Engineering the Interface Between Au Nanoparticles and CoO-Ov to Enhance the Catalytic Performance of 5-Hydroxymethylfurfural (HMF) to 2,5-Dimethylfuran (DMF)

Abstract

The interface between Au and support has attracted extensive interest because of its unique catalytic ability for hydrogen activation in catalytic hydrogenation/hydrogenolysis reactions. Herein, we create the Au-CoO-O_V interface in the 1.0%Au/Co₃O₄-Rod-250 catalyst, which could dissociate H₂ via the heterolytic way to yield rich hydride species and achieve excellent catalytic performance in the hydrogenolysis of biomass-derived 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF). The XRD and HRTEM analyses show that Au nanoparticles are uniformly dispersed on CoO-O_V surface and in situ DRIFTS spectra show the enhancement of heterolytic dissociation of hydrogen (signals of Au—D and O—D vibration) compared with bare CoO (Co₃O₄-Rod-250). This work provides insights for fabricating highly active Au-support catalysts for catalytic hydrogenation/hydrogenolysis reactions.

Keywords

Au-CoO-O_V interface / Hydride species / Heterolytic dissociation / 5-Hydroxymethylfurfural (HMF) / 2,5-Dimethylfuran (DMF)

References

[1] Cano I, Martínez-Prieto L M, van Leeuwen P W N M. . Catal. Sci. Technol. (UK), 2021, 11: 1157,

[2] Aireddy D R, Ding K L. . ACS Catal., 2022, 12: 4707,

[3] Jing Y X, Wang Y Q. . Chem Catal., 2023, 3: 100515,

[4] Lent v R, Auras S V, Cao K, Walsh A J, Gleeson M A, Juurlink L B F. . Science, 2019, 363: 155,

[5] Ma Y F, Wang L W, Liu J. . Chem. Res. Chinese Universities, 2022, 38(5): 1163,

[6] Ferrin P, Kandoi S, Nilekar A U, Mavrikakis M. . Surface Science, 2012, 606: 679,

[7] Xiang S, Dong L, Wang Z-Q, Han X, Daemen L L, Li J, Cheng Y Q, Guo Y, Liu X H, Hu Y F, Ramirez-Cuesta A J, Yang S H, Gong X-Q, Wang Y Q. . Nat. Commun., 2022, 13: 3657,

[8] Copéret C, Estes D P, Larmier K, Searles K. . Chem. Rev., 2016, 116: 8463,

[9] Wang L, Yan T J, Song R, Sun W, Dong Y C, Guo J L, Zhang Z Z, Wang X X, Ozin G A. . Angew. Chem. Int. Ed., 2019, 58: 9501,

[10] Ishida T, Murayama T, Taketoshi A, Haruta M. . Chem. Rev., 2020, 120: 464,

[11] Lou Y, Cai Y F, Hu W D, Wang L, Dai Q G, Zhan W C, Guo Y L, Hu P, Cao X-M, Liu J Y, Guo Y. . ACS Catal., 2020, 10: 6094,

[12] Haruta M. . Chem. Rec., 2003, 3: 75,

[13] Chen M S, Goodman D W. . Science, 2004, 306: 252,

[14] Zhang Y L, Zhang J Y, Zhang B S, Si R, Han B, Hong F, Niu Y M, Sun L, Li L, Qiao B T, Sun K J, Huang J H, Haruta M. . Nat. Commun., 2020, 11: 558,

[15] Lu Z, Piernavieja-Hermida M, Turner C H, Wu Z L, Lei Y. . J. Phys. Chem. C, 2018, 122: 1688,

[16] Li Z S, Zhang J H, Wang D Y, Ma W H, Zhong Q. . J. Phys. Chem. C, 2017, 121: 25215,

[17] Kanungo S, Keshri K S, Hoof A J F V, d’Angelo M F N, Schouten J C, Nijhuis T A, Hensen E J M, Chowdhury B. . J. Catal., 2016, 344: 434,

[18] Zhu Z G, Gao X J, Wang X M, Yin M D, Wang Q Y, Ren W Z, Wang B, Lü H Y, Liao W P. . J. Energy Chem., 2021, 62: 599,

[19] Hammer B, Norskov J K. . Nature, 1995, 376: 238,

[20] Hong F, Wang S Y, Zhang J Y, Fu J H, Jiang Q K, Sun K J, Huang J H. . Chinese J. Catal., 2021, 42: 1530,

[21] Wang C-M, Fan K-N, Liu Z-P. . J. Catal., 2009, 266: 343,

[22] Fiorio J L, Lopez N, Rossi L M. . ACS Catal., 2017, 7: 2973,

[23] Zhu Y, Tian L, Jiang Z, Pei Y, Xie S H, Qiao M H, Fan K N. . J. Catal., 2011, 281: 106,

