Applications of Lignin-Dervied Carbon Quantum Dots: Current Status and Challenges

Xiuxin Yin , Zhili Zhang , Fengfeng Li , Maoqing Fu , Tianci Qin , Xingxiang Ji , Yuanyuan Wang , Zhiwen Wang , Shaolong Sun

Exploration ›› 2025, Vol. 5 ›› Issue (3) : 70039

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Exploration ›› 2025, Vol. 5 ›› Issue (3) : 70039 DOI: 10.1002/EXP.70039
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Applications of Lignin-Dervied Carbon Quantum Dots: Current Status and Challenges

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Abstract

In recent years, lignin has attracted substantial attention from researchers because of its diverse sources, low cost, and renewability. The effective functionalization and enhanced value-added utilization of lignin have successfully addressed the challenges associated with biomass resource waste, low utilization rate, high material cost, and underwhelming performance in energy, environmental protection, and medical applications. The emergence of lignin carbon quantum dots (LCQDs) has opened new avenues for the development and utilization of lignin by offering exciting opportunities for their applications. LCQDs possess unique characteristics such as fluorescence properties, size effect, surface effect, and interface effects, which are promising for applications in many fields. This paper provides a comprehensive overview of the structure and applications of lignin with a specific focus on the preparation method of LCQDs as well as their various applications in drug delivery systems, electrode material fabrication, and antibacterial agent development. Furthermore, this study offers valuable insights into the prospects of LCQDs and aims to contribute to their functional development. Finally, the challenges associated with leveraging the fluorescence properties of LCQDs are discussed, along with potential directions for future research.

Keywords

application / fluorescence properties / LCQDs / lignin / preparation

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Xiuxin Yin, Zhili Zhang, Fengfeng Li, Maoqing Fu, Tianci Qin, Xingxiang Ji, Yuanyuan Wang, Zhiwen Wang, Shaolong Sun. Applications of Lignin-Dervied Carbon Quantum Dots: Current Status and Challenges. Exploration, 2025, 5(3): 70039 DOI:10.1002/EXP.70039

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References

[1]

Y. Xie, S. Gao, D. Zhang, C. Wang, and F. Chu, “Bio-Based Polymeric Materials Synthesized From Renewable Resources: A Mini-Review,” Resources Chemicals and Materials 2 (2023): 223-230.

[2]

W. Qu, X. Han, J. Liu, L. Yin, C. Liang, and P. Hu, “Unlocking The Graphitization Potential of Lignin: Insights Into Its Transformation Through Hot Pressing and Carbonization,” Green Chemistry 25, no. 23 (2023): 9873-9883.

[3]

H. Huang, C. Zheng, C. Huang, and S. Wang, “Dissolution Behavior of Ionic Liquids for Different Ratios of Lignin and Cellulose in the Preparation of Nanocellulose/Lignin Blends,” Journal of Colloid and Interface Science 657 (2024): 767-777.

[4]

S. Yang, Z. Zhang, X. Qiu, et al., “Engineering of the Microstructures of Enzymatic Hydrolysis Lignin-Derived Hard Carbon Anodes for Sodium-Ion Batteries,” Resources Chemicals and Materials 2 (2023): 245-251.

[5]

G. Zhao, K. Ning, M. Wei, et al., “Fabrication and Enhanced Supercapacitive Performance of Fe2N@Cotton-Based Porous Carbon Fibers as Electrode Material,” Resources Chemicals and Materials 2 (2023): 277-287.

[6]

X. Chen, Z. Li, L. Zhang, et al., “Preparation of a Novel Lignin-based Film With High Solid Content and Its Physicochemical Characteristics,” Industrial Crops and Products 164 (2021): 113396.

[7]

B. Zhang, Y. Liu, M. Ren, et al., “Sustainable Synthesis of Bright Green Fluorescent Nitrogen-Doped Carbon Quantum Dots From Alkali Lignin,” Chemsuschem 12 (2019): 4202-4210.

[8]

L. Zhu, D. Shen, Q. Liu, K. H. Luo, and C. Li, “Mild Acidolysis-Assisted Hydrothermal Carbonization of Lignin for Simultaneous Preparation of Green and Blue Fluorescent Carbon Quantum Dots,” ACS Sustainable Chemistry & Engineering 10 (2022): 9888-9898.

[9]

X. Liu, S. Zhao, X. Chen, et al., “The Effect of Lignin Molecular Weight on the Formation and Properties of Carbon Quantum Dots,” Green Chemistry 26 (2024): 3190-3201.

[10]

S. Zhao, X. Chen, C. Zhang, P. Zhao, A. J. Ragauskas, and X. Song, “Fluorescence Enhancement of Lignin-Based Carbon Quantum Dots by Concentration-Dependent and Electron-Donating Substituent Synergy and Their Cell Imaging Applications,” ACS Applied Materials & Interfaces Journal 13 (2021): 61565-61577.

