci, 13(4): 293–306
CrossRef Google scholar
[31]
Swain B (2016). Separation and purification of lithium by solvent extraction and supported liquid membrane, analysis of their mechanism: a review.J Chem Technol Biotechnol, 91(10): 2549–2562
CrossRef Google scholar
[32]
Tao S, Bi-wan X, Hui-sheng S (2008). The evolution of coal gangue (CG)–calcium hydroxide (CH)–gypsum–H2O system.Mater Struct, 41(7): 1307–1314
CrossRef Google scholar
[33]
Uddin M K (2017). A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade.Chem Eng J, 308: 438–462
CrossRef Google scholar
[34]
Wang D, Liu Q, Hou D, Zhang S, Guo P, Cheng H (2017). Improved method for preparation of methoxy-modified kaolinite.J Braz Chem Soc, 29(1): 33–37
CrossRef Google scholar
[35]
Wang M Y, Wang X W, Jiang C J, Tao C F (2014). Solvent extraction of molybdenum from acidic leach solution of Ni–Mo ore.Rare Met, 33(1): 107–110
CrossRef Google scholar
[36]
Wang Y, Cheng H, Hu Q, Liu L, Jia L, Gao S, Wang Y (2022). Pore structure heterogeneity of Wufeng-Longmaxi shale, Sichuan Basin, China: evidence from gas physisorption and multifractal geometries.J Petrol Sci Eng, 208: 109313
CrossRef Google scholar
[37]
Wang Y, Liu L, Cheng H (2021b). Gas adsorption characterization of pore structure of organic-rich shale: insights into contribution of organic matter to shale pore network.Nat Resour Res, 30(3): 2377–2395
CrossRef Google scholar
[38]
Wimpenny J, Colla C A, Yu P, Yin Q Z, Rustad J R, Casey W H (2015). Lithium isotope fractionation during uptake by gibbsite.Geochim Cosmochim Acta, 168: 133–150
CrossRef Google scholar
[39]
Xing H, Liu H, Zhang X, Deng H, Hu H, Yao H J F (2019). Enhanced sodium adsorption capacity of kaolinite using a combined method of thermal pre-activation and intercalation-exfoliation: alleviating the problems of slagging and fouling during the combustion of Zhundong coal.Fuel, 239: 312–319
CrossRef Google scholar
[40]
Xu P, Hong J, Xu Z, Xia H, Ni Q Q (2021). Novel aminated graphene quantum dots (GQDs-NH2)-engineered nanofiltration membrane with high Mg2+/Li+ separation efficiency.Separ Purif Tech, 258: 118042
CrossRef Google scholar
[41]
Xu X, Chen Y, Wan P, Gasem K, Wang K, He T, Adidharma H, Fan M (2016). Extraction of lithium with functionalized lithium ion-sieves.Prog Mater Sci, 84: 276–313
CrossRef Google scholar
[42]
Zhang X, Saldi G D, Schott J, Bouchez J, Kuessner M, Montouillout V, Henehan M, Gaillardet J (2021). Experimental constraints on Li isotope fractionation during the interaction between kaolinite and seawater.Geochim Cosmochim Acta, 292: 333–347
CrossRef Google scholar
[43]
Zhao Y, Cao Z, Zuh A A, Jia Y, Wang Q, Cheng H (2022). Synthesis of bismuth oxyiodide/kaolinite composite with enhanced photocatalytic activity.J Phys Chem Solids, 161: 110424
CrossRef Google scholar
[44]
Zhao Y, Wu M, Shen P, Uytterhoeven C, Mamrol N, Shen J, Gao C, Van der Bruggen B (2021). Composite anti-scaling membrane made of interpenetrating networks of nanofibers for selective separation of lithium.J Membr Sci, 618: 118668
CrossRef Google scholar
[45]
Zhou Y, Cheng H, Wei C, Zhang Y (2021). Effect of acid activation on structural evolution and surface charge of different derived kaolinites.Appl Clay Sci, 203: 105997
CrossRef Google scholar
[46]
Zhou Y, LaChance A M, Smith A T, Cheng H, Liu Q, Sun L (2019). Strategic design of clay-based multifunctional materials: from natural minerals to nanostructured membranes.Adv Funct Mater, 29(16): 1807611
CrossRef Google scholar

Acknowledgments

The authors gratefully acknowledge the financial support provided by the National Natural Science Foundation of China (Grant No. 42172043), the Science and Technology Major Projects of Shanxi Province of China (No. 20181101003), the Fundamental Research Funds for the Central Universities (No. 300102299306), and Scientific Innovation Practive Project of Postgraduates of Chang’an University (No. 300103722045). The authors thank LetPub for its linguistic assistance during the preparation of this manuscript.

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2022 Higher Education Press 2022
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