Towards Bio-derived Electrolytes for Sustainable Redox Flow Batteries

Abstract

The transition to renewable energy systems has intensified the need for sustainable, large-scale energy storage solutions, and redox flow batteries (RFBs) have emerged as a promising technology due to their scalability, safety, and long cycle life. However, conventional RFBs that rely on metal-based electrolytes face significant challenges, including high cost, resource scarcity, and environmental toxicity. Bio-derived electrolytes offer a sustainable alternative that combines renewable sources with tunable electrochemical properties. This review comprehensively summarizes the latest progress of RFB bio-derived electrolytes and discusses the electrochemical performances of plant-derived quinones, lignin derivatives, and fungal metabolites. The limitations in the systems, such as lower solubility limits, crossover issues, and long-term stability are evaluated, with suggested future research directions. The work provides valuable insights for the development of next-generation green RFB systems, which align with global sustainability goals.

Keywords

Redox flow battery / Electrolyte / Bio-derived electrolyte / Biomaterial / Sustainability / Chemical Sciences / Physical Chemistry (incl. Structural)

References

[1] WangW, LuoQ, LiB, WeiX, LiL, YangZAdv. Funct. Mater., 2013, 23: 970.

[2] RanaM M, UddinM, SarkarM R, MerajS T, ShafiullahG, MuyeenS, IslamM A, JamalTJ. Energy Storage, 2023, 68: 107811.

[3] HuoX, ShiX, BaiY, ZengY, AnLCell Rep. Phys. Sci., 2024, 5: 101782.

[4] HuoX, ShiX, WangQ, ZengY, AnLCurr. Opin. Electrochem., 2024, 49: 101633.

[5] LiJ, ZhangB, SongQ, BorthwickA GRSC Adv., 2016, 6: 32940.

[6] ReynardD, VrubelH, DennisonC R, BattistelA, GiraultHChemSusChem, 2019, 12: 1222.

[7] NavalpotroP, Castillo-MartínezE, Carretero-GonzálezJSustain. Energy Fuels, 2021, 5: 310.

[8] KoeseM, BlancoC F, VertV B, VijverM GJ. Ind. Ecol., 2023, 27: 223.

[9] PoliN, BonaldoC, MorettoM, GuarnieriMAppl. Energy, 2024, 362: 122954.

[10] JanoschkaT, MartinN, HagerM D, SchubertU SAngew. Chem. Int. Ed., 2016, 55: 14427.

[11] LiB, LiuJNatl. Sci. Rev., 2017, 4: 91.

[12] HouZ, ChenX, LiuJ, HuangZ, ChenY, ZhouM, LiuW, ZhouHJ. Power Sources, 2024, 601: 234242.

[13] BamgbopaM O, FetyanA, VaginM, AdelodunA AJ. Energy Storage, 2022, 50: 104352.

[14] DellerZ, JonesL A, ManiamSGreen Chem., 2021, 23: 4955.

[15] DingY, YuGAngew. Chem. Int. Ed., 2017, 56: 8614.

[16] LiedelCChemSusChem, 2020, 13: 2110.

[17] HanC, LiH, ShiR, ZhangT, TongJ, LiJ, LiBJ. Mater. Chem. A, 2019, 7: 23378.

[18] MiroshnikovM, DivyaK P, BabuG, MeiyazhaganA, AravaL M R, AjayanP M, JohnGJ. Mater. Chem. A, 2016, 4: 12370.

[19] BerlingS, HidalgoJ M, PatilN, García-QuismondoE, PalmaJ, de LeónC PJ. Energy Storage, 2023, 68: 107620.

[20] AbdelazizO Y, VivesM B, MankarS V, WarlinN, NguyenT T, ZhangB, HultebergC P, KhataeeAiScience, 2024, 27: 10941.

[21] KimN, LienemannS, KhanZ, GreczynskiG, RahmanudinA, VaginM, AhmedF, PetsagkourakisI, EdbergJ, CrispinXJ. Mater. Chem. A, 2023, 11: 25703.

[22] MiroshnikovM, MahankaliK, ThangavelN K, SatapathyS, AravaL M R, AjayanP M, JohnGChemSusChem, 2020, 13: 2186.

[23] LiuY, LuS, ChenS, WangH, ZhangJ, XiangYACS Appl. Energy Mater., 2019, 2: 2469.

[24] HuP, LanH, WangX, YangY, LiuX, WangH, GuoLEnergy Storage Mater., 2019, 19: 62.

[25] AdewuyiA, AkinreleJJ. Appl. Sci. Environ. Manag., 2022, 26: 187

[26] YangG, ZhuY, HaoZ, ZhangQ, LuY, YanZ, ChenJAdv. Energy Mater., 2024, 14: 2400022.

[27] LuoQ, ZengT, GuK, LinQ, YangWACS Appl. Energy Mater., 2024, 7: 11610.

[28] BajwaD S, PourhashemG, UllahA H, BajwaS GInd. Crops Prod., 2019, 139: 111526.

[29] WuX, JiangJ, WangC, LiuJ, PuY, RagauskasA, LiS, YangBBiofuels Bioprod. Biorefining., 2020, 14: 650.

[30] JungH Y, LeeJ S, HanH T, JungJ, EomK, LeeJ TPolymers, 2022, 14: 673.

[31] ChakrabortyM, Battestini VivesM, AbdelazizO Y, HenrikssonG, Wreland LindströmR, HultebergC P, KhataeeAACS Sustain. Chem. Eng., 2024, 12: 15409.

[32] MukhopadhyayA, HamelJ, KatahiraR, ZhuHACS Sustain. Chem. Eng., 2018, 6: 5394.

[33] JiaoL, SunM, YangJ, YangW, DaiHInd. Crops Prod., 2022, 187: 115431.

[34] SchlemmerW, NothdurftP, PetzoldA, RiessG, FrühwirtP, SchmalleggerM, Gescheidt-DemnerG, FischerR, FreunbergerS A, KernWAngew. Chem. Int. Ed., 2020, 59: 22943.

[35] JiaoL, SunM, YangJ, YangW, DaiHInt. J. Biol. Macromol., 2023, 229: 236.

[36] WilhelmsenC O, MuffJ, SørensenJ LEnergy Storage, 2023, 5: e450.

[37] ChristiansenJ V, IsbrandtT, PetersenC, SondergaardT E, NielsenM R, PedersenT B, SørensenJ L, LarsenT O, FrisvadJ CAppl. Microbiol. Biotechnol., 2021, 105: 8157.

[38] Huang J., Wang S., Chen J., Chen C., Lizundia E., Adv. Mater., 2025, 2416733.

[39] WilhelmsenC O, KristensenS B, NolteO, VolodinI A, ChristiansenJ V, IsbrandtT, SørensenT, PetersenC, SondergaardT E, Lehmann NielsenKBatteries & Supercaps, 2023, 6: e202200365.

[40] WilhelmsenC O, Pasadakis-KavounisA, ChristiansenJ V, IsbrandtT, AlmindM R, LarsenT O, HjelmJ, SørensenJ L, MuffJACS Sustain. Chem. Eng., 2023, 11: 9206.

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Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH