Multi-functional Photoelectric Sensor Based on a Three-fold Interpenetrated Cd(II) Coordination Polymer for Sensitive Detecting Different Ions

Abstract

Athree-fold interpenetrated cadmium coordination polymer [Cd₃(BTC)₂(H₂O)₉]·2H₂O(CP 1)(H₃BTC=1,3,5-benzenetricarboxylic acid) was selected and synthesized to investigate its photoelectric properties. CP 1 showed excellent sensitivity for Cr₂O₇ ²⁻ and Fe³⁺, low limit of detection(LOD: 0.39 µmol/L for Cr₂O₇ ²⁻ and 1.72 µmol/L for Fe³⁺) and stability as electrochemical sensor. More importantly, fluorescence sensing studies indicated that CP 1 exhibits sensing activity for Fe³⁺, Fe²⁺, and MnO₄ ⁻ with good cyclic stability and selectivity. Low LOD and high-sensitivity capability of CP 1 make it a potential multifunctional photoelectric sensor.

Keywords

Coordination polymer / Photoelectric sensor / Electrochemistry sensing / Fluorescence sensing / Cr₂O₇ ²⁻ and MnO₄ ⁻

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