Cu-KFI zeolite with 8-membered rings has been recognized as a highly promising catalyst for the ammonia selective catalytic reduction (NH3-SCR), but the Al-rich feature for this zeolite strongly influences its hydrothermal stability. One of the effective strategies for solving this issue is to introduce rare earth elements in the zeolite. Herein, we showed an efficient synthesis of LaCe-KFI zeolite from a spent fluid catalytic cracking (FCC) catalyst containing La and Ce species as the raw material under solvent-free conditions. Interestingly, the introduction of rare-earth elements in KFI zeolite could maintain the stability of active copper species and zeolite framework under hydrothermal aging conditions at 800 °C for 12 h, resulting in excellent hydrothermal stability and superior catalytic performance in NH3-SCR reaction. This novel method for zeolite production not only boosts catalytic efficiency but also facilitates the sustainable recycling of industrial solid waste, in good agreement with the tenets of green chemistry.
| [1] |
Mohan S, Dinesha P, Kumar SChem. Eng. J., 2020, 384: 123253
|
| [2] |
Song J, Wang Y, Walter E D, Washton N M, Mei D, Kovarik L, Engelhard M H, Prodinger S, Wang Y, Peden C H F, Gao FACS Catal., 2017, 7: 8214
|
| [3] |
Li J, Chang H, Ma L, Hao J, Yang R TCatal. Today, 2011, 175: 147
|
| [4] |
Shi Z, Peng Q, E J, Xie B, Wei J, Yin R, Fu GFuel, 2023, 331: 125885
|
| [5] |
Chen L, Janssens T V W, Vennestrøm P N R, Jansson J, Skoglundh M, Grönbeck HACS Catal., 2020, 10: 5646
|
| [6] |
Paolucci C, Parekh A A, Khurana I, Di Iorio J R, Li H, Caballero J D A, Shih A J, Anggara T, Delgass W N, Miller J T, Ribeiro F H, Gounder R, Schneider W FJ. Am. Chem. Soc., 2016, 138: 6028
|
| [7] |
Lee H, Kim J, Song I, Jeon S W, Cho S J, Kim D HCatal. Sci. Technol., 2022, 12: 7470
|
| [8] |
Su X, Wang Y, Bu L, Zhang X, Li Y, Sang J, Ren G, Wen MChem. Res. Chinese Universities, 2025, 41: 919
|
| [9] |
Dusselier M, Davis M EChem. Rev., 2018, 118: 5265
|
| [10] |
Hu C, Fu W, Yuan Z, Liu C, Wang Z, Yang WChem. Res. Chinese Universities, 2025, 41: 113
|
| [11] |
Zhang L, Wu Q, Meng X, Müller U, Feyen M, Dai D, Maurer S, McGuire R, Moini A, Parvulescu A-N, Zhang W, Shi C, Yokoi T, Pan X, Bao X, Gies H, Marler B, De Vos D E, Kolb U, Xiao F-SReact. Chem. Eng., 2019, 4: 975
|
| [12] |
Liu P, Wu Q, Chen Z, Xiao F-SChem. Res. Chinese Universities, 2024, 40: 646
|
| [13] |
Liu Z, Fu Y, Shan Y, Zhang T, Wang Y, Du J, Sun Y, He G, Shi X, Yu Y, He HACS Catal., 2024, 14: 1678
|
| [14] |
Garces L J, Hincapie B, Shen X, Makwana V D, Corbin D R, Sacco A, Suib S LMicro. Meso. Mater., 2014, 198: 9
|
| [15] |
Lozinska M M, Bruce E L, Mattock J, Chitac R G, Cox P A, Turrina A, Wright P AChem. Eur. J., 2022, 28: e202201689
|
| [16] |
Kim J, Cho S J, Kim D HACS Catal., 2017, 7: 6070
|
| [17] |
Han S, Tang X, Wang L, Ma Y, Chen W, Wu Q, Zhang L, Zhu Q, Meng X, Zheng A, Xiao F-SAppl. Catal. B: Environ., 2021, 281: 119480
|
| [18] |
Yu R, Kong H, Zhao Z, Shi C, Meng X, Xiao F-S, De Baerdemaeker T, Parvulescu A-N, Müller U, Zhang WChemCatChem, 2022, 14: e202200228
|
| [19] |
Zhao Z, Yu R, Shi C, Gies H, Xiao F-S, De Vos D, Yokoi T, Bao X, Kolb U, McGuire R, Parvulescu A-N, Maurer S, Müller U, Zhang WCatal. Sci. Technol., 2019, 9: 241
|
| [20] |
Usui T, Liu Z, Ibe S, Zhu J, Anand C, Igarashi H, Onaya N, Sasaki Y, Shiramata Y, Kusamoto T, Wakihara TACS Catal., 2018, 8: 9165
