Catalyst Development and Design in Propane Dehydrogenation

Abstract

Light-alkane direct dehydrogenation reaction, which has received wide attention in recent years, is an important industrial technology for the petrochemical fields. There are great progresses and developments on the Pt- and/or non-noble metal-based heterogeneous catalysts for selectively activating the C—H bond with the purpose of high alkene productivity. However, the coke formation and sintering of the metal would cause the catalyst deactivation. Thus, it is still a challenge to achieve catalysts with high catalytic performance and stability. This review describes recent advances in the strategies for promoting the metal dispersion and tuning the metal electron structures: (1) introduction of promoters; (2) synthesizing the highly active single-atom sites; (3) alteration of the support properties and encapsulation of subnanometer-sized clusters into the microporous zeolites. In addition, the elimination of coke on the support can be realized by decreasing the acid sites and co-feeding other gas flows. The alternative catalysts, such as non-noble metals and metal oxides, are also summarized. The active sites, reaction pathways and deactivation mechanism over various catalysts are also discussed, which is expected to help the efficient catalyst design for high selectivity to propene products. The challenges and perspectives of catalysts on light-alkane dehydrogenation are proposed for further development.

Keywords

Light-alkane direct dehydrogenation / Pt-based catalyst / Non-noble metal-based catalyst / Coke deposition

References

[1] Sattler J J H B, Ruiz-Martinez J, Santillan-Jimenez E, Weckhuysen B M. Chem. Rev., 2014, 114: 10613

[2] Pritchard J, Filonenko G A, van Putten R, Hensen E J M, Pidko E A. Chem. Soc. Rev., 2015, 44: 3808

[3] Rousseau R, Dixon D A, Kay B D, Dohnálek Z. Chem. Soc. Rev., 2014, 43: 7664

[4] Li C, Wang G. Chem. Soc. Rev., 2021, 50: 4359

[5] Wang L, Wang L, Meng X, Xiao F-S. Adv. Mater., 2019, 31: 1901905

[6] Hu Z-P, Han J, Wei Y, Liu Z. ACS Catal., 2022, 12: 5060

[7] Yu W, Porosoff M D, Chen J G. Chem. Rev., 2012, 112: 5780

[8] Kumar M S, Chen D, Walmsley J C, Holmen A. Catal. Commun., 2008, 9: 747

[9] Cybulskis V J, Bukowski B C, Tseng H-T, Gallagher J R, Wu Z, Wegener E, Kropf A J, Ravel B, Ribeiro F H, Greeley J, Miller J T. ACS Catal., 2017, 7: 4173

[10] Song M, Zhang B, Zhai Z, Liu S, Wang L, Liu G. Ind. & Eng. Chem. Res., 2023, 62: 3853

[11] Zhang B, Li G, Zhai Z, Chen D, Tian Y, Yang R, Wang L, Zhang X, Liu G. Aiche J., 2021, 67: e17295

[12] Li X, Zhou Y, Qiao B, Pan X, Wang C, Cao L, Li L, Lin J, Wang X. J. Energy Chem., 2020, 51: 14

[13] Ingale P, Knemeyer K, Preikschas P, Ye M, Geske M, D’Alnoncourt R N, Thomas A, Rosowski F. Catal. Sci. Technol., 2021, 11: 484

[14] Wang W, Shan Y, Song J, Fan X, Yu X, Kong L, Xiao X, Xie Z, Zhao Z. Chem. Res. Chinese Universities, 2025, 46: 20250011

[15] Zhang H, Feng F, Meng F, Wang G, Bing L, Zhang Q, Wang F, Fu H, Han D. J. Porous Mater., 2024, 31: 1257

[16] Li Y, Ma Y, Zhang Q, Kondratenko V A, Jiang G, Sun H, Han S, Wang Y, Cui G, Zhou M, Huan Q, Zhao Z, Xu C, Jiang G, Kondratenko E V. J. Catal., 2023, 418: 290

[17] Deng L, Chen Q, Jiang X, Liu X, Wang Z. Catal. Today, 2023, 410: 175

[18] Liu X, Lang W-Z, Long L-L, Hu C-L, Chu L-F, Guo Y-J. Chem. Eng. J., 2014, 247: 183

[19] Lee M-H, Nagaraja B M, Lee K Y, Jung K-D. Catal. Today, 2014, 232: 53

[20] Fu H, Zhang H, Ma H, Qian W, Ying W. Catal. Lett., 2024, 154: 3867

[21] Dou X, Li W, Zhang K, Hou H, He Z, Zhu C, Meira D M, Lopez-Haro M, Xia Z, He P, Xiao H, Liu L. ACS Catal., 2024, 14: 2859

[22] Hong H, Xu Z, Mei B, Hu W, Fornasiero P, Wang C, Wang T, Yue Y, Li T, Yang C, Cui Q, Zhu H, Bao X. Science, 2025, 388: 497

[23] Nakaya Y, Xing F, Ham H, Shimizu K-I, Furukawa S. Angew. Chem. Int. Ed., 2021, 60: 19715

[24] Liu X, Wang X, Zhen S, Sun G, Pei C, Zhao Z-J, Gong J. Chem. Sci., 2022, 13: 9537

[25] Chen S, Zhao Z-J, Mu R, Chang X, Luo J, Purdy S C, Kropf A J, Sun G, Pei C, Miller J T, Zhou X, Vovk E, Yang Y, Gong J. Chem, 2021, 7: 387

[26] Nakaya Y, Hirayama J, Yamazoe S, Shimizu K-I, Furukawa S. Nat. Commun., 2020, 11: 1

[27] Qi L, Babucci M, Zhang Y, Lund A, Liu L, Li J, Chen Y, Hoffman A S, Bare S R, Han Y, Gates B C, Bell A T. J. Am. Chem. Soc., 2021, 143: 21364

[28] Belskaya O B, Stepanova L N, Gulyaeva T I, Erenburg S B, Trubina S V, Kvashnina K, Nizovskii A I, Kalinkin A V, Zaikovskii V I, Bukhtiyarov V I, Likholobov V A. J. Catal., 2016, 341: 13

[29] Yu C, Ge Q, Xu H, Li W. Appl. Catal. A-Gen., 2006, 315: 58

[30] Luo L, Wang S, Wu Z, Qin Z, Dong M, Wang J, Fan W. Chem. Res. Chinese Universities, 2022, 38: 229

[31] Ma Y, Song S, Liu C, Liu L, Zhang L, Zhao Y, Wang X, Xu H, Guan Y, Jiang J, Song W, Han Y, Zhang J, Wu P. Nat. Catal., 2023, 6: 506

[32] Shen L-L, Xia K, Lang W-Z, Chu L-F, Yan X, Guo Y-J. Chem. Eng. J., 2017, 324: 336

[33] Xia K, Lang W-Z, Li P-P, Long L-L, Yan X, Guo Y-J. Chem. Eng. J., 2016, 284: 1068

[34] Xia K, Lang W-Z, Li P-P, Yan X, Guo Y-J. J. Catal., 2016, 338: 104

[35] Zhang X, Wang Y, Xu Y, Matusse E, Chang S, Sun T, Lu Y, Zhang L. Mol. Catal., 2023, 547: 113287

[36] Xu J, Shi C, Zhang S, Zheng Q, Pan L, Zhang X, Zou J-J. Chin. J. Chem., 2022, 40: 918

[37] Cao L, Qiu Y, Luo S, Jiang C, Jing F. Mol. Catal., 2022, 518: 112081

[38] Natarajan P, Khan H A, Yoon S, Jung K-D. J. Ind. Eng. Chem., 2018, 63: 380

[39] Liu L, Diaz U, Arenal R, Agostini G, Concepcion P, Corma A. Nat. Mater., 2017, 16: 132

[40] Liu L, López-Haro M, Lopes C W, Li C, Concepción P, Simonelli L, Calvino J J, Corma A. Nat. Mater., 2019, 18: 866

[41] Han S W, Park H, Han J, Kim J-C, Lee J, Jo C, Ryoo R. ACS Catal., 2021, 11: 9233