[11]

S. W. Park, S. H. Im, W. T. Hong, H. K. Yang, and Y. K. Jung, “Lignin-Derived Carbon Quantum Dot/PVA Films for Totally Blocking UV and High-energy Blue Light,” International Journal of Biological Macromolecules 268 (2024): 131919.

[12]

X. Gao, X. Zhou, Y. Ma, T. Qian, C. Wang, and F. Chu, “Facile and Cost-Effective Preparation of Carbon Quantum Dots for Fe3+ Ion and Ascorbic Acid Detection in Living Cells Based on the “On-Off-On” Fluorescence Principle,” Applied Surface Science 469 (2019): 911-916.

[13]

Z. Cheng, J. Ren, Y. Li, W. Chang, and Z. Chen, “Study on the Multiple Mechanisms Underlying the Reaction Between Hydroxyl Radical and Phenolic Compounds by Qualitative Structure and Activity Relationship,” Bioorganic & Medicinal Chemistry 10 (2002): 4067-4073.

[14]

S. Wang, G. Dai, H. Yang, and Z. Luo, “Lignocellulosic Biomass Pyrolysis Mechanism: A State-of-the-Art Review,” Progress in Energy and Combustion Science 62 (2017): 33-86.

[15]

E. Melro, L. Alves, F. E. Antunes, and B. Medronho, “A Brief Overview on Lignin Dissolution,” Journal of Molecular Liquids 265 (2018): 578-584.

[16]

R. S. C. Woo, H. Zhu, C. K. Y. Leung, and J.-K. Kim, “Environmental Degradation of Epoxy-Organoclay Nanocomposites Due to UV Exposure: Part II Residual Mechanical Properties,” Composites Science and Technology 68 (2008): 2149-2155.

[17]

D. J. Patil and S. N. Behera, “Synthesis and Characterization of Nanoparticles of Cobalt and Nickel Ferrites for Elimination of Hazardous Organic Dyes From Industrial Wastewater,” Environmental Science and Pollution Research 30 (2023): 53323-53338.

[18]

Z. E. Zadeh, A. Abdulkhani, O. Aboelazayem, and B. Saha, “Recent Insights Into Lignocellulosic Biomass Pyrolysis: A Critical Review on Pretreatment, Characterization, and Products Upgrading,” Processes 8 (2020): 799.

[19]

X. Zhu, G. Jiang, G. Wang, et al., “Cellulose-Based Functional Gels and Applications in Flexible Supercapacitors,” Resources Chemicals and Materials 2 (2023): 177-188.

[20]

X. Chen, T. Guo, X. Mo, et al., “Reduced Nutrient Release and Greenhouse Gas Emissions of Lignin-based Coated Urea by Synergy of Carbon Black and Polysiloxane,” International Journal of Biological Macromolecules 231 (2023): 123334.

[21]

W. H. Gong, C. Zhang, J. W. He, et al., “A Synergistic Hydrothermal-Deep Eutectic Solvents (DES) Pretreatment for Acquiring Xylooligosaccharides and Lignin Nanoparticles From Eucommia ulmoides Wood,” International Journal of Biological Macromolecules 209 (2022): 188-197.

[22]

Q. Ma, C. Yu, Y. Zhou, D. Hu, J. Chen, and X. Zhang, “A Review on the Calculation and Application of Lignin Hansen Solubility Parameters,” International Journal of Biological Macromolecules 256 (2024): 128506.

[23]

W. Zhong, W. Su, P. Li, K. Li, W. Wu, and B. Jiang, “Preparation and Research Progress of Lignin-Based Supercapacitor Electrode Materials,” International Journal of Biological Macromolecules 259 (2023): 128942.

[24]

D. R. Naron, F. X. Collard, and L. Tyhoda, J. F. Görgens, “Characterisation of Lignins From Different Sources by Appropriate Analytical Methods: Introducing Thermogravimetric Analysis-Thermal Desorption-Gas Chromatography-Mass Spectroscopy,” Industrial Crops and Products 101 (2017): 61-74.

[25]

J. Ralph, C. Lapierre, and W. Boerjan, “Lignin Structure and Its Engineering,” Current Opinion in Biotechnology 56 (2019): 240-249.

[26]

W. Kusiak, J. Majka, I. Ratajczak, M. Górska, and M. Zborowska, “Evaluation of Environmental Impact on Selected Properties of Lime (Tilia cordata Mill.) Wood,” Forests 11 (2020): 746.

[27]

J. Chen, X. Fan, L. Zhang, X. Chen, S. Sun, and R.-C. Sun, “Research Progress in Lignin-Based Slow/Controlled Release Fertilizer,” Chemsuschem 13 (2020): 4356-4366.

