Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties

Abstract

Solvothermal reactions of cadmium salts with bipyridyl diene and triene ligands[(1,3-bis((E)-2-(pyridin-4-yl)vinyl)benzene-(1,3-bpeb) and 1,6-bis(4-pyridyl)-1,3,5-hexatriene(bphte)] and one bipyridyl triene ligand[1,6-bis(4-pyridyl)-1,3,5-hexatriene-(bphte)] in the presence of auxiliary carboxylic acids including 2,6-dichlorobenzoic acid(2,6-HDCBA) and 2-naphthal-enecarboxylic acid(2-HNCA) gave rise to four coordination polymers [Cd(bphte)(2,6-DCBA)₂] _n(1), {[Cd(bphte)(2-NCA)₂]·5.8H₂O} _n(2), [Cd₂(1,3-bpeb)₂(2,6-DCBA)₄] _n(3) and {[Cd₄(1,3-bpeb)₄(2-NCA)₇(HCOO)]·2-HNCA·H₂O} _n(4), respectively. Compounds 1–4 were structurally characterized by elemental analysis, IR, ¹H NMR, powder X-ray diffraction, thermogravimetric analysis and single-crystal X-ray diffraction. They possess one-dimensional linear(1, 2) and zigzag(3, 4) chain structures. Their luminescent properties were explored while the representative sample 4 exhibited good luminescent performance in sensing Fe(III) in water.

Keywords

Coordination polymer / Bipyridyl olefinic ligand / Crystal structure / Luminescent property

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