[42] Sun Q, Wang N, Fan Q, Zeng L, Mayoral A, Miao S, Yang R, Jiang Z, Zhou W, Zhang J, Zhang T, Xu J, Zhang P, Cheng J, Yang D-C, Jia R, Li L, Zhang Q, Wang Y, Terasaki O, Yu J. Angew. Chem. Int. Ed., 2020, 59: 19450

[43] Wang N, Sun Q, Bai R, Li X, Guo G, Yu J. J. Am. Chem. Soc., 2016, 138: 7484

[44] Sun Q, Wang N, Yu J. Adv. Mater., 2021, 33: 2104442

[45] Zhang L, Chen X, Ma Y, Song S, Xu H, Guan Y, Song W, Zhang J, Wu P. ACS Catal., 2024, 14: 9431

[46] Wu J, Hua G, Liu J, Zhao Y, Ma H, Wang Y, Wu Z. Mol. Catal., 2025, 588: 115588

[47] Tang S, Liu H, Li T, Wang C, Cui Q, Yue Y, Meng X, Bao X. Chem. Eng. Sci., 2024, 286: 119674

[48] Luo L, Zhou T, Li W, Li X, Yan H, Chen W, Xu Q, Hu S, Ma C, Bao J, Pao C-W, Wang Z, Li H, Ma X, Luo L, Zeng J. Nano Lett., 2024, 24: 7236

[49] Lu J, Xu Z, Yue Y, Bao X, Lin M, Zhu H. Chem. Eng. J., 2024, 484: 149369

[50] Bing L, Sun Z, Zhang S, Chen B, Zhang H, Wang M, Chu C, Han D, Zhang J, Wang F, Wang G. Chem. Eng. J., 2024, 491: 151961

[51] Li S, Li Q, Li B, Chen X, Wu H, Wang S, Dong M, Wang J, Fan W. ACS Catal., 2024, 14: 17825

[52] Chen S, Li X, Qu Z, Li X, Gao Y, Liu P-F, Dong Z-Q, Yu P, Sun Q, Dou S, Liu Z, Sun J. Nat. Commun., 2025, 16: 1

[53] Wu J, Sharada S M, Ho C, Hauser A W, Head-Gordon M, Bell A T. Appl. Catal. A: Gen., 2015, 506: 25

[54] Wang P, Liao H, Yang M, Wu L, Tang Y, Tan L. Fuel, 2023, 354: 129421

[55] Sun P, Siddiqi G, Chi M, Bell A T. J. Catal., 2010, 274: 192

[56] Redekop E A, Galvita V V, Poelman H, Bliznuk V, Detavernier C, Marin G B. ACS Catal., 2014, 4: 1812

[57] Sun P, Siddiqi G, Vining W C, Chi M, Bell A T. J. Catal., 2011, 282: 165

[58] Ryoo R, Kim J, Jo C, Han S W, Kim J-C, Park H, Han J, Shin H S, Shin J W. Nature, 2020, 585: 221

[59] Liu H, Liu Y, Zhang X, Hu P, Zhou J, Wang H, Hu J, Chen S, Ji H. Fuel, 2023, 332: 125858

[60] Zha S, Sun G, Wu T, Zhao J, Zhao Z-J, Gong J. Chemical Science, 2018, 9: 3925

[61] Chang X, Lu Z, Wang X, Zhao Z-J, Gong J. Chem. Sci., 2023, 14: 6414

[62] Gao X, Xu W, Li X, Cen J, Xu Y, Lin L, Yao S. Chem. Eng. J., 2022, 443: 136393

[63] Choi Y S, Kim J-R, Hwang J-H, Roh H-S, Koh H L. Catal. Today, 2023, 411: 113957

[64] Deng L, Miura H, Ohkubo T, Shishido T, Wang Z, Hosokawa S, Teramura K, Tanaka T. Catal. Sci. Technol., 2019, 9: 947

[65] Werghi B, Wu L, Ebrahim A M M, Chi M, Ni H, Cargnello M, Bare S R R. Small, 2023, 19: 2207956