[28]

C. C. Lo, Y. W. Chang, Y. L. Chen, Y. L. Liu, H. S. Wu, and Y. M. Sun, “Lignin Recovery From Rice Straw Biorefinery Solid Waste by Soda Process With Ethylene Glycol as co-solvent,” Journal of the Taiwan Institute of Chemical Engineers 126 (2021): 50-57.

[29]

X. Meng, Y. Pu, P. Sannigrahi, M. Li, S. Cao, and A. J. Ragauskas, “The Nature of Hololignin,” ACS Sustainable Chemistry & Engineering 6, no. 1 (2018): 957-964.

[30]

N. Giummarella, I. V. Pylypchuk, O. Sevastyanova, and M. Lawoko, “New Structures in Eucalyptus Kraft Lignin With Complex Mechanistic Implications,” ACS Sustainable Chemistry & Engineering 8, no. 29 (2020): 10983-10994.

[31]

B. Hararak, W. Wanmolee, P. Wijaranakul, et al., “Physicochemical Properties of Lignin Nanoparticles From Softwood and Their Potential Application in Sustainable Pre-Harvest Bagging as Transparent UV-Shielding Films,” International Journal of Biological Macromolecules 229 (2023): 575-588.

[32]

J. M. Ha, K. R. Hwang, Y. M. Kim, et al., “Recent Progress in the Thermal and Catalytic Conversion of Lignin,” Renewable and Sustainable Energy Reviews 111 (2019): 422-441.

[33]

W. Zhang, J. Shen, P. Gao, Q. Jiang, and W. Xia, “An Eco-Friendly Strategy for Preparing Lignin Nanoparticles by Self-Assembly: Characterization, Stability, Bioactivity, and Pickering Emulsion,” Industrial Crops and Products 188 (2022): 115651.

[34]

J. Yang, J. Dai, X. Liu, S. Fu, E. Zong, and P. Song, “A Lignin-based Epoxy/TiO2 Hybrid Nanoparticle for Multifunctional Bio-based Epoxy With Improved Mechanical, UV Absorption and Antibacterial Properties,” International Journal of Biological Macromolecules 210 (2022): 85-93.

[35]

Q. Zhou, J. Chen, C. Wang, et al., “Preparation and Characterization of Lignin Nanoparticles and Chitin Nanofibers Reinforced PVA Films With UV Shielding Properties,” Industrial Crops and Products 188 (2022): 115669.

[36]

Y. Wang, J. Hou, Y. Huang, and Y. Fu, “Structure-Controlled Lignin Complex for PLA Composites With Outstanding Antibacterial, Fluorescent and Photothermal Conversion Properties,” International Journal of Biological Macromolecules 194 (2022): 1002-1009.

[37]

J. Zhang, Z. Tian, X.-X. Ji, and F. Zhang, “Light-Colored Lignin Extraction by Ultrafiltration Membrane Fractionation for Lignin Nanoparticles Preparation as UV-Blocking Sunscreen,” International Journal of Biological Macromolecules 231 (2023): 123244.

[38]

P. Miele, S. Bernard, D. Cornu, and B. Toury, “Recent Developments in Polymer-Derived Ceramic Fibers (PDCFs): Preparation, Properties and Applications—A Review,” Soft Materials 4 (2007): 249-286.

[39]

J. Rumpf, F. Armbruster, J. Frase, et al., “The Potential of Miscanthus as Lignocellulose Feedstock for the Development of Novel Packaging Materials,” paper presented at the International Society for Miscanthus and perennial Energy Grasses (MEG), Cheb, October 29-31, 2019.

[40]

K. Crouvisier-Urion, P. R. Bodart, P. Winckler, et al., “Biobased Composite Films from Chitosan and Lignin: Antioxidant Activity Related to Structure and Moisture,” ACS Sustainable Chemistry & Engineering 4, no. 12 (2016): 6371-6381.

[41]

Y. Qian, X. Zhong, Y. Li, and X. Qiu, “Fabrication of Uniform Lignin Colloidal Spheres for Developing Natural Broad-Spectrum Sunscreens With High Sun Protection Factor,” Industrial Crops and Products 101 (2017): 54-60.

[42]

D. Tian, J. Hu, J. Bao, R. P. Chandra, J. N. Saddler, and C. Lu, “Lignin Valorization: Lignin Nanoparticles as High-Value Bio-Additive for Multifunctional Nanocomposites,” Biotechnology for Biofuels 10 (2017): 192.

[43]

Y. Wang, X. Ji, Q. Wang, et al., “Recent Advanced Application of Lignin Nanoparticles in the Functional Composites: A Mini-Review,” International Journal of Biological Macromolecules 222 (2022): 2498-2511.