[24] Wan W J, Nie X W, Janik M J, Song C S, Guo X W. . J. Phys. Chem. C, 2018, 122: 17895,

[25] Urayama T, Mitsudome T, Maeno Z, Mizugaki T, Jitsukawa K, Kaneda K. . Chem. Eur. J., 2016, 22: 17962,

[26] Fujitani T, Nakamura I, Akita T, Okumura M, Haruta M. . Angew. Chem. Int. Ed., 2009, 48: 9515,

[27] Zhao J B, Yuan H F, Gui Y H, Li X M, Qin X M, Wei C Z, Liu Y F, Wang G Q, Zhou L M, Fang S M. . J. Mater. Sci., 2021, 56: 5760,

[28] Li S P, Dong M H, Yang J J, Cheng X M, Shen X J, Liu S L, Wang Z-Q, Gong X-Q, Liu H Z, Han B X. . Nat. Commun., 2021, 12: 584,

[29] Mahdavi-Shakib A, Whittaker T N, Yun T Y, Sravan Kumar K B, Rich L C, Wang S G, Rioux R M, Grabow L C, Chandler B D. . Nat. Catal., 2023, 6: 710,

[30] Xie X W, Li Y, Liu Z-Q, Haruta M, Shen W J. . Nature, 2009, 458: 746,

[31] Ouyang B, Xiong S H, Zhang Y H, Liu B, Li J L. . Appl. Catal. A-gen., 2017, 543: 189,

[32] Zhang S R, Shan J-J, Zhu Y, Frenkel A I, Patlolla A, Huang W X, Yoon S J, Wang L, Yoshida H, Takeda S, Tao F. . J. Am. Chem. Soc., 2013, 135: 8283,

[33] Zhang S R, Shan J-J, Zhu Y, Nguyen L, Huang W X, Yoshida H, Takeda S J, Tao F. . Nano Lett., 2013, 13: 3310,

[34] Lukashuk L, Föttinger K, Kolar E, Rameshan C, Teschner D, Hävecker M, Knop-Gericke A, Yigit N, Li H, McDermott E, Stöger-Pollach M, Rupprechter G. . J. Catal., 2016, 344: 1,

[35] Biesinger M C, Payne B P, Grosvenor A P, Lau L W M, Gerson A R, Smart R SC. . Appl. Surf. Sci., 2011, 257: 2717,

[36] Tsunoyama H, Ichikuni N, Sakurai H, Tsukuda T. . J. Am. Chem. Soc., 2009, 131: 7086,

[37] Zhou H R, Li B X, Zhang Y X, Yan X Y, Lv W X, Wang X B, Yuan B B, Liu Y, Yang Z X, Lou X D. . ACS Appl. Mater. Interfaces, 2021, 13: 40429,

[38] Chai M Q, Tan Y, Pei G X, Li L, Zhang L L, Liu X Y, Wang A Q, Zhang T. . J. Phys. Chem. C, 2017, 121: 19727,

[39] Guo Y, Jing Y X, Xia Q N, Wang Y Q. . ACC. Chem. Res., 2022, 55: 1301,

[40] Zhou H, Jing Y X, Wang Y Q. . Acta Phys.-Chim. Sin., 2022, 38: 2203016,

[41] Jiang Z W, Zeng Y J, Hu D, Guo R C, Yan K, Luque R. . Green Chem., 2023, 25: 871,

[42] Chen S, Wojcieszak R, Dumeignil F, Marceau E, Royer S. . Chem. Rev., 2018, 118: 11023,

[43] Dutta S, Bhat N S. . Biomass Conv. Bioref., 2023, 13: 541,

[44] Castillo C, Brijaldo M H, Silva L P C, Passos F B. . ChemCatChem, 2023, 15: e202300480,

[45] Mäki-Arvela P, Ruiz D, Murzin D Y. . ChemSusChem, 2021, 14: 150,

[46] Wang X F, Liang X H, Li J M, Li Q B. . Appl. Catal. A: Gen., 2019, 576: 85,

[47] Xiang S, Dong L, Wang Z-Q, Han X, Guo Y, Liu X H, Gong X-Q, Wang Y Q. . J. Energy Chem., 2023, 77: 191,

[48] Liu P X, Zhao Y, Qin R X, Mo S G, Chen G X, Gu L, Chevrier D M, Zhang P, Guo Q, Zang D D, Wu B H, Fu G, Zheng N F. . Science, 2016, 352: 797,

[49] Silverwood I P, Rogers S M, Callear S K, Parker S F, Catlow C R A. . Chem. Commun., 2016, 52: 533,

[50] Deng Q, Li X, Gao R J, Wang J, Zeng Z L, Zou J-J, Deng S G, Tsang S C E. . J. Am. Chem. Soc., 2021, 143: 21294,

[51] Billups W E, Chang S-C, Hauge R H, Margrave J L. . J. Am. Chem. Soc., 1995, 117: 1387,