[66] Ma S, Liu Z-P. Nat. Commun., 2022, 13: 1

[67] Tolek W, Suriye K, Praserthdam P, Panpranot J. Catal. Today, 2020, 358: 100

[68] Cai W, Mu R, Zha S, Sun G, Chen S, Zhao Z-J, Li H, Tian H, Tang Y, Tao F, Zeng L, Gong J. Sci. Adv., 2018, 4: eaar5418

[69] Motagamwala A H, Almallahi R, Wortman J, Igenegbai V O, Linic S. Science, 2021, 373: 217

[70] Wegener E C, Wu Z, Tseng H-T, Gallagher J R, Ren Y, Diaz R E, Ribeiro F H, Miller J T. Catal. Today, 2018, 299: 146

[71] Cesar L G, Yang C, Lu Z, Ren Y, Zhang G, Miller J T. ACS Catal., 2019, 9: 5231

[72] Wu Z, Bukowski B C, Li Z, Milligan C, Zhou L, Ma T, Wu Y, Ren Y, Ribeiro F H, Delgass W N, Greeley J, Zhang G, Miller J T. J. Am. Chem. Soc., 2018, 140: 14870

[73] Ma Y, Chen X, Guan Y, Xu H, Zhang J, Jiang J, Chen L, Xue T, Xue Q, Wei F, Wu P. J. Catal., 2021, 397: 44

[74] Wu X, Zhang Q, Chen L, Liu Q, Zhang X, Zhang Q, Ma L, Wang C. Fuel Process. Technol., 2020, 198: 106222

[75] Zhu Y, An Z, Song H, Xiang X, Yang W, He J. ACS Catal., 2017, 7: 6973

[76] Xu Z, Yue Y, Bao X, Xie Z, Zhu H. ACS Catal., 2020, 10: 818

[77] Liu H, Zhou J, Chen T, Hu P, Xiong C, Sun Q, Chen S, Lo T W B, Ji H. ACS Catal., 2023, 13: 2928

[78] Liu L, López-Haro M, Lopes C W, Rojas-Buzo S, Concepción P, Manzorro R, Simonelli L, Sattler A, Serna P, Calvino J J, Corma A. Nat. Catal., 2020, 3: 628

[79] Xia L, Zhang B, Hou G, Wang L, Liu S, Liu G. Aiche J., 2024, 70: e18444

[80] Zhou J, Liu H, Xiong C, Hu P, Wang H, Wang X, Ji H. Chem. Eng. J., 2023, 455: 139794

[81] Zhang B, Li G, Liu S, Qin Y, Song L, Wang L, Zhang X, Liu G. ACS Catal., 2022, 12: 1310

[82] Li B, Xu Z, Chu W, Luo S, Jing F. Chin. J. Catal., 2017, 38: 726

[83] Xie L, Chai Y, Sun L, Dai W, Wu G, Guan N, Li L. J. Energy Chem., 2021, 57: 92

[84] Qi L, Zhang Y, Babucci M, Chen C, Lu P, Li J, Dun C, Hoffman A S, Urban J J, Tsapatsis M, Bare S R, Han Y, Gates B C, Bell A T. ACS Catal., 2022, 12: 11177

[85] Wang P, Liao H, Yang H, Lv Q, Li Y, Wu L, Tang Y, Xie Z, Tan L. Chem. Eng. Sci., 2023, 269: 118450

[86] Zhang Y, Zhou Y, Huang L, Xue M, Zhang S. Ind. & Eng. Chem. Res., 2011, 50: 7896

[87] Zhang Y, Zhou Y, Shi J, Zhou S, Sheng X, Zhang Z, Xiang S. J. Mol. Catal. A: Chem., 2014, 381: 138

[88] Sun Q, Wang N, Fan Q, Zeng L, Mayoral A, Miao S, Yang R, Jiang Z, Zhou W, Zhang J, Zhang T, Xu J, Zhang P, Cheng J, Yang D-C, Jia R, Li L, Zhang Q, Wang Y, Terasaki O, Yu J. Angew. Chem. Int. Ed., 2020, 59: 19450

[89] Searles K, Chan K W, Mendes Burak J A, Zemlyanov D, Safonova O, Copéret C. J. Am. Chem. Soc., 2018, 140: 11674

