Controllable Synthesis of JIS-10:Eu³⁺ Red Phosphor and Performance Optimization of Fluorescent Probe for Antibiotic Detection

Abstract

A series of Eu³⁺ doped manganese phosphite (JIS-10:Eu³⁺) red phosphors was prepared via the hydrothermal method. The regulation of Eu³⁺ doping concentration on the material structure, luminescence properties, and antibiotic fluorescence sensing characteristics was systematically investigated. Experiments showed that when the Eu³⁺ doping concentration (molar fraction) was 0.01, the material exhibited the strongest red emission at 617 nm. Under near-ultraviolet excitation at 394 nm, the luminescence intensity of JIS-10:0.01Eu³⁺ showed a linear relationship with the Eu³⁺ concentration. When this material was used as a fluorescent probe for tetracycline detection, its fluorescence intensity exhibited a good linear response to tetracycline concentration in the range of 0.1–200 µmol/L, and it showed significant selectivity towards structural analogs, such as sulfadiazine and norfloxacin.

Keywords

Rare-earth / Photoluminescence / Red phosphors / Antibiotic detection

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RIGHTS & PERMISSIONS

Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH