Non-fused ring acceptors for organic solar cells

Mingqun Yang , Wenkui Wei , Xia Zhou , Zhiqiang Wang , Chunhui Duan

Energy Materials ›› 2021, Vol. 1 ›› Issue (1) : 100008

PDF
Energy Materials ›› 2021, Vol. 1 ›› Issue (1) :100008 DOI: 10.20517/energymater.2021.08
Review

Non-fused ring acceptors for organic solar cells

Author information +
History +
PDF

Abstract

Organic solar cells (OSCs) have experienced rapid development and achieved significant breakthroughs in power conversion efficiencies owing to the emergence of non-fullerene acceptors (NFAs) with ladder-type multiple fused ring structures. However, the high synthetic complexity and production cost of multiple fused ring NFAs hinder the commercial prospects of OSCs. In this context, the development of non-fused ring acceptors (NFRAs) with simple structures and facile synthesis has been proposed. In this mini review, we summarize the important progress in this field spanning from molecular design strategies to structure-performance relationships. Ultimately, with the aim of realizing the practical application of NFRAs in OSCs, we discuss the current challenges and future directions in terms of achieving high performance and low synthetic complexity simultaneously. These discussions provide valuable insights into the development of new NFRAs.

Keywords

Organic solar cells / non-fullerene acceptors / non-fused ring acceptors / low cost / device performance

Cite this article

Download citation ▾
Mingqun Yang, Wenkui Wei, Xia Zhou, Zhiqiang Wang, Chunhui Duan. Non-fused ring acceptors for organic solar cells. Energy Materials, 2021, 1(1): 100008 DOI:10.20517/energymater.2021.08

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Yu G,Hummelen JC,Heeger AJ.Polymer photovoltaic cells: enhanced efficiencies via a network of internal donor-acceptor heterojunctions.Science1995;270:270-91

[2]

Inganäs O.Organic photovoltaics over three decades.Adv Mater2018;30:e1800388

[3]

Hou J,Friend RH.Organic solar cells based on non-fullerene acceptors.Nat Mater2018;17:119-28

[4]

Brus VV,Luginbuhl BR,Bazan GC.Solution-processed semitransparent organic photovoltaics: from molecular design to device performance.Adv Mater2019;31:e1900904

[5]

Fukuda K,Someya T.The future of flexible organic solar cells.Adv Energy Mater2020;10:2000765

[6]

Zhang Y,Ding L.Indoor organic photovoltaics.Science Bulletin2020;65:2040-2

[7]

Lu L,Wu Q,Zhao D.Recent advances in bulk heterojunction polymer solar cells.Chem Rev2015;115:12666-731

[8]

Yue Q,Zhu X.n-Type molecular photovoltaic materials: design strategies and device applications.J Am Chem Soc2020;142:11613-28

[9]

Lai Y,Hsu C.Applications of functional fullerene materials in polymer solar cells.Energy Environ Sci2014;7:1866

[10]

Kumari T,Kang S,Yang C.Ternary solar cells with a mixed face-on and edge-on orientation enable an unprecedented efficiency of 12.1%.Energy Environ Sci2017;10:258-65

[11]

Lin Y,Zhang ZG.An electron acceptor challenging fullerenes for efficient polymer solar cells.Adv Mater2015;27:1170-4

[12]

Wang J.Fused-ring electron acceptors for photovoltaics and beyond.Acc Chem Res2021;54:132-43

[13]

Zhang J,Guo X,Yan H.Material insights and challenges for non-fullerene organic solar cells based on small molecular acceptors.Nat Energy2018;3:720-31

[14]

Cheng P,Zhan X.Next-generation organic photovoltaics based on non-fullerene acceptors.Nature Photon2018;12:131-42

[15]

Yao H,Yu R,Zhang H.Design, synthesis, and photovoltaic characterization of a small molecular acceptor with an ultra-narrow band gap.Angew Chem Int Ed Engl2017;56:3045-9

[16]

Shi X,Gao K.Terthieno[3,2-b]thiophene (6T) based low bandgap fused-ring electron acceptor for highly efficient solar cells with a high short-circuit current density and low open-circuit voltage loss.Adv Energy Mater2018;8:1702831

[17]

Yan C,Wang Z.Non-fullerene acceptors for organic solar cells.Nat Rev Mater2018;3:18003

[18]