[44]

L. Wu, S. Liu, Q. Wang, et al., “High Strength and Multifunctional Polyurethane Film Incorporated With Lignin Nanoparticles,” Industrial Crops and Products 177 (2022): 114526.

[45]

H. Cui, W. Jiang, C. Wang, et al., “Lignin Nanofiller-Reinforced Composites Hydrogels With Long-Lasting Adhesiveness, Toughness, Excellent Self-Healing, Conducting, Ultraviolet-Blocking and Antibacterial Properties,” Composites Part B: Engineering 225 (2021): 109316.

[46]

F. Huang, X. Cai, X. Hou, et al., “A Dynamic Covalent Polymeric Antimicrobial for Conquering Drug-Resistant Bacterial Infection,” Exploration 2 (2022): 20210145.

[47]

G. Awiaz, J. Lin, and A. Wu, “Recent Advances of Au@Ag Core-shell SERS-Based Biosensors,” Exploration 3 (2023): 20220072.

[48]

T. E. Nypelö, C. A. Carrillo, and O. J. Rojas, “Lignin Supracolloids Synthesized From (W/O) Microemulsions: Use in the Interfacial Stabilization of Pickering Systems and Organic Carriers for Silver Metal,” Soft Matter 11 (2015): 2046-2054.

[49]

J. Lu, X. Gao, S. Wang, et al., “Advanced Strategies to Evade the Mononuclear Phagocyte System Clearance of Nanomaterials,” Exploration 3 (2023): 20220045.

[50]

L. Tu, Z. Liao, Z. Luo, Y.-L. Wu, A. Herrmann, and S. Huo, “Ultrasound-Controlled Drug Release and Drug Activation for Cancer Therapy,” Exploration 1 (2021): 20210023.

[51]

B. Du, W. Li, Y. Bai, et al., “Fabrication of Uniform Lignin Nanoparticles With Tunable Size for Potential Wound Healing Application,” International Journal of Biological Macromolecules 214 (2022): 170-180.

[52]

D. Yiamsawas, S. J. Beckers, H. Lu, K. Landfester, and F. R. Wurm, “Morphology-Controlled Synthesis of Lignin Nanocarriers for Drug Delivery and Carbon Materials,” ACS Sustainable Chemistry & Engineering 3 (2017): 2375-2383.

[53]

M. Jabli, “Preparation of Alkali Lignin Extracted From Ligno-cellulosic Populus Tremula Fibers: Application to Copper Oxide Nanoparticles Synthesis, Characterization, and Methylene Blue Biosorption Study,” International Journal of Biological Macromolecules 226 (2023): 956-964.

[54]

W. Yang, E. Fortunati, D. Gao, et al., “Valorization of Acid Isolated High Yield Lignin Nanoparticles as Innovative Antioxidant/Antimicrobial Organic Materials,” ACS Sustainable Chemistry & Engineering 6, no. 3 (2018): 3502-3514.

[55]

W. Yang, E. Fortunati, F. Bertoglio, J. S. Owczarek, and D. Puglia, “Polyvinyl Alcohol/Chitosan Hydrogels With Enhanced Antioxidant and Antibacterial Properties Induced by Lignin Nanoparticles,” Carbohydrate Polymers 181 (2018): 275-284.

[56]

W. Yang, F. Xu, X. Ma, et al., “Highly-Toughened PVA/Nanocellulose Hydrogels With Anti-Oxidative and Antibacterial Properties Triggered by Lignin-Ag Nanoparticles,” Materials Science and Engineering C 129 (2021): 112385.

[57]

Z. Zhang, F. Vogelbacher, Y. Song, Y. Tian, and M. Li, “Bio-Inspired Optical Structures for Enhancing Luminescence,” Exploration 3 (2023): 20220052.

[58]

M. Yang, H. Li, J. Shen, et al., “Repurposing Lignin to Generate Functional Afterglow Paper,” Cell Reports Physical Science 3 (2022): 100867.

[59]

F. Xiong, Y. Han, G. Li, T. Qin, S. Wang, and F. Chu, “Synthesis and Characterization of Renewable Woody Nanoparticles Fluorescently Labeled by Pyrene,” Industrial Crops and Products 83 (2016): 663-669.

[60]

Y. Xue, X. Qiu, Y. Wu, et al., “Aggregation-induced Emission: The Origin of Lignin Fluorescence,” Polymer Chemistry 7 (2016): 3502-3508.

[61]

X. Yang, S. Hou, T. Chu, et al., “Preparation of Magnesium, Nitrogen-Codoped Carbon Quantum Dots From Lignin With Bright Green Fluorescence and Sensitive pH Response,” Industrial Crops and Products 167 (2021): 113507.

[62]

M. Si, J. Zhang, Y. He, et al., “Synchronous and Rapid Preparation of Lignin Nanoparticles and Carbon Quantum Dots From Natural Lignocellulose,” Green Chemistry 20 (2018): 3414-3419.

