A Luminescent Metal-Organic Framework with LON Topology for Highly Effective Fluorescence Sensing of Fe³⁺ and TNP

Abstract

A luminescent Ag-based metal-organic framework(compound 1) has been synthesized and its structure has been characterized. Compound 1 was fabricated using the Ag+ and bbimb²⁻ ligands and manifestes a rare LON topology. Compound 1 is selective not only in detecting traces of Fe³⁺ and 2,4,6-trinitrophenol(TNP) via luminescence quenching, but also demonstrates high selectivity in the presence of other competitors. Compound 1’s K _sv values towards Fe³⁺ can reach as high as 9.3×l0³ L/mol, which is higher than those of several other MOF materials. It is also a recyclable luminous sensor with the potential to be utilized for detecting TNP. Hence, based on its characteristics, compound 1 can be regarded as a prospective luminescence sensor for detecting Fe³⁺ and TNP.

Keywords

Metal-organic framework / Fluorescence quenching / Fe³⁺ / 2,4,6-Trinitrophenol(TNP)

References

[1] Feng D D, Zhao Y D, Wang X Q, Fang D D, Tang J, Fan L M, Yang J. Dalton Trans., 2019, 48: 10892.

[2] Zhang Q S, Wang J, Kirillov A M, Dou W, Xu C, Xu C L, Yang L Z, Fang R, Liu W S. ACS Appl. Mater. Interfaces, 2018, 10: 23976.

[3] Lin Y H, Yu L, Wang H, Li J. CrystEngComm, 2020, 22: 5946.

[4] Zhu Z, Natarajan V, Wang W N. J. Solid State Chem., 2020, 288: 121434.

[5] Hou L L, Song Y H, Xiao Y J, Wu R, Wang L. Microchem. J., 2019, 150: 104154.

[6] Wu S Y, Lin Y N, Liu J W, Shi W, Yang G M, Cheng P. Adv. Funct. Mater., 2018, 28: 1707169.

[7] Wang J, Li N, Xu Y X, Pang H. Chem. Eur. J., 2020, 26: 6402.

[8] Cai Z Z, Bien C E, Liu Q, Wade C R. Chem. Mater., 2020, 32: 4257.

[9] Pejman M, Firouzjaei M D, Aktij S A, Das P, Zolghadr E, Jafarian H, Shamsabadi A A, Elliott M, Sadrzadeh M, Sangermano M, Rahimpour A, Tiraferri A. ACS Appl. Mater. Interfaces, 2020, 12: 36287.

[10] Rosi N L. Chem. Res. Chinese Universities, 2021, 37(1): 187.

[11] Lei J, Zeng M, Fu L. Chem. Res. Chinese Universities, 2020, 36(4): 504.

[12] Pan T, Yang K, Han Y. Chem. Res. Chinese Universities, 2020, 36(1): 33.

[13] Zhao F H, Guo W Y, Li S Y, Li Z L, Yan X Q, Jia X M, Huang L W, You J M. J. Solid State Chem., 2019, 278: 120926.

[14] Hu Q, Liu J L, Zheng Q M, Chang J F, Wu L Z, Zhang M D, Qin L. Microporous Mesoporous Mater., 2021, 321: 111130.

[15] Yang L, Song Y H, Wang L. J. Mater. Chem. B, 2020, 8: 3292.

[16] Du J L, Zhang X Y, Li C P, Gao J P, Hou J X, Jing X, Mu Y J, Li L J. Sens. Actuators, B, 2018, 257: 207.

[17] Liu W N, Tong W Q, Ma L L, Wang Y, Wang J M, Hou L, Wang Y Y. Dalton Trans., 2019, 48: 7786.

[18] Wu D, Liu J, Jin J, Cheng J G, Wang M, Yang G P, Wang Y Y. Cryst. Growth Des., 2019, 19: 6774.

[19] Dhankhar S S, Sharma N, Nagaraja C M. Inorg. Chem. Front., 2019, 6: 1058.