Tang C,Wang JY.High-performance ladder-type heteroheptacene-based nonfullerene acceptors enabled by asymmetric cores with enhanced noncovalent intramolecular interactions.Angew Chem Int Ed Engl2021;60:19314-23

[19]

Ma Y,Wan S.Efficient organic solar cells from molecular orientation control of m-series acceptors.Joule2021;5:197-209

[20]

Yuan J,Zhou L.Single-junction organic solar cell with over 15% efficiency using fused-ring acceptor with electron-deficient core.Joule2019;3:1140-51

[21]

Zhu C,Cai F.Tuning the electron-deficient core of a non-fullerene acceptor to achieve over 17% efficiency in a single-junction organic solar cell.Energy Environ Sci2020;13:2459-66

[22]

Cui Y,Zhang J.Single-junction organic photovoltaic cells with approaching 18% efficiency.Adv Mater2020;32:e1908205

[23]

Liu Q,Jin K.18% efficiency organic solar cells.Science Bulletin2020;65:272-5

[24]

Chen S,Jia T.High-performance polymer solar cells with efficiency over 18% enabled by asymmetric side chain engineering of non-fullerene acceptors.Sci China Chem2021;64:1192-9

[25]

Bi P,Chen Z.Reduced non-radiative charge recombination enables organic photovoltaic cell approaching 19% efficiency.Joule2021;5:2408-19

[26]

Meng H,Deng M,Yu L.18.77 % efficiency organic solar cells promoted by aqueous solution processed cobalt(II) acetate hole transporting layer.Angew Chem Int Ed Engl2021;60:22554-61

[27]

Cui Y,Yao H.Single-junction organic photovoltaic cell with 19% efficiency.Adv Mater2021;33:e2102420

[28]

Li C,Song J.Non-fullerene acceptors with branched side chains and improved molecular packing to exceed 18% efficiency in organic solar cells.Nat Energy2021;6:605-13

[29]

Zhan L,Xia X.Layer-by-layer processed ternary organic photovoltaics with efficiency over 18.Adv Mater2021;33:e2007231

[30]

Qin J,Zuo C.A chlorinated copolymer donor demonstrates a 18.13% power conversion efficiency.J Semicond2021;42:010501

[31]

Jin K,Ding L.D18, an eximious solar polymer!.J Semicond2021;42:010502

[32]

Li X,Xiao Z,Zhang B.Dithieno[3',2':3,4;2'',3'':5,6]benzo[1,2-c][1,2,5]oxadiazole-based polymer donors with deep HOMO levels.J Semicond2021;42:060501

[33]

Meng X,Xiao Z.Side chain engineering on D18 polymers yields 18.74% power conversion efficiency.J Semicond2021;42:100501

[34]

Wang J,Zu Y.A tandem organic photovoltaic cell with 19.6% efficiency enabled by light distribution control.Adv Mater2021;33:e2102787

[35]

Wang H,Yu J.Molecular engineering of central fused-ring cores of non-fullerene acceptors for high-efficiency organic solar cells.J Mater Chem A2019;7:4313-33

[36]

Duan C.The new era for organic solar cells: non-fullerene small molecular acceptors.Science Bulletin2020;65:1231-3

[37]

Dey S.Recent progress in molecular design of fused ring electron acceptors for organic solar cells.Small2019;15:e1900134

[38]

Xu YX,Yip HL.Improved charge transport and absorption coefficient in indacenodithieno[3,2-b]thiophene-based ladder-type polymer leading to highly efficient polymer solar cells.Adv Mater2012;24:6356-61

[39]

Shen F,Li X.Nonfullerene small-molecule acceptors with perpendicular side-chains for fullerene-free solar cells.J Mater Chem A2018;6:15433-55

[40]

Yang X.Organic semiconductors: commercialization and market.J Semicond2021;42:090201

[41]

Osedach TP,Bulović V.Effect of synthetic accessibility on the commercial viability of organic photovoltaics.Energy Environ Sci2013;6:711

[42]

Li N,Brabec CJ.Analyzing the efficiency, stability and cost potential for fullerene-free organic photovoltaics in one figure of merit.Energy Environ Sci2013;11:1355-61

[43]

Yang W,Wang Y.Balancing the efficiency, stability, and cost potential for organic solar cells via a new figure of merit.Joule2021;5:1209-30

[44]