[63]

W. Chao, Y. Li, X. Sun, G. Cao, C. Wang, and S.-H. Ho, “Enhanced Wood-Derived Photothermal Evaporation System by In-Situ Incorporated Lignin Carbon Quantum Dots,” Chemical Engineering Journal 405 (2021): 126703.

[64]

H. Zhang, Y. Liu, and S. Qu, “Recent Advances in Photo-Responsive Carbon Dots for Tumor Therapy,” Responsive Materials 2, no. 2 (2024): e20240012.

[65]

T. Zhang, Q. Cheng, J. H. Lei, et al., “Constructing Oxygen-Related Defects in Carbon Nanodots With Janus Optical Properties: Noninvasive NIR Fluorescent Imaging and Effective Photocatalytic Therapy,” Advanced Materials 35 (2023): 2302705.

[66]

Z. A. Qiao, Y. Wang, Y. Gao, et al., “Commercially Activated Carbon as the Source for Producing Multicolor Photoluminescent Carbon Dots by Chemical Oxidation,” Chemical Communications 46 (2009): 8812.

[67]

M. Tuerhong, Y. Xu, and X. B. Yin, “Review on Carbon Dots and Their Applications,” Chinese Journal of Analytical Chemistry 45 (2017): 139-150.

[68]

J. Wang, C. F. Wang, and S. Chen, “Amphiphilic Egg-Derived Carbon Dots: Rapid Plasma Fabrication, Pyrolysis Process, and Multicolor Printing Patterns,” Angewandte Chemie International Edition 51 (2012): 9297-9301.

[69]

Y. Liu, D. Cheng, B. Wang, et al., “Carbon Dots-Inked Paper With Single/Two-Photon Excited Dual-Mode Thermochromic Afterglow for Advanced Dynamic Information Encryption,” Advanced Materials 36 (2024): 2403775.

[70]

Z. H. Liu, B.-Z. Li, J. S. Yuan, and Y. J. Yuan, “Creative Biological Lignin Conversion Routes Toward Lignin Valorization,” Trends in Biotechnology 40 (2022): 1550-1566.

[71]

T. Aro and P. Fatehi, “Production and Application of Lignosulfonates and Sulfonated Lignin,” Chemsuschem 10 (2017): 1861-1877.

[72]

Z. Pang, Y. Fu, H. Yu, et al., “Efficient Ethanol Solvothermal Synthesis of High-Performance Nitrogen-Doped Carbon Quantum Dots From Lignin for Metal Ion Nanosensing and Cell Imaging,” Industrial Crops and Products 183 (2022): 114957.

[73]

J. Xu, P. Zhou, L. Yuan, X. Liu, J. Ma, and C. Zhang, “Dual Lignin Valorization Enabled by Carbon Quantum Dots and Lithium-Sulfur Cathode,” Industrial Crops and Products 170 (2021): 113801.

[74]

Z. Zhu, R. Cheng, L. Ling, Q. Li, and S. Chen, “Rapid and Large-Scale Production of Multi-Fluorescence Carbon Dots by a Magnetic Hyperthermia Method,” Angewandte Chemie International Edition 59 (2020): 3099-3105.

[75]

L. Hao, Y. Yu, Z. Liang, et al., “Deciphering Photocatalytic Degradation of Methylene Blue by Surface-Tailored Nitrogen-Doped Carbon Quantum Dots Derived From Kraft Lignin,” International Journal of Biological Macromolecules 242 (2023): 124958.

[76]

W. Chen, C. Hu, Y. Yang, J. Cui, and Y. Liu, “Rapid Synthesis of Carbon Dots by Hydrothermal Treatment of Lignin,” Materials 9 (2016): 184.

[77]

Z. Ding, F. Li, J. Wen, X. Wang, and R. Sun, “Gram-Scale Synthesis of Single-Crystalline Graphene Quantum Dots Derived From Lignin Biomass,” Green Chemistry 20 (2018): 1383-1390.

[78]

S. Zhao, X. Chen, J. Su, et al., “Interaction of Lignin and Xylan in the Hydrothermal Synthesis of Lignocellulose-Based Carbon Quantum Dots and Their Application in In-Vivo Bioimaging,” International Journal of Biological Macromolecules 222 (2022): 1876-1887.

[79]

J. Hou, J. Yan, Q. Zhao, Y. Li, H. Ding, and L. Ding, “A Novel One-Pot Route for Large-Scale Preparation of Highly Photoluminescent Carbon Quantum Dots Powders,” Nanoscale 5 (2013): 9558.

[80]

H. Zhu, X. Wang, Y. Li, Z. Wang, F. Yang, and X. Yang, “Microwave Synthesis of Fluorescent Carbon Nanoparticles With Electrochemiluminescence Properties,” Chemical Communications 2009, no. 34 (2009): 5118.

