A Multifunctional Cobalt (II) Metal-Organic Framework with Nanoporous Channels for Gas and Dye Absorption, and Magnetic Performance

Abstract

Coordination polymer {[Co(BTIA)(H₂O)_0.5]·1.5CH₃OH} _n(Co-1) was synthesized from Co(NO₃)₂·6H₂O and multidentate ligand 4,6-bis-(4H-1,2,4-triazol-1-yl)-isophthalic acid(H₂BTIA) under solvothermal conditions. Crystal analysis found that Co-1 was a (4⁴·6²)₂(4¹⁶·6¹²) 3D framework with one dimensional channels, which gives it good adsorption performance for greenhouse gas CO₂ and anionic dyes CR²⁻ and TY⁻. In particular for the large-size CR²⁻, it behaves a very fast removal rate. In addition, magnetic analysis discloses that antiferromagnetic(AF) coupling exists in binuclear cobalt unit.

Keywords

Co (II) ion / Metal-organic framework(MOF) / Gas adsorption / Dye adsorption / Congo red

References

[1] Furukawa H, Ko N, Go Y B, Aratani N, Choi S B, Choi E, Yazaydin A O, Snurr R Q, O’Keeffe M, Kim J, Yaghi O M. Science, 2010, 329: 424.

[2] Li J R, Sculley J, Zhou H C. Chem. Rev., 2012, 112: 869.

[3] Li B, Wen H M, Cui Y J, Zhou W, Qian G D, Chen B L. Adv. Mater., 201, 28: 8819.

[4] Feng L, Wang K Y, Day G S, Ryder M R, Zhou H C. Chem. Rev., 2020, 120: 13087.

[5] Wang K Y, Feng L G, Yan T H, Wu S X, Joseph E A, Zhou H C. Angew. Chem. Int. Ed., 2020, 59: 11349.

[6] Lian X Z, Fang Y, Joseph E, Wang Q, Li J L, Banerjee S, Lollar C, Wang X, Zhou H C. Chem. Soc. Rev., 2017, 46: 3386.

[7] Wu D, Zhang P F, Yang G P, Hou L, Zhang W Y, Han Y F, Liu P, Wang Y Y. Coord. Chem. Rev., 2021, 434: 213709.

[8] Li L B, Lin R B, Krishna R, Li H, Xiang S C, Wu H, Li J P, Zhou W, Chen B L. Science, 2018, 362: 443.

[9] Lan T H, Li L B, Chen Y, Wang X Q, Yang J F, Li J P. Adv. Mater., 2021, 33: 2100866.

[10] Cui W G, Zhang G Y, Hu T L, Bu X H. Coor. Chem. Rev., 2019, 387: 79.

[11] Wang T, Lin E, Peng Y L, Chen Y, Cheng P, Zhang Z J. Coord. Chem. Rev., 2020, 423: 213485.

[12] Liao P Q, Huang N Y, Zhang W X, Zhang J P, Chen X M. Science, 2017, 356: 1193.

[13] Yi J D, Xie R, Xie Z L, Chai G L, Liu T F, Chen R P, Huang Y B, Cao R. Angew. Chem. Int. Ed., 2020, 59: 23641.

[14] Hou S L, Dong J, Zhao B. Adv. Mater., 2020, 32: 1806163.

[15] Ding M, Flaig R W, Jiang H L, Yaghi O M. Chem. Soc. Rev., 2019, 48: 2783.

[16] Peng D, Yin L, Hu P, Li B, Ouyang Z W, Zhuan G L, Wang Z X. Inorg. Chem., 2018, 57: 2577.

[17] Liu J H, Li L D, Li X X, Zhao D, Sun Y Q, Zheng S T. Chem. Commun., 2019, 55: 7394.

[18] Pinkowicz D, Southerland H I, Avendaño C, Prosvirin A, Sanders C, Wernsdorfer W, Pedersen K S, Dreiser J, Clérac R, Nehrkorn J, Simeoni G, Schnegg A, Holldack K, Dunbar K R. J. Am. Chem. Soc., 2015, 137: 14406.

[19] Liu X Q, Feng X W, Meihaus K R, Meng X X, Zhang Y, Li L, Liu J L, Pedersen K S, Keller L, Shi W, Zhang Y Q, Cheng P, Long J R. Angew. Chem. Int. Ed., 2020, 59: 10610.

[20] Ma Y J, Hu J X, Han S D, Pan J, Li J H, Wang G M. J. Am. Chem. Soc., 2020, 142: 2682.

[21] Sumida K, Rogow D L, Mason J A, McDonald T M, Bloch E D, Herm Z R, Bae T H, Long J R. Chem. Rev., 2012, 112: 724.

[22] Xiang S, He Y, Zhang Z, Wu H, Zhou W, Krishna R, Chen B. Nat. Commun., 2012, 3: 954.

