Extraction and identification of elemental carbon in sediment and its environmental and climatic implications

ZHOU Bin1, SHEN Chengde2, ZHENG Hongbo3, CHEN Jinyang4

PDF(273 KB)
PDF(273 KB)
Front. Earth Sci. ›› 2008, Vol. 2 ›› Issue (2) : 131-137. DOI: 10.1007/s11707-008-0024-y

Extraction and identification of elemental carbon in sediment and its environmental and climatic implications

  • ZHOU Bin1, SHEN Chengde2, ZHENG Hongbo3, CHEN Jinyang4
Author information +
History +

Abstract

Elemental carbon was extracted from sediments by chemical oxidation and identified by Raman spectroscopy. The experimental results indicate that elemental carbon, defined by processing, is a continuum ranging from single crystal graphite to amorphous carbon. Chemical oxidation is a feasible method to extract elemental carbon from sediments, and when experimental condition and time are properly controlled, it can remove organic carbon without any loss of elemental carbon. However, due to the differences in experimental conditions and methods, different results have been obtained. Therefore, we believe that the determination of standard sample and its concentration as well as the unification of the experimental method are of great importance. Also, the unification and definition of all these carbon particulates can facilitate transect comparison and further research in related fields. In profile research, elemental carbon was extracted and determined by using the same method. The elemental carbon curve tends to change with other climatic proxies, indicating elemental carbon can provide another new proxy for climatic and environmental changes. Based on the analysis, we deduce that the elemental carbon record has different implications for climate and environmental changes on different timescales.

Cite this article

Download citation ▾
ZHOU Bin, SHEN Chengde, ZHENG Hongbo, CHEN Jinyang. Extraction and identification of elemental carbon in sediment and its environmental and climatic implications. Front. Earth Sci., 2008, 2(2): 131‒137 https://doi.org/10.1007/s11707-008-0024-y