Li X,Sun C.Simplified synthetic routes for low cost and high photovoltaic performance n-type organic semiconductor acceptors.Nat Commun2019;10:519 PMCID:PMC6355909

[45]

Li S,Liu F.An unfused-core-based nonfullerene acceptor enables high-efficiency organic solar cells with excellent morphological stability at high temperatures.Adv Mater2018;30:1705208

[46]

Peng W,Shao L.Simple-structured small molecule acceptors constructed by a weakly electron-deficient thiazolothiazole core for high-efficiency non-fullerene organic solar cells.J Mater Chem A2018;6:24267-76

[47]

Wang K,Duan T.Simple near-infrared nonfullerene acceptors enable organic solar cells with >9% efficiency.ACS Appl Mater Interfaces2019;11:6717-23

[48]

Huang H,Feng S.Noncovalently fused-ring electron acceptors with near-infrared absorption for high-performance organic solar cells.Nat Commun2019;10:3038 PMCID:PMC6620284

[49]

Chen YN,Wang Y.A fully non-fused ring acceptor with planar backbone and near-IR absorption for high performance polymer solar cells.Angew Chem Int Ed Engl2020;59:22714-20

[50]

Pang S,Zhang S.Nonfused nonfullerene acceptors with an A-D-A'-D-A framework and a benzothiadiazole core for high-performance organic solar cells.ACS Appl Mater Interfaces2020;12:16531-40

[51]

Liu Y,Feng S.Exploiting noncovalently conformational locking as a design strategy for high performance fused-ring electron acceptor used in polymer solar cells.J Am Chem Soc2017;139:3356-9

[52]

Fei Z,Jiao X.An alkylated indacenodithieno[3,2-b]thiophene-based nonfullerene acceptor with high crystallinity exhibiting single junction solar cell efficiencies greater than 13% with low voltage losses.Adv Mater2018;30:1705209

[53]

Yao H,Qin Y.Design and synthesis of a low bandgap small molecule acceptor for efficient polymer solar cells.Adv Mater2016;28:8283-7

[54]

Huang C,Gao K.Highly efficient organic solar cells based on S,N-heteroacene non-fullerene acceptors.Chem Mater2018;30:5429-34

[55]

Huang H,Facchetti A.Organic and polymeric semiconductors enhanced by noncovalent conformational locks.Chem Rev2017;117:10291-318

[56]

Zhang Z,Yin X.Conformation locking on fused-ring electron acceptor for high-performance nonfullerene organic solar cells.Adv Funct Mater2018;28:1705095

[57]

Feng S,Tang N.Regulating the packing of non-fullerene acceptors via multiple noncovalent interactions for enhancing the performance of organic solar cells.ACS Appl Mater Interfaces2020;12:4638-48

[58]

Wang Y,Cui X.Small molecule acceptors with a ladder-like core for high-performance organic solar cells with low non-radiative energy losses.J Mater Chem A2020;8:12495-501

[59]

Ma L,Zhu J.Completely non-fused electron acceptor with 3D-interpenetrated crystalline structure enables efficient and stable organic solar cell.Nat Commun2021;12:5093 PMCID:PMC8384863

[60]

Li S,Zhao W.Revealing the effects of molecular packing on the performances of polymer solar cells based on A-D-C-D-A type non-fullerene acceptors.J Mater Chem A2018;6:12132-41

[61]

Zhao J,Yu L,Li Y.Highly efficient non-fused-ring electron acceptors enabled by the conformational lock and structural isomerization effects.ACS Appl Mater Interfaces2021;13:25214-23

[62]

Zhang X,Yu J.High-performance noncovalently fused-ring electron acceptors for organic solar cells enabled by noncovalent intramolecular interactions and end-group engineering.Angew Chem Int Ed Engl2021;60:12475-81

[63]

Hou R,Ma X.Noncovalently fused-ring electron acceptors with C2v symmetry for regulating the morphology of organic solar cells.ACS Appl Mater Interfaces2020;12:46220-30

[64]

Yi Y,Zheng N.Small molecule acceptors with a nonfused architecture for high-performance organic photovoltaics.Chem Mater2019;31:904-11

[65]

Lee J,Lee H.Side-chain engineering of nonfullerene acceptors for near-infrared organic photodetectors and photovoltaics.ACS Energy Lett2019;4:1401-9

[66]