[81]

J. Wang, C. Cheng, Y. Huang, et al., “A Facile Large-Scale Microwave Synthesis of Highly Fluorescent Carbon Dots From Benzenediol Isomers,” Journal of Materials Chemistry C 2 (2014): 5028-5035.

[82]

Z. Ma, Y. Han, X. Wang, G. Sun, and Y. Li, “Lignin-Derived Hierarchical Porous Flower-Like Carbon Nanosheets Decorated With Biomass Carbon Quantum Dots for Efficient Oxygen Reduction,” Colloids Surf A Physicochem Eng Asp 652 (2022): 129818.

[83]

S. Rai, B. K. Singh, P. Bhartiya, et al., “Lignin Derived Reduced Fluorescence Carbon Dots With Theranostic Approaches: Nano-Drug-Carrier and Bioimaging,” Journal of Luminescence 190 (2017): 492-503.

[84]

H. Li, X. He, L. Yang, et al., “One-Step Ultrasonic Synthesis of Water-Soluble Carbon Nanoparticles With Excellent Photoluminescent Properties,” Carbon 49 (2011): 605-609.

[85]

Z. Ma, H. Ming, H. Huang, Y. Liu, and Z. Kang, “One-Step Ultrasonic Synthesis of Fluorescent N-Doped Carbon Dots From Glucose and Their Visible-Light Sensitive Photocatalytic Ability,” New Journal of Chemistry 36 (2012): 861.

[86]

X.-H. Shen, J.-H. Zhang, H. Li, J.-J. Wang, and X.-C. Wang, “Ultrasonic Vibration-Assisted Milling of Aluminum Alloy,” International Journal of Advanced Manufacturing Technology 63 (2012): 41-49.

[87]

H. Huang, Y. Cui, M. Liu, et al., “A One-Step Ultrasonic Irradiation Assisted Strategy for the Preparation of Polymer-Functionalized Carbon Quantum Dots and Their Biological Imaging,” Journal of Colloid and Interface Science 532 (2018): 767-773.

[88]

C. Qi, H. Wang, A. Yang, X. Wang, and J. Xu, “Facile Fabrication of Highly Fluorescent N-Doped Carbon Quantum Dots Using an Ultrasonic-Assisted Hydrothermal Method: Optical Properties and Cell Imaging,” ACS Omega 6 (2021): 32904-32916.

[89]

Z. Hu, X.-Y. Jiao, and L. Xu, “The N,S Co-Doped Carbon Dots With Excellent Luminescent Properties From Green Tea Leaf Residue and Its Sensing of Gefitinib,” Microchemical Journal 154 (2020): 104588.

[90]

B. Lei, C. Liu, Z. L. Zhang, and D. W. Pang, “Photoluminescence-Tunable Carbon Nanodots: Surface-State Energy-Gap Tuning,” Advanced Materials 27 (2015): 1663-1667.

[91]

S. Hu, Z. Wei, Q. Chang, A. Trinchi, and J. Yang, “A Facile and Green Method Towards Coal-Based Fluorescent Carbon Dots With Photocatalytic Activity,” Applied Surface Science 378 (2016): 402-407.

[92]

S. Zhu, Y. Song, X. Zhao, J. Shao, J. Zhang, and Y. Bai, “The Photoluminescence Mechanism in Carbon Dots (Graphene Quantum Dots, Carbon Nanodots, and Polymer Dots): Current State and Future Perspective,” Nano Research 8 (2015): 355-381.

[93]

M. Je, H. J. Jung, R. Koutavarapu, et al., “Pulsed Laser Irradiation Synthesis of Lead Selenide Quantum Dots From Lead and Selenium Salts in Various Surfactants,”Materials Chemistry and Physics 217 (2018): 427-436.

[94]

Y. P. Sun, B. Zhou, Y. Lin, et al., “Quantum-Sized Carbon Dots for Bright and Colorful Photoluminescence,” Journal of the American Chemical Society 128 (2006): 7756-7757.

[95]

S. Hu, J. Liu, J. Yang, Y. Wang, and S. Cao, “Laser Synthesis and Size Tailor of Carbon Quantum Dots,” Journal of Nanoparticle Research 13 (2011): 7247-7252.

[96]

D. B. Shinde and V. K. Pillai, “Electrochemical Preparation of Luminescent Graphene Quantum Dots From Multiwalled Carbon Nanotubes,” Chemistry - A European Journal 18 (2012): 12522-12528.

[97]

F. Yuan, L. Ding, Y. Li, et al., “Multicolor Fluorescent Graphene Quantum Dots Colorimetrically Responsive to All-pH and a Wide Temperature Range,” Nanoscale 7 (2015): 11727-11733.