[20] Yu C Y, Sun X D, Zou L F, Li G H, Zhang L R, Liu Y L. Inorg. Chem., 2019, 58: 4026.

[21] Hazra A, Bej S, Mondal A, Murmu N C, Banerjee P. ACS Omega, 2020, 5: 15949.

[22] Zhang F, Chen S Y, Nie S Q, Luo J, Lin S M, Wang Y, Yang H. Polymers, 2019, 11: 1956.

[23] Deng Y J, Chen N J, Li Q Y, Wu X J, Huang X L, Lin Z H, Zhao Y G. Cryst. Growth Des., 2017, 17: 3170.

[24] Xing S H, Bing Q M, Qi H, Liu J Y, Bai T Y, Li G H, Shi Z, Feng S H, Xu R R. ACS Appl. Mater. Interfaces, 2017, 9: 23828.

[25] Xing S H, Bing Q M, Song L F, Li G H, Liu J Y, Shi Z, Feng S H, Xu R R. Chem. Eur. J., 201, 22: 16230.

[26] Alam P, Leung N L C, Zhang J, Kwok R T K, Lam J W Y, Tang B Z. Coord. Chem. Rev., 2021, 429: 213693.

[27] Han L J, Kong Y J, Hou G Z, Chen H C, Zhang X M, Zheng H G. Inorg. Chem., 2020, 59: 7181.

[28] Qian L L, Wang Z X, Ding J G, Tian H X, Li K, Li B L, Li H Y. Dyes Pigm., 2020, 175: 108159.

[29] Zuo L Q, Zhang T F, Zhang Z K, Hou J X, Liu G J, Du J L, Li L J. Inorg. Chem., Commun., 2019, 99: 113.

[30] Wiwasuku T, Boonmak J, Siriwong K, Ervithayasuporn V, Youngme S. Sens. Actuators, B, 2019, 284: 403.

[31] Varnaseri N, Ramazani A, Morsali A, Rouhani F. J. Solid State Chem., 2020, 291: 121622.

[32] Wang X K, Wang Y T, Wang X, Lu K B, Jiang W F, Cui P P, Hao H G, Dai F N. Dalton Trans., 2020, 49: 15473.

[33] Wen G L, Wu W P, Wang F W, Liu D F, Wang X L, Rong J W, Wang Y Y. CrystEngComm, 2021, 23: 6171.

[34] Chand S, Mondal M, Pal S C, Pal A, Maji S, Mandal D, Das M C. New J. Chem., 2018, 42: 12865.

[35] Dalapati R, Biswas S. Chem. Asian J., 2019, 14: 2822.

[36] Bai K P, Zhou L J, Yang G P, Cao M X, Wang Y Y. Chemistryselect., 2019, 4: 12794.

[37] Wang X H, Lei M Y, Zhang T J, Zhang Q F, Zhang R F, Yang M. Dalton Trans., 2021, 50: 3816.

[38] Zhang X D, Ren G J, Li M L, Yang W T, Pan Q H. Cryst. Growth Des., 2019, 19: 6308.

[39] Peng M N, Huang K, Li X L, Han D F, Qiu Q, Jing L H, Qin D B. J. Solid State Chem., 2019, 280: 156.

[40] Wang B, Lv X L, Feng D W, Xie L H, Zhang J, Li M, Xie Y B, Li J R, Zhou H C. J. Am. Chem. Soc., 201, 138: 6204.

[41] Wang X Y, Yan P F, Li Y X, An G H, Yao X, Li G M. Cryst. Growth Des., 2017, 17: 2178.

[42] Wang D, Hu Z Y, Xu S S, Li D D, Zhang Q, Ma W, Zhou H P, Wu J Y, Tian Y P. Dalton Trans., 2019, 48: 1900.

[43] Wei J Z, Wang X L, Sun X J, Hou Y, Zhang X, Yang D D, Dong H, Zhang F M. Inorg. Chem., 2018, 57: 3818.

[44] Yang H R, Chen W Y, Chen D M, Zheng Y P, Fang S M. J. Solid State Chem., 2020, 291: 121658.