[23] Zhang Z J, Yao Z Z, Xiang S C, Chen B L. Energy Environ. Sci., 2014, 7: 2868.

[24] Okesola B O, Smith D K. Chem. Soc. Rev., 201, 45: 4226.

[25] Zeng M H, Yin Z, Tan Y X, Zhang W X, He Y P, Kurmoo M. J. Am. Chem. Soc., 2014, 136: 4680.

[26] Zou C, Zhang Z, Xu X, Gong Q, Li J, Wu C D. J. Am. Chem. Soc., 2012, 134: 87.

[27] Jia Y Y, Ren G J, Li A L, Zhang L Z, Feng R, Zhang Y H, Bu X H. Cryst. Growth Des., 201, 16: 5593.

[28] Zhou Y, Yao S, Ma Y L, Li G H, Huo Q S, Liu Y L. Chem. Commun., 2018, 54: 3006.

[29] Yang X M, Yan C Y, Li Z Y, Li X, Yu Q, Sang T T, Gai Y L, Zhang Q F, Xiong K C. Inorg. Chem., 2021, 60: 5988.

[30] Wang X S, Liang J, Li L, Lin Z J, Bag P P, Ga S Y, Huang Y B, Cao R. Inorg. Chem., 2015, 55: 2641.

[31] Wu M K, Yi F Y, Fang Y, Xiao X W, Wang S C, Pan L Q, Zhu S R, Tao K, Han L. Cryst. Growth Des., 2017, 10: 5458.

[32] Rodriguez A, Sakiyama H, Masciocchi N, Galli S, Galez N, Lloret F, Colacio E. Inorg. Chem., 2005, 44: 8399.

[33] Li J P, Li B J, Pan M T, Liu B, Cheng J J, Li R Y, Gao X L, Wang S M, Hou H W, Liu Z Y. Cryst. Growth Des., 2017, 17: 2975.

[34] Caballero A B, Rodriguez-Dieguez A, Lezama L, Barea E, Salas J M. Dalt. Trans., 2011, 40: 5180.

[35] Caballero A B, Rodriguez-Dieguez A, Barea E, Quiros M, Salas J M. CrystEngComm., 2010, 12: 3038.

[36] Chen W M, Meng X L, Zhuang G L, Wang Z, Kurmoo M, Zhao Q Q, Wang X P, Shan B R, Tung C H, Sun D. J. Mater. Chem. A, 2017, 5: 13079.

[37] Wang X P, Chen W M, Qi H, Li X Y, Rajnák C, Feng Z Y, Kurmoo M, Boča R, Jia C J, Tung C H, Sun D. Chem. Eur. J., 2017, 23: 7990.

[38] Zhou X J, Liu L L, Tai X S, Zhang H. Chem. Res. Chinese Universities, 2018, 34(5): 723.

[39] Park J, Li J R, Sañudo E C, Yuan D Q, Zhou H C. Chem. Commun., 2012, 48: 883.

[40] Liu Z Y, Zhao H, Song W C, Wang X G, Liu Z Y, Zhao X J, Yang E C. J. Mater. Chem. C, 2019, 7: 191.

[41] Shi W J, Li Y Z, Hu Q X, Wang G D, Hou L, Wang Y Y. J. Solid State Chem., 2020, 283: 121170.

[42] Chen K J, Lin R B, Liao P Q, He C T, Lin J B, Xue W, Zhang Y B, Zhang J P, Chen X M. Cryst. Growth Des., 2013, 13: 2118.

[43] Liu B, Zhao R L, Yang G P, Hou L, Wang Y Y, Shi Q Z. CrystEngComm, 2013, 15: 2057.

[44] Zhai Q G, Lin Q, Wu T, Zheng S T, Bu X H, Feng P Y. Chem. Mater., 2012, 24: 2624.

[45] Ling Y, Yang F L, Deng M L, Chen Z X, Liu X F, Weng L H, Zhou Y M. Dalton Trans., 2012, 41: 4007.

[46] Song Y, Fan R Q, Xing K, Du X, Su T, Wang P, Yang Y L. Cryst. Growth Des., 2017, 17: 2549.

[47] Zhou Y, Yao S, Ma Y L, Li G H, Huo Q S, Liu Y L. Chem. Commun., 2018, 54: 3006.

[48] Rabu P, Rueff J M, Huang Z L, Angelov S, Souletie J, Drillon M. Polyhedron, 2021, 20: 1677.

[49] Rueff J M, Masciocchi N, Rabu P, Sironi A, Skoulios A. Chem.—Eur. J., 2002, 8: 1813.

[50] Rueff J M, Masciocchi N, Rabu P, Sironi A, Skoulios A. Eur. J. Inorg. Chem., 2001, 2001: 2843.