Two Indium(III)-based Fluorescent Metal-Organic Frameworks for Highly Sensing Fe³⁺, 2,4-DNP, and TNP

Abstract

Two novel metal-organic frameworks (MOFs), JLU-MOF130 ([In(NH₂−BDC)(Imi)(1H−Imi)]·DMF·H₂O, NH₂−H₂BDC=2-aminobenzene-1,4-dicarboxylic acid, 1H−Imi=1H-imidazole, DMF=N,N-dimethylformamide) and JLU-MOF131 ([In(1,4-NDC)(Imi) (1H−Imi)]·DMF_0.5, 1,4-H₂NDC=1,4-naphthalene-dicarboxylic acid), were synthesized. JLU-MOF130 features a three-dimensional (3D) architecture with a neb topology. JLU-MOF131 is characterized by a two-dimensional (2D) structure with an sql topology. JLU-MOF130 has excellent fluorescence detection performance towards Fe³⁺, 2,4-dinitrophenol (2,4-DNP), and 2,4,6-trinitrophenol (TNP), but the fluorescence detection performance of JLU-MOF131 is further improved by converting NH₂−H₂BDC to more conjugated 1,4-H₂NDC. The Stern-Volmer (SV) quenching constant (K _SV) values of JLU-MOF130 sensing 2,4-DNP, TNP, and Fe³⁺ are 5.24×10⁴, 4.44×10⁴, and 4.73×10³ L/mol, respectively. The corresponding limit of detection (LOD) values are 1.17, 1.36, and 14.59 µmol/L. The K _SV values for JLU-MOF131 are 1.26×10⁵, 9.02×10⁴, and 8.48×10³ L/mol, and the corresponding LOD values are 0.35, 0.42, and 3.60 µmol/L, respectively. interestingly, the emission wavelengths of the two MOFs obviously shift as the fluorescence emission intensities decrease upon the addition of 2,4-DNP and TNP, which can be applied in selective detection.

Keywords

Metal-organic framework / Fluorescence quenching / Fe³⁺ / 2,4-Dinitrophenol (2,4-DNP) / 2,4,6-Trinitrophenol (TNP)

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