[98]

M. He, X. Guo, J. Huang, H. Shen, Q. Zeng, and L. Wang, “Mass Production of Tunable Multicolor Graphene Quantum Dots From an Energy Resource of Coke by a One-Step Electrochemical Exfoliation,” Carbon 140 (2018): 508-520.

[99]

H. Huang, S. Yang, Q. Li, et al., “Electrochemical Cutting in Weak Aqueous Electrolytes: The Strategy for Efficient and Controllable Preparation of Graphene Quantum Dots,” Langmuir 34, no. 1 (2017): 250-258.

[100]

J. Zhou, C. Booker, R. Li, et al., “An Electrochemical Avenue to Blue Luminescent Nanocrystals From Multiwalled Carbon Nanotubes (MWCNTs),” Journal of the American Chemical Society 129 (2007): 744-745.

[101]

L. Zheng, Y. Chi, Y. Dong, J. Lin, and B. Wang, “Electrochemiluminescence of Water-Soluble Carbon Nanocrystals Released Electrochemically From Graphite,” Journal of the American Chemical Society 131 (2009): 4564-4565.

[102]

X. Li, X. Liu, Y. Su, T. Jiang, D. Li, and X. Ma, “Green Synthesis of Carbon Quantum Dots From Wasted Enzymatic Hydrolysis Lignin Catalyzed by Organic Acids for UV Shielding and Antioxidant Fluorescent Flexible Film,” Industrial Crops and Products 188 (2022): 115568.

[103]

L. Zhu, D. Shen, and K. H. Luo, “Triple-Emission Nitrogen and Boron Co-Doped Carbon Quantum Dots From Lignin: Highly Fluorescent Sensing Platform for Detection of Hexavalent Chromium Ions,” Journal of Colloid and Interface Science 617 (2022): 557-567.

[104]

H. Nawaz, X. Zhang, S. Chen, et al., “Recent Developments in Lignin-Based Fluorescent Materials,” International Journal of Biological Macromolecules 258 (2024): 128737.

[105]

Y. Shi, X. Liu, M. Wang, et al., “Synthesis of N-Doped Carbon Quantum Dots From Bio-Waste Lignin for Selective Irons Detection and Cellular Imaging,” International Journal of Biological Macromolecules 128 (2019): 537-545.

[106]

X. Cui, Z. Zhang, Y. Yang, S. Li, and C.-S. Lee, “Organic Radical Materials in Biomedical Applications: State of the Art and Perspectives,” Exploration 2 (2022): 20210264.

[107]

Y. Du, Y. Huo, Q. Yang, et al., “Ultrasmall Iron-Gallic Acid Coordination Polymer Nanodots With Antioxidative Neuroprotection for PET/MR Imaging-Guided Ischemia Stroke Therapy,” Exploration 3 (2023): 20220041.

[108]

V. N. Mehta, S. Jha, H. Basu, R. K. Singhal, and S. K. Kailasa, “One-Step Hydrothermal Approach to Fabricate Carbon Dots From Apple Juice for Imaging of Mycobacterium and Fungal Cells,” Sensors and Actuators B: Chemical 213 (2015): 434-443.

[109]

B. Zhi, Y. Cui, S. Wang, et al., “Malic Acid Carbon Dots: From Super-resolution Live-Cell Imaging to Highly Efficient Separation,” ACS Nano 12 (2018): 5741-5752.

[110]

S. T. Yang, X. Wang, H. Wang, et al., “Carbon Dots as Nontoxic and High-Performance Fluorescence Imaging Agents,” Journal of Physical Chemistry C 113 (2009): 18110-18114.

[111]

J. Zhou, Z. Sheng, H. Han, M. Zou, and C. Li, “Facile Synthesis of Fluorescent Carbon Dots Using Watermelon Peel as a Carbon Source,” Materials Letters 66 (2012): 222-224.

[112]

K. Jiang, S. Sun, L. Zhang, et al., “Red, Green, and Blue Luminescence by Carbon Dots: Full-Color Emission Tuning and Multicolor Cellular Imaging,” Angewandte Chemie International Edition 54 (2015): 5360-5363.

[113]

D. Wei, S. Lv, J. Zuo, S. Zhang, and S. Liang, “Recent Advances Research and Application of Lignin-Based Fluorescent Probes,” Reactive & Functional Polymers 178 (2022): 105354.

[114]

X. Hou, J. Xu, P. Zhou, et al., “Engineered Full-Color-Emissive Lignin Carbon Dots Enable Selectively Fluorescent Sensing of Metal Ions,” Industrial Crops and Products 192 (2023): 116116.

[115]

A. A. Myint, W. K. Rhim, J.-M. Nam, J. Kim, and Y. W. Lee, “Water-soluble, Lignin-Derived Carbon Dots With High Fluorescent Emissions and Their Applications in Bioimaging,” Journal of Industrial and Engineering Chemistry 66 (2018): 387-395.