[90] Sun G, Zhao Z-J, Mu R, Zha S, Li L, Chen S, Zang K, Luo J, Li Z, Purdy S C, Kropf A J, Miller J T, Zeng L, Gong J. Nat. Commun., 2018, 9: 1

[91] Ren G-Q, Pei G-X, Ren Y-J, Liu K-P, Chen Z-Q, Yang J-Y, Su Y, Liu X-Y, Li W-Z, Zhang T. J. Catal., 2018, 366: 115

[92] Xiong H, Lin S, Goetze J, Pletcher P, Guo H, Kovarik L, Artyushkova K, Weckhuysen B M, Datye A K. Angew. Chem. Int. Ed., 2017, 56: 8986

[93] Filez M, Redekop E A, Poelman H, Galvita V V, Ramachandran R K, Dendooven J, Detavernier C, Marin G B. Chem. Mater., 2014, 26: 5936

[94] Yu Q, Yu T, Chen H, Fang G, Pan X, Bao X. J. Energy Chem., 2020, 41: 93

[95] Liu G, Zeng L, Zhao Z-J, Tian H, Wu T, Gong J. ACS Catal., 2016, 6: 2158

[96] Cesar L G, Yang C, Lu Z, Ren Y, Zhang G, Miller J T. ACS Catal., 2019, 9: 5231

[97] Li J, Li J, Zhao Z, Fan X, Liu J, Wei Y, Duan A, Xie Z, Liu Q. J. Catal., 2017, 352: 361

[98] Shi L, Deng G-M, Li W-C, Miao S, Wang Q-N, Zhang W-P, Lu A-H. Angew. Chem., Int. Ed., 2015, 54: 13994

[99] Rochlitz L, Pessemesse Q, Fischer J W A, Klose D, Clark A H, Plodinec M, Jeschke G, Payard P-A, Coperet C. J. Am. Chem. Soc., 2022, 144: 13384

[100] Larsson M, Hultén M, Blekkan E A, Andersson B. J. Catal., 1996, 164: 44

[101] Li Q, Sui Z, Zhou X, Zhu Y, Zhou J, Chen D. Top. Catal., 2011, 54: 888

[102] Galvita V, Siddiqi G, Sun P, Bell A T. J. Catal., 2010, 271: 209

[103] Hauser A W, Gomes J, Bajdich M, Head-Gordon M, Bell A T. PCCP, 2013, 15: 20727

[104] Sattler J J H B, Beale A M, Weckhuysen B M. PCCP, 2013, 15: 12095

[105] Shan Y-L, Zhu Y-A, Sui Z-J, Chen D, Zhou X-G. Catal. Sci. Technol., 2015, 5: 3991

[106] Zhang Y, Chen M, Wang W, Zhang Y. Catal. Sci. Technol., 2024, 14: 3924

[107] Bian K, Zhang G, Zhu J, Wang X, Wang M, Lou F, Liu Y, Song C, Guo X. ACS Catal., 2022, 12: 6559

[108] Zhang Y, Aly M. Appl. Catal. A-Gen., 2022, 643: 118795

[109] Rogg S, Hess C. J. CO2 Util., 2021, 50: 101604

[110] Jang E J, Lee J, Jeong H Y, Kwak J H. Appl. Catal. A-Gen., 2019, 572: 1

[111] Ponomaryov A B, Smirnov A V, Pisarenko E V, Shostakovsky M V. Appl. Catal. A-Gen., 2024, 673: 119588

[112] Bai L, Zhou Y, Zhang Y, Liu H, Sheng X. Ind. & Eng. Chem. Res., 2009, 48: 9885

[113] Jablonski E L, Castro A A, Scelza O A, de Miguel S R. Appl. Catal. A-Gen., 1999, 183: 189

[114] Kogan S B, Herskowitz M. Catal. Commun., 2001, 2: 179

[115] Llorca J, Homs N, León J, Sales J, Fierro J L G, Ramirez de la Piscina P. Appl. Catal. A-Gen., 1999, 189: 77

[116] Bariås O A, Holmen A, Blekkan E A. Catal. Today, 1995, 24: 361

[117] Iglesias-Juez A, Beale A M, Maaijen K, Weng T C, Glatzel P, Weckhuysen B M. J. Catal., 2010, 276: 268

[118] Vu B K, Song M B, Ahn I Y, Suh Y-W, Suh D J, Kim W-I, Koh H-L, Choi Y G, Shin E W. Appl. Catal. A-Gen., 2011, 400: 25

[119] Praserthdam P., Mongkhonsi T., Kunatippapong S., Jaikaew B., Lim N.; Eds.:Bartholomew C. H., Fuentes G. A., Catalyst Deactivation, 1997, 111, 153.

[120] Bao Khanh V, Song M B, Ahn I Y, Suh Y-W, Suh D J, Kim J S, Shin E W. J. Ind. Eng. Chem., 2011, 17: 71

[121] Jiang F, Zeng L, Li S, Liu G, Wang S, Gong J. ACS Catal., 2015, 5: 438

[122] Guntida A, Wannakao S, Praserthdam P, Panpranot J. Catal. Sci. Technol., 2020, 10: 5100

[123] Childers D J, Schweitzer N M, Shahari S M K, Rioux R M, Miller J T, Meyer R J. J. Catal., 2014, 318: 75

[124] Milligan C A, Seemakurthi R R, Gao J, Greeley J P, Miller J T, Ribeiro F H, Zemlyanov D Y. J. Phys. Chem. C, 2022, 126: 13660

[125] Zhang L, Sun J, Jiang S, He H, Ren G, Zhai D, Tu R, Zhai S, Yu T. Catal. Sci. Technol., 2022, 12: 3874

[126] Chen X, Qin X, Jiao Y, Peng M, Diao J, Ren P, Li C, Xiao D, Wen X, Jiang Z, Wang N, Cai X, Liu H, Ma D. Nat. Commun., 2023, 14: 1

[127] Zhang Y, Shi S, Wang Z, Lan H, Liu L, Sun Q, Guo G, He X, Ji H. Aiche J., 2024, 70: e18431

[128] Zeng L, Li W, Wei X, Cheng J, Zhou W, Zheng Y, Cai F, Liu Y, Cheng K, Zhang Q, Wang Y. Chemcatchem, 2023, 15: e202201405

[129] Zeng L, Cheng K, Sun F, Fan Q, Li L, Zhang Q, Wei Y, Zhou W, Kang J, Zhang Q, Chen M, Liu Q, Zhang L, Huang J, Cheng J, Jiang Z, Fu G, Wang Y. Science, 2024, 383: 998

[130] Zhang M, Feng H, Wang S, Liu T, Deng Y, Han J, Zhang X. J. Phys. Chem. Lett., 2024, 15: 3785

[131] He Y, Song Y, Cullen D A, Laursen S. J. Am. Chem. Soc., 2018, 140: 14010

[132] He Y, Song Y, Laursen S. ACS Catal., 2019, 9: 10464

[133] Zhang Q, Jiang X, Su Y, Zhao Y, Qiao B. Chin. J. Catal., 2024, 57: 105

[134] Wei S, Dai H, Long J, Lin H, Gu J, Zong X, Yang D, Tang Y, Yang Y, Dai Y. Chem. Eng. J., 2023, 455: 140726

[135] Hu Z-P, Qin G, Han J, Zhang W, Wang N, Zheng Y, Jiang Q, Ji T, Yuan Z-Y, Xiao J, Wei Y, Liu Z. J. Am. Chem. Soc., 2022, 144: 12127

[136] Qu Z, He G, Zhang T, Fan Y, Guo Y, Hu M, Xu J, Ma Y, Zhang J, Fan W, Sun Q, Mei D, Yu J. J. Am. Chem. Soc., 2024, 146: 8939

[137] Zhang L, Ma X, Zheng J, Liu Y, Qin B, Du Y, Wang X, Wang Q, Li W, Li R. Catal. Lett., 2023, 153: 3466

[138] Zhang H, Ma H, Zhao C, Zhou F, Zhu X, Wang G, Li C. Energ. Fuels, 2024, 38: 1355

[139] Zhang H, Ma H, Zhou F, Zhao C, Wang M, Yang M, Wang G, Zhu X, Li C. Catal. Lett., 2024, 154: 4332

[140] Tan S, Hu B, Kim W-G, Pang S H, Moore J S, Liu Y, Dixit R S, Pendergast J G, Sholl D S, Nair S, Jones C W. ACS Catal., 2016, 6: 5673

[141] Wang Y, Wan Z, Ma Q, Gao X, Zhang J, Fan S, Zhao T-S. ACS Appl. Nano Mater., 2024, 7: 21516

[142] Yun J H, Lobo R F. J. Catal., 2014, 312: 263

[143] Wang J, Liu M, Li J, Wang C, Zhang X, Zheng Y, Li X, Xu L, Guo X, Song C, Zhu X. ACS Catal., 2022, 12: 5930

[144] Sun Y-N, Gao Y-N, Wu Y, Shan H, Wang G, Li C. Catal. Commun., 2015, 60: 42

[145] Sun Y, Wu Y, Shan H, Li C. Catal. Lett., 2015, 145: 1413

[146] Estes D. P., Siddiqi G., Allouche F., Kovtunov K. V., Safonova O. V., Trigub A. L., Koptyug I. V., Coperet C., J. Am. Chem. Soc., 2016, 138.

[147] Sun Y-N, Tao L, You T, Li C, Shan H. Chem. Eng. J., 2014, 244: 145

[148] Sun Y, Wu Y, Tao L, Shan H, Wang G, Li C. J. Mol. Catal. A-Chem., 2015, 397: 120

[149] Zhao Z-J, Wu T, Xiong C, Sun G, Mu R, Zeng L, Gong J. Angew. Chem. Int. Ed., 2018, 57: 6791

[150] Rodemerck U, Stoyanova M, Kondratenko E V, Linke D. J. Catal., 2017, 352: 256

[151] Liu G, Zhao Z-J, Wu T, Zeng L, Gong J. ACS Catal., 2016, 6: 5207

[152] Cai L, Zhao Y, Tian X, Qin D, Wei C, Cai X, Chu W, Yang W. Chem. Eng. J., 2024, 494: 153925

[153] He D, Zhang Y, Yang S, Mei Y, Luo Y. Chemcatchem, 2018, 10: 5434

[154] Shee D, Sayari A. Appl. Catal. A-Gen., 2010, 389: 155

[155] Sun X, Xue J, Ren Y, Li X, Zhou L, Li B, Zhao Z. Mol. Catal., 2021, 505: 111520

[156] Sattler J J H B, González-Jiménez I D, Mens A M, Arias M, Visser T, Weckhuysen B M. Chem. Commun., 2013, 49: 1518

[157] Otroshchenko T, Kondratenko V A, Rodemerck U, Linke D, Kondratenko E V. J. Catal., 2017, 348: 282

[158] Zhang Y, Zhao Y, Otroshchenko T, Han S, Lund H, Rodemerck U, Linke D, Jiao H, Jiang G, Kondratenko E V. J. Catal., 2019, 371: 313

[159] Zhang Y, Zhao Y, Otroshchenko T, Lund H, Pohl M-M, Rodemerck U, Linke D, Jiao H, Jiang G, Kondratenko E V. Nat. Commun., 2018, 9: 1

[160] Otroshchenko T, Bulavchenko O, Thanh H V, Rabeah J, Bentrup U, Matvienko A, Rodemerck U, Paul B, Kraehnert R, Linke D, Kondratenko E V. Appl. Catal. A-Gen., 2019, 585: 117189

[161] Chen S, Xu Y, Chang X, Pan Y, Sun G, Wang X, Fu D, Pei C, Zhao Z, Su D, Gong J. Science, 2024, 385: 295

[162] Xie Z, Yu T, Song W, Li J, Zhao Z, Liu B, Gao Z, Li D. ACS Catal., 2020, 10: 14678

[163] Li C-F, Guo X, Shang Q-H, Yan X, Ren C, Lang W-Z, Guo Y-J. Ind.&Eng. Chem. Res., 2020, 59: 4377