|
| [21] |
Fan J, Ning P, Wang Y, Song Z, Liu X, Wang H, Wang J, Wang L, Zhang QChem. Eng. J., 2019, 369: 908
|
| [22] |
Wang Y, Li G-G, Zhang S-Q, Zhang X-Y, Zhang X, Hao Z-PChem. Eng. J., 2020, 393: 124782
|
| [23] |
Bian C, Luo X, Chen X, Liu R, Li J, Zhu G, Xu H, Han S, Zhu J, Zhu LInorg. Chem., 2024, 63: 10798
|
| [24] |
Sun M, Nie X, Zhang X, Liu S, Song C, Guo XChem. Bio. Eng., 2024, 1: 231
|
| [25] |
Xiao Y, Wang Y, Wang C, Fang W, Liu P, Hui Y, Li H, Zhou H, Xiao F-SChem. Bio. Eng., 2025, 2: 485
|
| [26] |
Cai B, Liu J, An Z, Wang Y, Du Y, Yin CMicro. Meso. Mater., 2025, 394: 113684
|
| [27] |
Jin Y, Sun Q, Qi G, Yang C, Xu J, Chen F, Meng X, Deng F, Xiao F-SAngew. Chem. Int. Ed., 2013, 52: 9172
|
| [28] |
Wang X, Wu Q, Chen C, Pan S, Zhang W, Meng X, Maurer S, Feyen M, Müller U, Xiao F-SChem. Commun., 2015, 51: 16920
|
| [29] |
Jin Y, Chen X, Sun Q, Sheng N, Liu Y, Bian C, Chen F, Meng X, Xiao F-SChem. Eur. J., 2014, 20: 17616
|
| [30] |
Chatelain T, Patarin J, Farré R, Pétigny O, Schulz PZeolites, 1996, 17: 328
|
| [31] |
Liu Q, Pham T, Porosoff M D, Lobo R FChemSusChem, 2012, 5: 2237
|
| [32] |
Chen Z, Fan C, Pang L, Ming S, Guo W, Liu P, Chen H, Li TChem. Eng. J., 2018, 348: 608
|
| [33] |
Fan C, Chen Z, Pang L, Ming S, Zhang X, Albert K B, Liu P, Chen H, Li TAppl. Catal. A: Gen., 2018, 550: 256
|
| [34] |
Han M, Jiao Y, Zhou C, Guo Y, Guo Y, Lu G, Wang L, Zhan WRare Met., 2019, 38: 210
|
| [35] |
Wang H, Xu R, Jin Y, Zhang RCatal. Today, 2019, 327: 295
|
| [36] |
Li R, Wang P, Ma S, Yuan F, Li Z, Zhu YChem. Eng. J., 2020, 379: 122376
|
| [37] |
Sultana A, Fujitani T, Iki NClean. Mater., 2022, 4: 100096
|
| [38] |
Gao F, Walter E D, Karp E M, Luo J, Tonkyn R G, Kwak J H, Szanyi J, Peden C H FJ. Catal., 2013, 300: 20
|
| [39] |
Kim Y J, Lee J K, Min K M, Hong S B, Nam I-S, Cho B KJ. Catal., 2014, 311: 447
|
| [40] |
Albert K B, Fan C, Pang L, Chen Z, Ming S, Albert T, Li TAppl. Surf. Sci., 2019, 479: 1200
|
| [41] |
Zhou C, Zhang H, Yang L, Wu D, He S, Yang H, Xiong HFuel, 2022, 309: 122178
|
| [42] |
Cao Y, Zou S, Lan L, Yang Z, Xu H, Lin T, Gong M, Chen YJ. Mol. Catal. A: Chem., 2015, 398: 304
|
| [43] |
Quindimil A, De-La-Torre U, Pereda-Ayo B, González-Marcos J A, González-Velasco J RAppl. Catal. B: Environ., 2018, 238: 393
|
| [44] |
Shi W, Fu Y, Jiang W, Ye Y, Kang J, Liu D, Ren Y, Li D, Luo C, Xu ZChem. Eng. J., 2019, 357: 33
|
| [45] |
Xiao H, Du J, Shen T, Hu Y, Zhang Y, Yan Z, Shan Y, Shan W, Yan Y, Yu Y, He HAppl. Catal. B: Environ., 2026, 384: 126218
|
| [46] |
Li G, Deng Z, Zhang Y, Li X, Li L, Liu W, Ji J, Huang S, Huang T, Peng HAppl. Catal. B: Environ., 2025, 378: 125647
|
| [47] |
Guo X, Ding Z, Kang N, Yang L, Wang Y, Zhang C, Li Z, Zhang T, Wang Y, Wang Y, Qu HFuel, 2024, 361: 130694
|
| [48] |
Zang Y, Bi Y, Liu C, Zhang Y, Li Q, Wang Y, Zhang M, Liu Q, Zhang ZFuel, 2023, 340: 127442
|
| [49] |
Li Q, Zang Y, Wang Y, Liu C, Liu Q, Han R, Zhang ZFuel, 2024, 371: 131892
|
| [50] |
Miao B, Wang X, Chu Q, Mao Y, Li QChem. Eng. J., 2025, 525: 169881
|
| [51] |
Chen Z, Cui J, Zeng H, Zhou C, Qu H, Zhong QJ. Environ. Chem. Eng., 2026, 14: 120876
|
| [52] |
Chen L, Ren S, Liu L, Su B, Yang J, Chen Z, Wang M, Liu QJ. Environ. Chem. Eng., 2022, 10: 107167
|
RIGHTS & PERMISSIONS
Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH
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