Wang X,Zhou J.High-performance simple nonfused ring electron acceptors with diphenylamino flanking groups.ACS Appl Mater Interfaces2021;13:39652-9

[67]

Yu H,Li X.Modulating energy level on an A-D-A′-D-A-type unfused acceptor by a benzothiadiazole core enables organic solar cells with simple procedure and high performance.Sol RRL2020;4:2000421

[68]

Liu X,Zhang X,Wei Z.An A-D-A′-D-A type unfused nonfullerene acceptor for organic solar cells with approaching 14% efficiency.Sci China Chem2021;64:228-31

[69]

Zhang X,Qin L.Side-chain engineering for enhancing the molecular rigidity and photovoltaic performance of noncovalently fused-ring electron acceptors.Angew Chem Int Ed Engl2021;60:17720-5

[70]

Huang J,Fan X,Yang L.A-D-C-D-A type non-fullerene acceptors based on the benzotriazole (BTA) unfused core for organic solar cells.New J Chem2021;45:12802-7

[71]

Li Y,Wu Z.Regulating the aggregation of unfused non-fullerene acceptors via molecular engineering towards efficient polymer solar cells.ChemSusChem2021;14:3579-89

[72]

Luo D,Zheng N.High-performance and low-energy loss organic solar cells with non-fused ring acceptor by alkyl chain engineering.Chemical Engineering Journal2021;420:129768

[73]

Li S,Lau T.Near-infrared nonfullerene acceptors based on benzobis(thiazole) unit for efficient organic solar cells with low energy loss.Small Methods2019;3:1900531

[74]

Ye S,Li S.Synergistic effects of chlorination and branched alkyl side chain on the photovoltaic properties of simple non-fullerene acceptors with quinoxaline as the core.ChemSusChem2021;14:3599-606

[75]

Geng S,Gao J.Non-fullerene acceptors with a thieno[3,4-c]pyrrole-4,6-dione (TPD) core for efficient organic solar cells.Chin J Polym Sci2019;37:1005-14

[76]

Miao J,Liu J.An A-D-A'-D-A type small molecule acceptor with a broad absorption spectrum for organic solar cells.Chem Commun (Camb)2018;54:303-6

[77]

Lv R,Li S.Influences of quinoid structures on stability and photovoltaic performance of nonfullerene acceptors.Sol RRL2020;4:2000286

[78]

Gao H,Cai Y.Achieving both enhanced voltage and current through fine-tuning molecular backbone and morphology control in organic solar cells.Adv Energy Mater2019;9:1901024

[79]

Zhang X,Feng H.Side chain engineering investigation of non-fullerene acceptors for photovoltaic device with efficiency over 15%.Sci China Chem2020;63:1799-806

[80]

Qian D,Zhang M.Design, application, and morphology study of a new photovoltaic polymer with strong aggregation in solution state.Macromolecules2012;45:9611-7

[81]

Zhang M,Ma W,Hou J.A large-bandgap conjugated polymer for versatile photovoltaic applications with high performance.Adv Mater2015;27:4655-60

[82]

Wu Z,Zhang L.A ligand-free direct heteroarylation approach for benzodithiophenedione-based simple small molecular acceptors toward high efficiency polymer solar cells.J Mater Chem A2021;9:3314-21

[83]

Yu ZP,Chen FX.Simple non-fused electron acceptors for efficient and stable organic solar cells.Nat Commun2019;10:2152 PMCID:PMC6517432

[84]

Liu ZX,Shen Z.Molecular insights of exceptionally photostable electron acceptors for organic photovoltaics.Nat Commun2021;12:3049 PMCID:PMC8144627

[85]

Wen TJ,Chen Z.Simple non-fused electron acceptors leading to efficient organic photovoltaics.Angew Chem Int Ed Engl2021;60:12964-70

[86]

Bao S,Fan H.Volatilizable solid additive-assisted treatment enables organic solar cells with efficiency over 18.8% and fill factor exceeding 80%.Adv Mater2021;

[87]

Hong L,Wu Z.Eco-compatible solvent-processed organic photovoltaic cells with over 16% efficiency.Adv Mater2019;31:e1903441

[88]

Zhou Y,Lu H.High-efficiency organic solar cells based on a low-cost fully non-fused electron acceptor.Adv Funct Mater2021;31:2101742

PDF

136

Accesses

0

Citation

Detail

Sections
Recommended

/