[116]

L. Zhu, D. Shen, Q. Liu, C. Wu, and S. Gu, “Sustainable Synthesis of Bright Green Fluorescent Carbon Quantum Dots From Lignin for Highly Sensitive Detection of Fe3+ Ions,” Applied Surface Science 565 (2021): 150526.

[117]

R. Wang, G. Xia, W. Zhong, et al., “Direct Transformation of Lignin Into Fluorescence-Switchable Graphene Quantum Dots and Their Application in Ultrasensitive Profiling of a Physiological Oxidant,” Green Chemistry 21 (2019): 3343-3352.

[118]

P. Zhang, W. Li, X. Zhai, C. Liu, L. Dai, and W. Liu, “A Facile and Versatile Approach to Biocompatible “Fluorescent Polymers” From Polymerizable Carbon Nanodots,” Chemical Communications 48 (2012): 10431.

[119]

R. Atchudan, T. N. J. I. Edison, K. R. Aseer, S. Perumal, N. Karthik, and Y. R. Lee, “Highly Fluorescent Nitrogen-Doped Carbon Dots Derived From Phyllanthus Acidus Utilized as a Fluorescent Probe for Label-Free Selective Detection of Fe3+ Ions, Live Cell Imaging and Fluorescent Ink,” Biosensors & Bioelectronics 99 (2018): 303-311.

[120]

X. Miao, D. Qu, D. Yang, et al., “Synthesis of Carbon Dots With Multiple Color Emission by Controlled Graphitization and Surface Functionalization,” Advanced Materials 30 (2018): 1704740.

[121]

Z. Wang, F. Yuan, X. Li, et al., “53% Efficient Red Emissive Carbon Quantum Dots for High Color Rendering and Stable Warm White-Light-Emitting Diodes,” Advanced Materials 29 (2017): 1702910.

[122]

L. Zhu, H. Wu, S. Xie, H. Yang, and D. Shen, “Multicolor Lignin-Derived Carbon Quantum Dots: Controllable Synthesis and Photocatalytic Applications,” Applied Surface Science 662 (2024): 160126.

[123]

L. Zhu, D. Shen, and K. H. Luo, “Lignin-Derived Carbon Quantum Dots-decorated Bi7O9I3 Nanosheets With Enhanced Photocatalytic Performance: Synergism of Electron Transfer Acceleration and Molecular Oxygen Activation,” Applied Surface Science 608 (2023): 155273.

[124]

H. Ma, J. He, Z. Li, et al., “Lignin-Derived Carbon Quantum Dots/Ni-MOL Heterojunction From Red Phosphorus-Assisted Ball Milling Pretreatment and Their Application in Photocatalysis: An Insight From Experiment and DFT Calculation,” Industrial Crops and Products 189 (2022): 115829.

[125]

Z. Jiang, X. Zhang, W. Sun, et al., “Building a Bridge From Papermaking to Solar Fuels,” Angewandte Chemie International Edition 58 (2019): 14850-14854.

[126]

Q. Gao, Z. Yuan, G. Yang, et al., “Enhancement of Lignin-Based Carbon Quantum Dots From Poplar Pre-Hydrolysis Liquor on Photocatalytic CO2 Reduction Via TiO2 Nanosheets,” Industrial Crops and Products 160 (2021): 113161.

[127]

X. Guo, R. Yang, Y. Wang, C. Cheng, D. Fu, and J. Sheng, “Molecularly Designed and Synthesized of Bright Blue Nitrogen-Doped Lignin-Derived Carbon Dots Applied in Printable Anti-Counterfeiting,” International Journal of Biological Macromolecules 253 (2023): 126723.

[128]

L. Zhu, D. Shen, Q. Wang, and K. Luo, “Green Synthesis of Tunable Fluorescent Carbon Quantum Dots From Lignin and Their Application in Anti-Counterfeit Printing,” ACS Appl Mater Interfaces 13 (2021): 56465-56475.

[129]

R. Wang, Z. Guo, Y. Liu, et al., “Concentration-Dependent Emissive Lignin-Derived Graphene Quantum Dots for Bioimaging and Anti-Counterfeiting,” Diamond and Related Materials 117 (2021): 108482.

[130]

S. J. Park, Y. P. Jin, J. W. Chung, H. K. Yang, and S. S. Yi, “Color Tunable Carbon Quantum Dots From Wasted Paper by Different Solvents for Anti-Counterfeiting and Fluorescent Flexible Film,” Chemical Engineering Journal 383 (2019): 123200.

[131]

J. Wang, W. Chen, D. Yang, et al., “Monodispersed Lignin Colloidal Spheres With Tailorable Sizes for Bio-Photonic Materials,” Small 18 (2022): 2200671.

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