A cigarette filter-derived nitrogen-doped carbon nanoparticle coating layer for stable Zn-ion battery anodes

Abstract

Despite the low cost, safety and high theoretical capacity of metallic zinc, zinc anodes face chronic problems, including zinc dendrites, corrosion and side reactions in aqueous zinc-ion batteries (ZIBs). Herein, a nitrogen-doped carbon nanoparticle coating layer derived from discarded cigarette filters is constructed to suppress parasitic side reactions and zinc dendrite growth. The dense coating layer isolates water from the zinc anode, effectively inhibiting side reactions. Furthermore, the special micro-mesoporous structure and sufficient zincophilic groups guarantee uniform Zn stripping/plating. Consequently, durable cycle stability (2400 cycles at a current density of 1 mA cm^-2) with a stable polarization potential is achieved for symmetrical cells. The coating layer derived in this study therefore has the potential to improve the electrochemical performance of ZIBs.

Keywords

Zinc dendrites / nitrogen-doped carbon nanoparticle coating layer / micro-mesoporous structure / zinc affinity

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