[164] Weckhuysen B M, Keller D E. Catal. Today, 2003, 78: 25

[165] Ganduglia-Pirovano M V, Popa C, Sauer J, Abbott H, Uhl A, Baron M, Stacchiola D, Bondarchuk O, Shaikhutdinov S, Freund H-J. J. Am. Chem. Soc., 2010, 132: 2345

[166] Sokolov S, Bychkov V Y, Stoyanova M, Rodemerck U, Bentrup U, Linke D, Tyulenin Y P, Korchak V N, Kondratenko E V. ChemCatChem, 2015, 7: 1691

[167] Rodemerck U, Sokolov S, Stoyanova M, Bentrup U, Linke D, Kondratenko E V. J. Catal., 2016, 338: 174

[168] Sun Z, Zhu Z, Zhang H, Chu C, Han D, Zhang J, Wang F, Bing L, Wang G. Ind.& Eng. Chem. Res., 2024, 63: 7614

[169] Bai P, Yang M, Chen X, Liu Y, Yang W, Zhao L, Wu P, Wang C, Mintova S, Yan Z. Catal. Today, 2022, 402: 248

[170] Zhang L, Chen K, Chen H, Han X, Liu C, Qiao L, Wu W, Yang B. Chem. Eng. J., 2024, 483: 149366

[171] Weckhuysen B M, Wachs I E, Schoonheydt R A. Chem. Rev., 1996, 96: 3327

[172] Sanfilippo D, Buonomo F, Fusco G, Lupieri M, Miracca I. Chem. Eng. Sci., 1992, 47: 2313

[173] Fridman V Z, Xing R, Severance M. Appl. Catal. A-Gen., 2016, 523: 39

[174] Fridman V Z, Xing R. Appl. Catal. A-Gen., 2017, 530: 154

[175] De Rossi S, Casaletto M P, Ferraris G, Cimino A, Minelli G. Appl. Catal. A-Gen., 1998, 167: 257

[176] Sokolov S, Stoyanova M, Rodemerck U, Linke D, Kondratenko E V. J. Catal., 2012, 293: 67

[177] Zhang Y, Yang S, Lu J, Mei Y, He D, Luo Y. Ind.& Eng. Chem. Res., 2019, 58: 19818

[178] Sim S, Gong S, Bae J, Park Y-K, Kim J, Choi W C, Hong U G, Park D S, Song I K, Seo H, Kang N Y, Park S. Mol. Catal., 2017, 436: 164

[179] Li P-P, Lang W-Z, Xia K, Luan L, Yan X, Guo Y-J. Appl. Catal. A-Gen., 2016, 522: 172

[180] Liu J, Liu Y, Ni Y, Liu H, Zhu W, Liu Z. Catal. Sci. Technol., 2020, 10: 1739

[181] Jin D, Xu H, Zhu J, Cheng D. Mol. Catal., 2023, 551: 113624

[182] Otroshchenko T, Radnik J, Schneider M, Rodemerck U, Linke D, Kondratenko E V. Chem. Commun., 2016, 52: 8164

[183] Otroshchenko T P, Kondratenko V A, Rodemerck U, Linke D, Kondratenko E V. Catal. Sci. Technol., 2017, 7: 4499

[184] Li M, Wang S, Dong M, Wang J, Fan W. Chem. Res. Chinese Universities, 2025, 41: 529

[185] Otroshchenko T, Sokolov S, Stoyanova M, Kondratenko V A, Rodemerck U, Linke D, Kondratenko E V. Angew. Chem., Int. Ed., 2015, 54: 15880

[186] Xu Y, Chen S, Chang X, Wang X, Sun G, Lu Z, Zhao Z-J, Pei C, Gong J. ACS Catal., 2023, 13: 6104

[187] Zhao D, Tian X, Doronkin D E, Han S, Kondratenko V A, Grunwaldt J-D, Perechodjuk A, Thanh Huyen V, Rabeah J, Eckelt R, Rodemerck U, Linke D, Jiang G, Jiao H, Kondratenko E V. Nature, 2021, 599: 234

[188] Huang Z, He D, Deng W, Jin G, Li K, Luo Y. Nat. Commun., 2023, 14: 1

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