References

1. Bird M I Cali J A 1998 A million-yearrecord of fire in sub-Saharan AfricaNature394(6695)767769. doi:10.1038/29507
2. Bird M I Grocke D 1997 Determinationof the abundance and carbon-isotope composition of elemental carbonin sedimentsGeochim Cosmochim Acta61(16)34133423. doi:10.1016/S0016‐7037(97)00157‐9
3. Cachier H Brémond M P Buat-Ménard P 1989 Determination of atmosphericsoot carbon with a simple thermal methodTellus41B379390
4. Chylek P Johnson B Wu H 1992 Black carbon concentration in a Green1and Dye-3 ice coreGeophys Res Lett19(19)19511953. doi:10.1029/92GL01904
5. Ducret J Cachier H 1992 Particulatecarbon content in rain at various temperate and tropical locationsJ Atmos Chem155567. doi:10.1007/BF00053609
6. Gilbert L M 1962 Fire as a factor in the development of vegetation typesAust Fores266770
7. Goldberg E D 1985 Black carbon in the environmentalJohn WileyNew York1198
8. Gustafsson O Bucheli T D Kukulska Z et al. 2001 Evaluation of a protocol for thequantification of black carbonGlobal BiogeochemicalCycles15881890. doi:10.1029/2000GB001380
9. Gustafsson O Haghseta F Chan C et al. 1997 Quantification of the dilute sedimentarysoot phase: Implications for PAH speciation and bioavailabilityEnviron Sci Technol2416871693
10. Imbrie J Hays J D Martinson D G et al. 1984 The orbital theory of Pleistoceneclimate: Support from a revised chronology of the marine 18O recordIn: Berger AImbrie JHays J et al.Milankovitch and ClimateReidelDordrecht269306
11. Jia G D 2000 Bio-geochemical record in sediments from South China Seasince the last 30 ky[Dissertation]GuangzhouGuangzhouInstitute of Geochemistry, Chinese Academy of Sciences (in Chinese with English abstract)
12. Lavanchy V M H Gaggeler H W Nyeki S et al. 1999 Elemental carbon (EC) and blackcarbon (BC) measurements with a thermal method and an aethalometerat the high-alpine research station JungfraujochAtmoshperic Environment3327592769. doi:10.1016/S1352‐2310(98)00328‐8
13. Lim B Cachier H 1996 Determinationof black carbon by chemical oxidation and thermal treatment in recentmarine and lake sediments and Cretaceous-Tertiary claysChemical Geology131143154. doi:10.1016/0009‐2541(96)00031‐9
14. Luo Y L Chen H C Wu G X et al. 2001 Records of natural fire and climatehistory during the last three glacial-interglacial cycles around theSouth China Sea-Charcoal record from the ODP 1114Science in China (Series D)30(10)854860 (in Chinese)
15. Middelburg J J Nieuwenhuize J van Breugel P 1999 Black carbon in marine sedimentsMar Chem65245252. doi:10.1016/S0304‐4203(99)00005‐5
16. Patterson W A Edwards K J Maguire K J et al. 1987 Microscopic charcoal as a fossilindicator of fireQuat Sci Rev6323. doi:10.1016/0277‐3791(87)90012‐6
17. Penner J E Novakov T 1996 Carbonaceousparticles in the atmosphere: A historyical perspective to the Fifthinternattional conference on carbonaceous particles in the atmosphereJournal of Geophysical Research1011937319378. doi:10.1029/96JD01175
18. Schmidt M W I Skjemstad J O Czimczik C I et al. 2001 Comparative analysis of black carbonin soilsGlobal Biogeochemical Cycles15(1)163167. doi:10.1029/2000GB001284
19. Shen C D Yi W X Yang Y et al. 2004 Concentrations of “elementalcarbon” in samples from the Peking Man Site at Zhoukoudian andthe possibility of their application in the development of evidencefor the use of fire by humansChinese ScienceBulletin49(3)275278 (in Chinese). doi: 10.1360/03wd0620
20. Singh G Geissler E A 1985 Late Cainozoichistory of fire, lake levels and climate at Lake George New SouthWales, AustraliaPhilos Trans R Soc London311379447. doi:10.1098/rstb.1985.0156
21. Smith D M Griffin J J Goldberg E D 1973 Elemental carbon in marine sediment: Abaseline for burningNature241268270. doi:10.1038/241268a0
22. Sun X J Li X Chen H C 2000 Evidence for natural fire and climatehistory since 37 ka BP in the northern part of the South China SeaScience in China (Series D)30(2)163168 (in Chinese)
23. Sun Y B 2000 The grain size of quatz and variability of eolian fluxin the Chinese Loess Plateau since the late Cenozoic[Dissertation]BeijingInstitute of Geology and Geophysics, Chinese Academyof Sciences (in Chinese with English abstract)
24. Verardo D J Ruddiman W F 1996 Late Pleistocenecharcoal in tropical Atlantic deep-sea sediments: Climatic and geochemicalsignificanceGeology24(9)855857. doi:10.1130/0091‐7613(1996)024<0855:LPCITA>2.3.CO;2
25. Winkler M G 1985 Charcoal analysis for paleoenvironmental interpretation:A chemical assayQuaternary Research23313326. doi:10.1016/0033‐5894(85)90038‐9
26. Wolbach W S Anders E 1989 Elementalcarbon in sediments: Determination and isotopic analysis in the presenceof kerogenGeochimica Et Cosmochimica Acta53(7)16371647. doi:10.1016/0016‐7037(89)90245‐7
27. Wolbach W S Anders E Nazarov M A 1990 Fires at the K/T boundary: Carbon at theSumbar, Turkmenia, siteGeochimica et CosmochimicaActa54(4)11331146. doi:10.1016/0016‐7037(90)90444‐P
28. Yang Y Shen C D Yi W X et al. 2001 The elemental carbon record inWeinan loess since the last 21 kaChineseScience Bulletin46(18)15411544. doi:10.1007/BF02900576
29. Zeng Y S Wu C D 2005 Experimentalstudy of the influence of temperature and water on the structure stateof kerogen at 100 MPa pressureActa PetrologicaSinica21(1)245250 (in Chinese)
30. Zheng Z Chen X H 1994 Raman spectraof coal-based graphiteScience in China(Ser B)24(6)640647 (in Chinese)
31. Zhou B Shen C D Shen Y M et al. 2006 A biomass burning record from theChinese loess since L4 layer: Indicator, environmental and climaticimplicationsChinese Science Bullitin51(10)12111217 (in Chinese)
32. Zhou B Shen C D Sun W D et al. 2007 Elemental carbon record of paleofirehistory on the Chinese Loess Plateau during the last 420 ka andits response to environmental and climate changesPalaeogeography, Palaeoclimatology, Palaeoecology252(3–4)617625. doi:10.1016/j.palaeo.2007.05.014
33. Zhou B Shen C D Yi W X et al. 2002 The determination and study ofelemental carbon in soilSoil and environment11(2)133135
34. Zhou B 2005 The record of elemental carbon in the Loess of LingtaiSection since the Late Cenozoic and the environment and climate change[Dissertation]GuangzhouGuangzhou Institute ofGeochemistry, Chinese Academy of Sciences (inChinese with English abstract)
AI Summary AI Mindmap
PDF(273 KB)

Accesses

Citations

Detail

Sections
Recommended

/