Configurational Selectivity Study of Two-dimensional Covalent Organic Frameworks Isomers Containing D 2h and C 2 Building Blocks

Xuhan Zheng; Lin Zhang; Chenxiao Xie; Hui Wang; Hui Liu; Qingyan Pan; Yingjie Zhao

doi:10.1007/s40242-022-2001-5

Chemical Research in Chinese Universities ›› 2022, Vol. 38 ›› Issue (2) : 639 -642. DOI: 10.1007/s40242-022-2001-5

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Configurational Selectivity Study of Two-dimensional Covalent Organic Frameworks Isomers Containing D _2h and C ₂ Building Blocks

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Abstract

The isomerization of covalent organic frameworks(COFs) materials is still a mysterious and attractive topic. Diversified monomer structures are still urgently needed to explore the in-depth mechanism of isomerization in these special COFs. This work provides a new D _2h monomer for the construction of [D _2h+C ₂] 2D COFs isomers. A new D _2h monomer adopted here was proven to tend to form a single pore framework structure.

Keywords

Covalent organic framework / Isomerization / Kagome / Dynamic covalent bond

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Xuhan Zheng, Lin Zhang, Chenxiao Xie, Hui Wang, Hui Liu, Qingyan Pan, Yingjie Zhao. Configurational Selectivity Study of Two-dimensional Covalent Organic Frameworks Isomers Containing D _2h and C ₂ Building Blocks. Chemical Research in Chinese Universities, 2022, 38(2): 639-642 DOI:10.1007/s40242-022-2001-5

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