Variabilities of carbonate δ¹³C signal in response to the late Paleozoic glaciations, Long’an, South China

Abstract

An integrated study of biostratigraphy, microfacies, and stable carbon isotope stratigraphy was carried out on the late Famennian–early Asselian carbonates of the Long’an section in Guangxi, South China. Stable carbon isotope studies in the Long’an section have revealed four major positive shifts of δ¹³C values in the Carboniferous strata in South China. The first shift occurred in the Siphonodella dasaibaensia zone in the Tournaisian, with an amplitude of 4.19‰. The second shift occurred near the Visean/Serpukhovian boundary, with an amplitude of 2.63‰. The third shift occurred in the Serpukhovian, with an amplitude of 3.95‰. The fourth shift occurred in the Kasimovian, with an amplitude of 3.69‰. Furthermore, there were several brief positive δ¹³C shifts during the late Famennian to early Tournaisian. All of these shifts can be well correlated globally, and each corresponds to sea-level regressions in South China and Euro-America, indicating increases in ocean primary productivity and global cooling events. Chronologically, the four major positive excursions of δ¹³C, together with several brief positive δ¹³C shifts that were observed during the late Famennian to the early Tournaisian, correspond to the well-accepted Glacial I, II, and III events.

Keywords

carbon isotopes / Late Paleozoic Ice Age / Carboniferous / sea-level changes / global climate variation

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Acknowledgments:

This paper has received both technical and financial supports respectively from the National Basic Research Program of China under the State Key Laboratory of Geological Process and Mineral Resources, China University of Geosciences (Wuhan) (No. KZ11K312), the National Natural Science Foundation of China (Grant No. 41702366) and the Fundamental Research Funds for the Central Universities (No. 3142018004)

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